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7,7,8,8-tetracyanoquinodimethane microsheets for hydrogen peroxide reduction

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Abstract

In this Letter, we demonstrate for the first time that 7,7,8,8-tetracyanoquinodimethane microsheets (TCNQMSs) can effectively catalyze the reduction of H2O2 because TCNQ is a strong electron acceptor, TCNQMSs modified glass carbon electrode (GCE) is prepared by a simple casting method. This H2O2 sensor shows a fast amperometric response time of less than 3 s, and the corresponding linear range is estimated to be from 3 to 238 mM (r = 0.992) and a detection limit of 4.76 μM at a signal-to-noise ratio of 3. Our present study is important because it provides us a new structure for H2O2 detection application.

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References

  1. Klassen, N., Marchington, D., and McGovan, H.C.E., Anal. Chem., 1994, vol. 66, p. 2921.

    Article  CAS  Google Scholar 

  2. Chang, M.C.Y., Pralle, A., Isacoff, E.Y., and Chang, C.J., J. Am. Chem. Soc., 2004, vol. 126, p. 15392.

    Article  CAS  Google Scholar 

  3. Wang, B., Zhang, J., Pan, Z., Tao, X., and Wang, H., Biosens. Bioelectron., 2009, vol. 24, p. 1141.

    Article  CAS  Google Scholar 

  4. Song, Y., Wang, L., Ren, C., Zhu, G., and Li, Z., Sens. Actuators B, vol. 114, p. 1001.

  5. Tanner, P.A. and Wong, A.Y.S., Anal. Chim. Acta, 1998, vol. 370, p. 279.

    Article  CAS  Google Scholar 

  6. Dringen, R., Kussmaul, L., and Hampreeht, B., Brain Research Protocols, 1998, vol. 2, p. 223.

    Article  CAS  Google Scholar 

  7. Carmine, T.C., Bruchelt, G., Hahn, T., and Niethammer, D., J. Biolumin. Chemilumin., 1994, vol. 9, p. 267.

    Article  CAS  Google Scholar 

  8. Bui, M.N., Pham, X., Han, K.N., Li, C.A., Kim, Y.S., and Seong, G.H., Sen Actuators B, 2010, vol. 150, p. 436.

    Article  CAS  Google Scholar 

  9. Welch, C.M., Banks, C.E., Simm, A.O., and Compton, R.G., Anal. Bioanal. Chem., 2005, vol. 382, p. 12.

    Article  CAS  Google Scholar 

  10. Li, Y., Zhang, J., Xuan, J., Jiang, L., and Zhu, J., Electrochem. Commun., 2010, vol. 12, p. 777.

    Article  CAS  Google Scholar 

  11. Tian, J., Liu, S., and Sun, X., Langmuir, 2010, vol. 26, p. 15112.

    Article  CAS  Google Scholar 

  12. Liu, S., Tian, J., Wang, L., Li, H., Zhang, Y., and Sun, X., Macromolecules, 2010, vol. 43, p. 10078.

    Article  CAS  Google Scholar 

  13. Tseng, T.C., Urban, C., Wang, Y., Otero, R., Tait, S.L., Alcami, M., Ecija, D., Trelka, M., Gallego, J.M., Lin, N., Konuma, M., Starke, U., Nefedov, A., Langner, A., Woll, C., Herrang, M.A., Martin, F., Kern, K., and Miranda, R., Nat. Chem, 2010, vol. 2, p. 374.

    Article  CAS  Google Scholar 

  14. Chae, I.S., Kang, S.W., Park, J.Y., Lee, Y.G., Lee, J.H., Won, J., and Kang, Y.S., Angew. Chem. Int. Ed., 2011, vol. 50, p. 2982.

    Article  CAS  Google Scholar 

  15. Heintz, R.A., Zhao, H.H., Xiang, O.Y., Grandinetti, G., Cowen, J., and Dunbar, K.R., Inorg. Chem., 1999, vol. 38, p. 144.

    Article  CAS  Google Scholar 

  16. Miyasaka, H., Campos-Fernandez, C.S., Clerac, R., and Dunbar, K.R., Angew. Chem., Int. Ed. Engl., 2000, vol. 39, p. 3831.

    Article  CAS  Google Scholar 

  17. Miyasaka, H., Motokawa, N., Matsunaga, S., Yamashita, M., Sugimoto, K., Mori, T., Toyota, N., and Dunbar, K.R., J. Am. Chem. Soc., 2010, vol. 132, p. 1532.

    Article  CAS  Google Scholar 

  18. Shimomura, S., Yanai, N., Matsuda, R., and Kitagawa, S., Inorg. Chem., 2011, vol. 50, p. 172.

    Article  CAS  Google Scholar 

  19. Li, H., Wang, L., Zhai, J., Luo, Y., Zhang, Y., Tian, J., and Sun, X., Anal. Methods, 2011, vol. 3, p. 1051.

    Article  CAS  Google Scholar 

  20. Bard, A.J. and Faulkner, L.R., Electrochemical Methods: Fundamentals and Applications, N.Y.: Inc. John Wiley & Sons, 2001, 2nd ed.

    Google Scholar 

  21. Lin, D., Jiang, Y., Wang, Y., and Sun, S., J. Nanomater, 2008, vol. 1, p. 473791.

    Google Scholar 

  22. Lu, W., Liao, F., Luo, Y., Chang, G., and Sun, X., Electrochim. Acta, 2011, vol. 56, p. 2295.

    Article  CAS  Google Scholar 

  23. Shabanov, O.M., Ismailova, F.O., Maksumova, D.G., Gadzhiev, S.M., and Magomedova, A.O., Russ. J. Electrochem., 2006, vol. 42, p. 986.

    Article  CAS  Google Scholar 

  24. Fridman, V.A., Bogdanovskaya, V.A., and Tarasevich, M.R., Russ. J. Electrochem., 1998, vol. 34, p. 56.

    CAS  Google Scholar 

  25. Xu, X.X., Zhang, J.X., Guo, F., Zhang, W., Zhou, H.M., Wang, B.L., Zheng, Y.F., Wang, Y.B., Cheng, Y., Luo, X., and Jang, B.Z., Colloids Surf. B: Biointerfaces, 2011, vol. 84, p. 427.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, School of Chemistry and Chemical Industry, China West Normal University, Nanchong, 637002, Sichuan, China

    Xiaoyun Qin, Wenbo Lu, Yonglan Luo, Guohui Chang & Xuping Sun

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  1. Xiaoyun Qin
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  2. Wenbo Lu
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  3. Yonglan Luo
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  4. Guohui Chang
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  5. Xuping Sun
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Corresponding author

Correspondence to Xuping Sun.

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Published in Russian in Elektrokhimiya, 2013, Vol. 49, No. 11, pp. 1219–1222.

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Qin, X., Lu, W., Luo, Y. et al. 7,7,8,8-tetracyanoquinodimethane microsheets for hydrogen peroxide reduction. Russ J Electrochem 49, 1097–1100 (2013). https://doi.org/10.1134/S1023193512080071

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  • DOI: https://doi.org/10.1134/S1023193512080071

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