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Structure and electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with metallic palladium inclusions

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Abstract

The electrochemical behavior of PEDOT/Pd composite films obtained by the chemical deposition of ultradisperse Pd particles in the poly-3,4-ethylenedioxythiophene (PEDOT) polymer matrix was studied. The structure of the films was determined by electron microscopy and energy-dispersion X-ray fluorescence analysis. The electrochemical properties of PEDOT/Pd composite films in solutions containing hydrogen peroxide was also studied. Special attention was paid to the effect of the time of the chemical deposition of palladium in the polymer structure on the electroreduction of hydrogen peroxide in phosphate buffer solutions.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    V. V. Kondratiev, T. A. Babkova & S. N. Eliseeva

Authors
  1. V. V. Kondratiev
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  2. T. A. Babkova
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  3. S. N. Eliseeva
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Correspondence to V. V. Kondratiev.

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Original Russian Text © V.V. Kondratiev, T.A. Babkova, S.N. Eliseeva, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 2, pp. 226–233.

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Kondratiev, V.V., Babkova, T.A. & Eliseeva, S.N. Structure and electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with metallic palladium inclusions. Russ J Electrochem 48, 205–211 (2012). https://doi.org/10.1134/S1023193512020061

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  • DOI: https://doi.org/10.1134/S1023193512020061

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