Abstract
The class of oxygen-ion-conducting rare-earth pyrochlores has been considerably extended. New solid electrolytes, Ln2Ti2O7 (Ln = Dy-Lu) and Ln2Hf2O7 (Ln = Eu, Gd) pyrochlores, are intrinsic ionic conductors at elevated temperatures, as are the well known Ln2Zr2O7 (Ln = Sm-Gd) zirconates, which suggests that oxygen ion conduction in the rare-earth pyrochlore family has a general character. The thermodynamic order-disorder transitions that yield a PII cation- and anion-disordered pyrochlore phase possessing high oxygen ion conductivity occur throughout the rare-earth pyrochlore family: Ln2M2O7 (Ln = Sm-Lu; M = Ti, Zr, Hf). The composition-structure-oxygen-ionic conductivity relationship is analyzed for Ln2(M2 − x Ln x )O7 − δ (Ln = Sm-Lu; M = Ti, Zr, Hf) with x from 0 to 0.81.
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Michel, D., Perez, Y., Jorba, M., and Collongues, R., Mater. Res. Bull., 1974, vol. 9, p. 1457.
Van Dijk, T., de Vries, K.J., and Burggraaf, A.J., Phys. Status Solidi A, 1980, vol. 58, p. 115.
Subramanian, M.A., Aravamudan, G., and Subba Rao, G.V., Prog. Solid State Chem., 1983, vol. 15, p. 55.
Belov, N.V., Mineral. Sb. (Lvov), 1950, no. 4, p. 21.
Collongues, R., Ann. Chim., 1963, vol. 8, p. 395.
Whittle, K.R., Lumpkin, G.R., and Ashbrook, S.E., J. Solid State Chem., 2006, vol. 179, p. 512.
Scientific and Technological Forecasts in the Field of Ferroelectric Materials Synthesis, in Nauchno-tekhnicheskie prognozy v oblasti kataliza, korrozii i sinteza segnetomaterialov (Scientific and Technological Forecasts in the Fields of Catalysis, Corrosion, and Ferroelectric Materials Synthesis), Moscow: NII Tekh.-Ekonom. Issled. im. L.Ya. Karpova, 1976.
Lau, G.C., Muegge, B.D., McQueen, T.M., Duncan, E.L., and Cava, R.G., Solid State Chem., 2006, vol. 179, p. 3126.
Chakoumakos, B., J. Solid State Chem., 1984, vol. 53, p. 120.
McCauley, R.A., J. Appl. Phys., 1980, vol. 51, p. 290.
Lau, G.C., McQueen, T.M., Huang, Q., Zandbergen, H.W., and Cava, R.J., J. Solid State Chem., 2008, vol. 181, p. 45.
Lau, G.C., Ueland, B.G., Dahlberg, M.L., Freitas, R.S., Huang, Q., Zandbergen, H.W., Schiffer, P., and Cava, R.J., Phys. Rev. B: Condens. Matter Mater. Phys., 2007, vol. 76, paper 054 430.
Lau, G.C., Freitas, R.S., Ueland, B.G., Muegge, B.D., Duncan, E.L., Schiffer, P., and Cava, R.J., Nat. Phys., 2006, vol. 2, p. 249.
Wuensch, B.J., Eberman, K.W., Heremans, C., Ku, E.M., Onnerud, P., Yeo, E.M.E., Haile, S., Stalik, J.K., and Jorgensen, J.D., Solid State Ionics, 2000, vol. 129, p. 111.
Knop, O., Brisse, F., Meads, R.E., and Bainbridge, J., Can. J. Chem., 1968, vol. 46, p. 3829.
Moreno, K.J., Fuentes, A.F., Garcia-Barriocanal, J., Leon, C., and Santamaria, J., J. Solid State Chem., 2006, vol. 179, p. 323.
Komissarova, L.N., Shatskii, V.M., Pushkina, G.Ya., Shcherbakova, L.G., Mamsurova, L.G., and Sukhanova, G.E., Soedineniya redkozemel’nykh elementov. Karbonaty, oksalaty, nitraty, titanaty (Rare-Earth Compounds: Carbonates, Oxalates, Nitrates, and Titanates), Moscow: Nauka, 1984.
Petrova, M.A., Novikova, A.S., and Grebenshchikov, R.G., Izv. Akad. Nauk SSSR, Neorg. Mater., 1982, vol. 18, p. 599.
Arsent’ev, P.A., Glushkova, V.B., Evdokimov, A.A., Keler, E.K., Kravchenko, V.B., Kravchinskaya, M.V., Krzhizhanovskaya, V.A., Kuznetsov, A.K., Kurbanov, Kh.M., Potemkin, A.V., Tikhonov, P.A., and Tseitlin, M.N., Soedineniya redkozemel’nykh elementov. Tsirkonaty, gafnaty, niobaty, tantalaty, antimonaty (Rare-Earth Compounds: Zirconates, Hafnates, Niobates, Tantalates, and Antimonates), Moscow: Nauka, 1985.
Shevchenko, A.V., Lopato, L.M., and Nazarenko, L.V., Izv. Akad. Nauk SSSR, Neorg. Mater., 1984, vol. 20, p. 1862.
Fomina, L.N. and Pal’guev, S.F., Zh. Neorg. Khim., 1977, vol. 22, p. 326.
Moreno, K.J., Fuentes, A.F., Maczka, M., Hanuza, J., Amador, U., Santamaria, J., and Leon, C., Phys. Rev. B: Condens. Matter Mater. Phys., 2007, vol. 75, paper 184 303.
Shlyakhtina, A.V., Shcherbakova, L.G., and Knot’ko, A.V., Russ. J. Electrochem., 2003, vol. 39, p. 467.
Shlyakhtina, A.V., Shcherbakova, L.G., and Knotko, A.V., Ferroelectrics, 2003, vol. 294, p. 175.
Shlyakhtina, A.V., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2004, vol. 40, p. 59.
Shlyakhtina, A.V., Shcherbakova, L.G., Knotko, A.V., and Steblevskii, A.V., J. Solid State Electrochem., 2004, vols. 8–9, p. 661.
Shlyakhtina, A.V., Knotko, A.V., Boguslavskii, M.V., Stefanovich, S.Yu., Peryshkov, D.V., Kolbanev, I.V., and Shcherbakova, L.G., Solid State Ionics, 2005, vol. 176, p. 2297.
Shlyakhtina, A.V., Boguslavskii, M.V., Stefanovich, S.Yu., Kolbanev, I.V., Knotko, A.V., Karyagina, O.K., Borisov, S.A., and Shcherbakova, L.G., Inorg. Mater., 2006, vol. 42, p. 519.
Shlyakhtina, A.V., Knotko, A.V., Boguslavskii, M.V., Stefanovich, S.Yu., Kolbanev, I.V., Larina, L.L., and Shcherbakova, L.G., Solid State Ionics, 2007, vol. 178, p. 59.
Tsipis, E.V., Shlyakhtina, A.V., Shcherbakova, L.G., Kolbanev, I.V., Kharton, V.V., Vyshatko, N.P., and Frade, J.R., J. Electroceram., 2003, vol. 10, p. 153.
Shtukenberg, A.G., Punin, Yu.O., and Frank-Kamenetskaya, O.V., Usp. Khim., 2006, vol. 75, no. 12, p. 1212.
Belov, D.A., Shlyakhtina, A.V., Stefanovich, S.Yu., Kolbanev, I.V., Belousov, Yu.A., Karyagina, O.K., and Shcherbakova, L.G., Mater. Res. Bull., 2009, vol. 44, p. 1613.
Shlyakhtina, A.V., Levchenko, A.V., Abrantes, J.C.C., Bychkov, V.Yu., Korchak, V.N., Rassulov, V.A., Larina, L.L., Karyagina, O.K., and Shcherbakova, L.G., Mater. Res. Bull., 2007, vol. 42, p. 742.
Shlyakhtina, A.V., Knot’ko, A.V., Larina, L.L., Borichev, S.A., and Shcherbakova, L.G., Inorg. Mater., 2004, vol. 40, p. 1312.
Abrantes, J.C.C., Levchenko, A.V., Shlyakhtina, A.V., Shcherbakova, L.G., Horovistiz, A.L., Fagg, D.P., and Frade, J.R., Solid State Ionics, 2006, vol. 177, p. 1785.
Shlyakhtina, A.V., Ukshe, A.E., and Shcherbakova, L.G., Russ. J. Electrochem., 2005, vol. 41, p. 265.
Van Dijk, M.P., Mijlhoff, A.J., and Burgraaf, A.J., J. Solid State Chem., 1986, vol. 62, p. 377.
Collongues, R., Queyroux, F., Perez, Y., Jorba, M., and Jilles, J.C., Bull. Soc. Chim. Fr., 1965, vol. 4, p. 1141.
Shlyakhtina, A.V., Kolbanev, I.V., Knotko, A.V., Boguslavskii, M.V., Stefanovich, S.Yu., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2005, vol. 41, p. 854.
Diaz-Guillen, J.A., Fuentes, A.F., Diaz-Guillen, M.R., Almanza, J.M., Santamaria, J., and Leon, C., J. Power Sources, 2009, vol. 186, p. 349.
Yamamura, H., Nishino, H., Kakinuma, K., and Nomura, K., Solid State Ionics, 2003, vol. 158, p. 359.
Volchenkova, Z.S. and Zubankova, D.S., Izv. Akad. Nauk SSSR, Neorg. Mater., 1982, vol. 18, no. 12, p. 2009.
Volchenkova, Z.S. and Zubankova, D.S., Izv. Akad. Nauk SSSR, Neorg. Mater., 1987, vol. 23, no. 7, p. 1175.
Kiruthika, G.V.M., Govindan Kutty, K.V., and Varadarju, U.V., Solid State Ionics, 1998, vol. 110, p. 335.
Shlyakhtina, A.V., Kolbanev, I.V., Shcherbakova, L.G., and Oleinikov, N.N., Materialovedenie, 1998, vol. 10, p. 24.
Shlyakhtina, A.V., Shcherbakova, L.G., Kolbanev, I.V., and Knot’ko, A.V., Materialovedenie, 2002, vol. 65, p. 2.
Eberman, K.W., Wuensch, B.J., and Jorgensen, J.D., Solid State Ionics, 2002, vol. 148, p. 521.
Pruneda, M. and Artacho, E., Phys. Rev. B: Condens. Matter Mater. Phys., 2005, vol. 72, paper 085 107.
Panero, W.R., Stixrude, L., and Ewing, R.C., Phys. Rev. B: Condens. Matter Mater. Phys., 2004, vol. 70, paper 054 110.
Fuentes, A.F., Boulahya, K., Maszka, M., Hanuza, J., and Amado, U., Solid State Sci., 2005, vol. 7, p. 343.
Li, N., Xiao, H.Y., Zu, X.T., Wang, L.M., Ewing, R.C., Lian, J., and Gao, F., J. Appl. Phys., 2007, vol. 102, paper 063 704.
Ushakov, S.V., Navrotsky, A., Tangeman, J.A., and Helean, K.B., J. Am. Ceram. Soc., 2007, vol. 90, no. 4, p. 1171.
Burggraaf, A.J., van Dijk, T., and Verkerk, M.J., Solid State Ionics, 1981, vol. 5, p. 519.
Van Dijk, M.P., Burggraaf, A.J., Cormark, A.N., and Catlow, C.R.A., Solid State Ionics, 1985, vol. 17, p. 159.
Van Dijk, M.P., de Vries, K.J., and Burggraaf, A.J., Solid State Ionics, 1983, vols. 9–10, p. 913.
Van Dijk, M.P., de Vries, K.J., and Burggraaf, A.J., Solid State Ionics, 1985, vol. 16, p. 211.
Van Dijk, M.P., de Vries, K.J., and Burggraaf, A.J., Solid State Ionics, 1986, vol. 21, p. 73.
Pirzada, M., Grimes, R.W., Minervini, L., Maguire, J.F., and Sickafus, K.E., Solid State Ionics, 2001, vol. 140, p. 201.
Chen, J., Liang, J., Wang, L.M., Ewing, R.C., Wang, R.G., and Pan, W., Phys. Rev. Lett., 2002, vol. 88, paper 105901.
Wilde, P.J. and Catlow, C.R.A., Solid State Ionics, 1998, vol. 112, p. 173.
Nishino, H., Yamamura, H., Arai, T., Kakinuma, K., and Nomura, K., J. Ceram Soc. Jpn., 2004, vol. 112, no. 10, p. 541.
Uehara, T., Koto, K., and Kanamaru, F., Solid State Ionics, 1987, vol. 23, p. 137.
Arachi, Y., Sakai, H., Yamamoto, O., Takeda, Y., and Imanishai, N., Solid State Ionics, 1999, vol. 121, p. 133.
Volchenkova, Z.S. and Zubankova, D.S., Tr. Inst. Ele- ktrokhim., Ural. Nauchn. Tsentr, Akad. Nauk SSSR, 1976, vol. 23, p. 83.
Volchenkova, Z.S., Izv. Akad. Nauk SSSR, Neorg. Mater., 1969, vol. 5, no. 6, p. 1096.
Glushkova, V.B., Kravchinskaya, M.V., Kuznetsov, A.K., and Tikhonov, P.A., Dioksid gafniya i ego soedineniya s oksidami redkozemel’nykh elementov (Hafnium Dioxide and Its Compounds with Rare-Earth Oxides), Leningrad: Nauka, 1984.
Saly, V., Hartmanova, M., and Glushkova, V.B., Solid State Ionics, 1989, vol. 36, p. 189.
Bogdanov, A.G., Rudenko, V.S., and Makarov, L.P., Dokl. Akad. Nauk SSSR, 1965, vol. 160, p. 1065.
Zubankova, D.S. and Volchenkova, Z.S., Tr. Inst. Elektrokhim., Ural. Nauchn. Tsentr, Akad. Nauk SSSR, 1976, vol. 24, p. 89.
Volchenkova, Z.S. and Zubankova, D.S., Tr. Inst. Elektrokhim., Ural. Nauchn. Tsentr, Akad. Nauk SSSR, 1976, vol. 24, p. 66.
Spiridonov, F.M., Komissarova, L.N., Kocharov, A.G., and Spitsin, V.I., Zh. Neorg. Khim., 1969, vol. 14, p. 2535.
Volchenkova, Z.S. and Zubankova, D.S., Izv. Akad. Nauk SSSR, Neorg. Mater., 1978, vol. 14, p. 45.
Kharton, V.V., Yaremchenko, A.A., Naumovich, E.N., and Marques, F.M.B., J. Solid State Electrochem., 2000, vol. 4, p. 243.
Shlyakhtina, A.V., Savvin, S.N., Levchenko, A.V., Knotko, A.V., Fedtke, P., Busch, A., Barfels, T., Wienecke, M., and Shcherbakova, L.G., J. Electroceram., 2010, vol. 24, p. 300.
Brixner, L.H., Inorg. Chem., 1964, vol. 3, p. 1065.
Uematsu, K., Shinozaki, K., Sakurai, O., Mizutani, N., and Kato, M., J. Am. Ceram. Soc., 1979, vol. 62, p. 219.
Kramer, S.A. and Tuller, H.L., Solid State Ionics, 1995, vol. 82, p. 15.
Kramer, S.A., Spears, M.A., and Tuller, H.L., Solid State Ionics, 1994, vol. 72, p. 59.
Mori, M., Tompsett, G.M., Sammes, N.M., Suda, E., and Takeda, Y., Solid State Ionics, 2003, vol. 158, p. 79.
Shlyakhtina, A.V., Savvin, S.N., Levchenko, A.V., Kolbanev, I.V., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2008, vol. 44, p. 299.
Shlyakhtina, A.V., Abrantes, J.C.C., Larina, L.L., and Shcherbakova, L.G., Solid State Ionics, 2005, vol. 176, p. 1653.
Levchenko, A., Abrantes, J.C.C., Shlyakhtina, A.V., Shcherbakova, L.G., Horovistiz, A.L., and Frade, J.R., Mater. Sci. Forum, 2006, vols. 515–516, p. 417.
Shlyakhtina, A.V., Abrantes, J.C.C., Levchenko, A.V., Knot’ko, A.V., Karyagina, O.K., and Shcherbakova, L.G., Solid State Ionics, 2006, vol. 177, p. 1149.
Shlyakhtina, A.V., Fedtke, P., Busch, A., Kolbanev, I.V., Barfels, T., Wienecke, M., Sokolov, A.E., Ulianov, V.A., Trounov, V.A., and Shcherbakova, L.G., Solid State Ionics, 2008, vol. 179, p. 1004.
Shannon, R.D. and Prewitt, C.T., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1969, vol. 25, no. 5, p. 925.
Shlyakhtina, A.V., Mosunov, A.V., Stefanovich, S.Yu., Knotko, A.V., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2005, vol. 41, p. 264.
Shlyakhtina, A.V., Mosunov, A.V., Stefanovich, S.Yu., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2004, vol. 40, p. 1317.
Shlyakhtina, A.V., Abrantes, J.C.C., Levchenko, A.V., Stefanovich, S.Yu., Knotko, A.V., Larina, L.L., and Shcherbakova, L.G., Mater. Sci. Forum, 2006, vols. 514-516, p. 422.
Horovistiz, A.L., Abrantes, J.C.C., Boguslavskii, M.V., Shlyakhtina, A.V., Fagg, D.P., Shcherbakova, L.G., and Frade, J.R., Solid State Ionics, 2009, vol. 180, p. 774.
Shlyakhtina, A.V., Savvin, S.N., Levchenko, A.V., Boguslavskii, M.V., and Shcherbakova, L.G., Solid State Ionics, 2008, vol. 179, p. 985.
Shlyakhtina, A.V., Belov, D.A., Karyagina, O.K., and Shcherbakova, L.G., J. Alloys Compd., 2009, vol. 479, p. 6.
Porat, O., Heremance, C., and Tuller, H.L., Solid State Ionics, 1997, vol. 94, p. 75.
Tuller, H.L., Ionic and Mixed Conductors, Materials Design and Optimization in High-Temperature Electrochemistry: Ceramics and Metals, Poulsen, F.W., Bonanos, N., Linderoth, S., Mogensen, M., and Zachau-Christiansen, B, Eds., Roskilde: Rise Nation Labor, 1996, pp. 139–153.
Deng, Z.Q., Niu, H.J., Kuang, X.J., Allix, M., Claridge, J.B., and Rosseinsky, M.J., Chem. Mater., 2008, vols. 20–22, p. 6911.
Kröger, F.A., The Chemistry of Imperfect Crystals, Amsterdam: North-Holland, 1964.
Pirzada, M., Grimes, R.W., and Maguire, J.F., Solid State Ionics, 2003, vol. 161, p. 81.
Shlyakhtina, A.V., Kolbanev, I.V., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2006, vol. 42, p. 528.
Lacorre, P., Goutenoir, F., Bohnke, O., and Retoux, R., Nature, 2000, vol. 404, p. 856.
Shlyakhtina, A.V., Sokolov, A.E., Ul’yanov, V.A., Trunov, V.A., Boguslavskii, M.V., Levchenko, A.V., and Shcherbakova, L.G., Crystallogr. Rep., 2009, vol. 54, p. 25.
Holtappels, P., Vogt, U., and Graule, T., Adv. Eng. Mater., 2005, vol. 7, no. 5, p. 292.
Heremans, C., Wuensch, B.J., Stalik, J.K., and Prince, E.P., Solid State Chem., 1995, vol. 117, p. 108.
Moon, P.K. and Tuller, H.L., Solid State Ionics, 1988, vols. 28–30, p. 470.
Shlyakhtina, A.V., Knotko, A.V., Boguslavskii, M.V., Stefanovich, S.Yu., Kolbanev, I.V., Peryshkov, D.V., and Shcherbakova, L.G., Inorg. Mater., 2005, vol. 41, p. 406.
Shlyakhtina, A.V., Savvin, S.N., Levchenko, A.V., Kolbanev, I.V., Karyagina, O.K., and Shcherbakova, L.G., Inorg. Mater., 2008, vol. 44, p. 299.
Ivanov-Shitz, A.K. and Murin, I.V., Ionika tverdogo tela (Solid-State Ionics), St. Petersburg: S.-Peterburg. Gos. Univ., 2000, vol. 1.
West, A.R., Solid State Chemistry and Its Applications, New York: Wiley, 1984, vol. 1.
Al’mukhametov, R.F., Abdullin, A.R., and Kutusheva, R.M., 9-oe Mezhdunarodnoe soveshchanie “Fundamental’nye problemy ioniki tverdogo tela” (9th Int. Conf. Fundamental Issues in Solid-State Ionics), Chernogolovka: Inst. Problem Khimicheskoi Fiziki Ross. Akad. Nauk, 2008, p. 32.
Nguyen, B., Liu, Y., and Wither, R.L., Solid State Commun., 2008, vol. 145, p. 72.
Roth, R.S., Vanderah, T.A., Bordet, P., Grey, I.E., Mumme, W.G., Cai, L., and Nino, J.C., J. Solid State Chem., 2008, vol. 181, p. 406.
Deepa, M., Prabhakar Rao, P., Radhakrishnan, A.N., Sibi, K.S., and Koshy, P., Mater. Res. Bull., 2009, vol. 44, p. 1481.
Hagenmuller, P., Proc. Indian Acad. Sci. Chem. Sci., 1983, vol. 92, p. 1.
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Original Russian Text © A.V. Shlyakhtina, L.G. Shcherbakova, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 1, pp. 3–30.
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Shlyakhtina, A.V., Shcherbakova, L.G. New solid electrolytes of the pyrochlore family. Russ J Electrochem 48, 1–25 (2012). https://doi.org/10.1134/S1023193512010144
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DOI: https://doi.org/10.1134/S1023193512010144