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Catalytically active electrodes in the redox processes of oligomeric peroxides

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Abstract

The catalytic activity of different electrodes (Pt, glassy carbon, and amorphous metal alloys Al87.0Y5.0Ni8.0, Fe78.5Ni1.0Mo0.5Si6.0B14.0, and Fe73.1Cu1.0Nb3.0Si15.5B7.4) in the redox processes of polyfunctional oligomeric peroxides based on vinylacetate, 3-tert-butylperoxy-3-phenylbutylmethylmethacrylate and maleic anhydride and vinylacetate, 3-tert-butylperoxy-3-methylbutylmethacrylate and maleic anhydride was evaluated by potentiometry and cyclic voltammetry. It was established that amorphous metal iron-based Fe73.1Cu1.0Nb3.0Si15.5B7.4 and Fe78.5Ni1.0Mo0.5Si6.0B14.0 electrodes manifested a high electrocatalytic activity comparable with that of a platinum electrode in the redox processes of polyfunctional oligomeric peroxides.

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Authors and Affiliations

  1. Ivan Franko L’viv National University, ul. Kirila i Mefodiya 6, L’viv, 79005, Ukraine

    M. A. Kovbuz, O. M. Hertsyk & L. M. Boichishin

Authors
  1. M. A. Kovbuz
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  2. O. M. Hertsyk
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  3. L. M. Boichishin
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Corresponding author

Correspondence to O. M. Hertsyk.

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Original Russian Text © M.A. Kovbuz, O.M. Hertsyk, L.M. Boichishin, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 10, pp. 1276–1280.

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Kovbuz, M.A., Hertsyk, O.M. & Boichishin, L.M. Catalytically active electrodes in the redox processes of oligomeric peroxides. Russ J Electrochem 47, 1194–1198 (2011). https://doi.org/10.1134/S1023193511100089

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  • DOI: https://doi.org/10.1134/S1023193511100089

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