Abstract
The process of synthesis of tryalkyl phosphates, i.e., derivatives of methanol, butanol, and diethylene glycol, by anodic oxidation of dimethyl phosphite in the corresponding alcohol is studied. It is found that three alkyl phosphates corresponding to the three possible combinations of substituents bound to phosphorus in phosphate are formed. It is established that the cause for formation of two of the three oxidation products is reesterification of the initial dimethyl phosphite by the alcohol in the course of electrolysis. It is assumed that the process of reesterification is catalyzed by the acid formed in the anode layer.
Similar content being viewed by others
References
Ohmori, H., Nakai, Sh., Sekiguchi, M., and Masui, M., Chem. Pharm. Bull., 1979, vol. 27, p. 1700.
Tomilov, A.P., Chernykh, I.N., and Martynov, B.I., Zh. Obshch. Khim., 1997, vol. 67, no. 7, p. 1192.
Arbuzov, B.A. and Vinogradova, V.S., Dokl. Akad. Nauk SSSR, 1952, vol. 83, no. 1, p. 79.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.Yu. Berezkin, V.V. Turygin, A.V. Khudenko, S.A. Zhestkov, N.E. Kuz’mina, A.P. Tomilov, E.A. Fokin, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 10, pp. 1272–1275.
Rights and permissions
About this article
Cite this article
Berezkin, M.Y., Turygin, V.V., Khudenko, A.V. et al. Electrochemical synthesis of substituted trialkyl phosphates. Russ J Electrochem 47, 1190–1193 (2011). https://doi.org/10.1134/S1023193511100028
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193511100028