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Electrochemical synthesis of tris(2-chloroethyl) phosphate

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Abstract

Process of preparation of tris(2-chloroethyl) phosphate, a neutral ester of ethylene chlorohydrin and phosphoric acid, by direct electrochemical synthesis from elemental phosphorus and ethylene chlorohydrin in a diaphragmless electrolyzer was studied. Solubility of white phosphorus in tris(2-chloroethyl) phosphate was studied. The formation of tris(2-chloroethyl) phosphate from white and red phosphorus was found to proceed in close yields.

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Authors and Affiliations

  1. State Research Institute of Organic Chemistry and Technology, sh. Entuziastov 23, Moscow, 111024, Russia

    M. Yu. Berezkin, V. V. Turygin & A. P. Tomilov

Authors
  1. M. Yu. Berezkin
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  2. V. V. Turygin
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  3. A. P. Tomilov
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Correspondence to V. V. Turygin.

Additional information

Presented at the 18th AllRussian Conference on Organic Electrochemistry, Tambov, September 15–19, 2014.

Original Russian Text © M.Yu. Berezkin, V.V. Turygin, A.P. Tomilov, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 11, pp. 1223–1228.

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Berezkin, M.Y., Turygin, V.V. & Tomilov, A.P. Electrochemical synthesis of tris(2-chloroethyl) phosphate. Russ J Electrochem 51, 1086–1091 (2015). https://doi.org/10.1134/S1023193515110026

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  • DOI: https://doi.org/10.1134/S1023193515110026

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