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Aging of electrolyte La0.88Sr0.12Ga0.82Mg0.18O3 − δ made using magnetic-pulse compaction

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Abstract

Ceramics of the La0.88Sr0.12Ga0.82Mg0.18O3 − δ solid electrolyte was obtained by magnetic-pulse compaction (MPC) of a powder synthesized using the self-propagating high-temperature synthesis technique with further sintering at 1380°C. Conductivity and its change in time were studied. It was shown that conductivity of fresh samples coincides with conductivity of ceramics obtained using the classical solid-phase synthesis. It was established that conductivity of electrolyte decreased by 18% during isothermal exposure at 700°C for 1 year.

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References

  1. Fergus, J.W., J. Power Sources, 2006, vol. 162, p. 30.

    Article  CAS  Google Scholar 

  2. Shkerin, S.N., Korneva, A.A., Krasil’nikov, V.N., Plaksin, S.V., Korzun, I.V., Vovkotrub, E.G., Khrustov, V.A., Gyrdasova, O.I., Vaganov, E.G., and Kuz’min, A.V., Tez. dokl. XIV Ros. konf. po fiz. khimii i elektroimii tverdykh i rasplavlennykh elektrolitov, In-t vysokotemperatur elektrokhimii UrO RAN, Ekaterinburg (Abstracts of XIV Russian Conference in Physical Chemistry and Electrochemistry of Solid and Molten Electrolytes, Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg), 2007, vol. 2, p. 158.

    Google Scholar 

  3. Gorelov, V., Bronin, D., Sokolova, Ju., Nafe, H., and Adlinger, F., J. Europ. Ceram. Soc., 2001, vol. 21, p. 2311.

    Article  CAS  Google Scholar 

  4. Cong, L., He, T., Ji, Y., Guan, P., Huang, Y., and Su, W., J. Alloys Comp., 2003, vol. 348, p. 325.

    Article  CAS  Google Scholar 

  5. Djurado, E. and Labeau, M., J. Eur. Ceram. Soc., 1998., vol. 18, p. 1397.

    Article  CAS  Google Scholar 

  6. Korneva, A.A., Krasil’nikov, V.N., Shkerin, S.N., Gyrdasova, O.I., Lilipin, A.S., Nikonov, A.V., and Rempel’, A.A., RF Patent No. 2387052, 2010.

  7. Ivanov, V.V., Lipilin, A.S., Kotov, Yu.A., Khrustov, V.R., Shkerin, S.N., Paranin, S.N., Spirin, A.V., and Laygorodov, A.S., J. Power Sources, 2006, vol. 159, p. 605.

    Article  CAS  Google Scholar 

  8. Ivanov, V.V., Lipilin, A.S., Spirin, A.S., Rempel’, A.A., Paranin, S.N., Khrustov, V.R., Shkerin, S.N., Valentsev, A.V., and Zhuravlev, V.D., Al’ternativnaya energetika i ekologiya, 2007, no. 2, p. 75.

  9. Huang, K., Tichy, R.S., and Goodenough, J., J. Am. Ceram. Soc., 1998, vol. 81, p. 2565.

    Article  CAS  Google Scholar 

  10. Rozumek, M., Majewski, P., and Aldinger, F., J. Am. Ceram. Soc., 2004, vol. 87, p. 656.

    Article  CAS  Google Scholar 

  11. Ishihara, T., Perovskite Oxide for Solid Oxide Fuel Cells, New York: Springer, 2009.

    Book  Google Scholar 

  12. Kharton, V.V., Shaula, A.L., Vyshatko, N.P., and Marques, F.M.B., Electrochim. Acta, 2003, vol. 48, p. 1817.

    Article  CAS  Google Scholar 

  13. Shkerin, S.N., Bronin, D.I., Kalashnikova, N.A., and Beresnev, S.M., Elektrokhimiya, 2004, vol. 40, p. 504 [Russ. J. Electrochem., 2004, vol. 40, p. 449].

    Google Scholar 

  14. Polini, R., Pamio, A., and Traversa, E., J. Eur. Ceram. Soc., 2004, vol. 24, p. 1365.

    Article  CAS  Google Scholar 

  15. Li, Z.-C., Zhang, H., Bergmana, B., and Zoub, X., J. Eur. Ceram. Soc., 2006, vol. 26, p. 2357.

    Article  CAS  Google Scholar 

  16. Liu, N., Shi, M., Wang, C., Yung, Y.P., Majewski, P., and Aldinger, F., J. Mater. Sci., 2006, vol. 41, p. 4205.

    Article  CAS  Google Scholar 

  17. Yao, W., Tang, Z., Zhang, Z., Luo, S., Li, J., and Tan, Q., Mat. Sci. Eng., 2003, vol. B99, p. 309.

    CAS  Google Scholar 

  18. Huang, K. and Goodenough, J., J. Alloys Comp., 2000, vol. 303–304, p. 454.

    Article  Google Scholar 

  19. Schmidt, S., Berckemeyer, F., and Weppner, W., Ionics, 2000, vol. 6, p. 139.

    Article  CAS  Google Scholar 

  20. Perfil’ev, M. V., Demin, A. K., Kuzin, B. L., and Lipilin, A. S., Vysokotemperaturnyi elektroliz gazov (High-Temperature Gas Electrolysis), Moscow: Nauka, 1988.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, ul. Amundsena 106, Yekaterinburg, 620016, Russia

    A. V. Nikonov, A. S. Lipilin & A. A. Korneva

  2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    S. N. Shkerin

  3. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia

    V. N. Krasil’nikov & O. I. Gyrdasova

Authors
  1. A. V. Nikonov
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  2. S. N. Shkerin
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  3. A. S. Lipilin
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  4. A. A. Korneva
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  5. V. N. Krasil’nikov
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  6. O. I. Gyrdasova
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Correspondence to A. V. Nikonov.

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Original Russian Text © A.V. Nikonov, S.N. Shkerin, A.S. Lipilin, A.A. Korneva, V.N. Krasil’nikov, O.I. Gyrdasova, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 6, pp. 783–786.

Published on the basis of a presentation delivered at the Xth Conference “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2010.

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Nikonov, A.V., Shkerin, S.N., Lipilin, A.S. et al. Aging of electrolyte La0.88Sr0.12Ga0.82Mg0.18O3 − δ made using magnetic-pulse compaction. Russ J Electrochem 47, 733–736 (2011). https://doi.org/10.1134/S1023193511060085

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  • DOI: https://doi.org/10.1134/S1023193511060085

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