Skip to main content
Log in

Sonoelectrochemical studies on mass transport in some standard redox systems

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

A systematic study pertaining to the effects of ultrasound on four redox processes at a glassy carbon electrode has been undertaken. Ru(NH3)6Cl3, K4Fe(CN)6, methylviologen, and benzoquinone are the redox probes investigated. Ultrasound intensity, distance between the electrode and sonoprobe, the type of sonoprobe and its geometrical arrangement with respect to the working electrode are the variables invoked. Rotating disc electrode and impedance measurements have been made to obtain information on the mass transport processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Compton, R.G., Hardcastle, J.L., and Del Campo, J., Sonoelectrochemistry: Physical Aspects, in Encyclopaedia of Electrochemistry, Bard, A.J., Stratmann, M., and Unwin, P.R., Eds., Weinheim: Wiley-VCH, 2003, vol. 3.

    Google Scholar 

  2. Compton, R.G., Eklund, J.C., and Marken, F., Electroanalysis, 1997, vol. 9, p. 509.

    Article  CAS  Google Scholar 

  3. Mason, T.J., Lorimer, J.P., and Walton, D.J., Ultrasonics, 1990, vol. 28, p. 333.

    Article  CAS  Google Scholar 

  4. Delplancke, J., Di Bella, V., Reisse, J., and Winand, R., Mat. Res. Soc. Symp. Proc., 1995, vol. 372, p. 75.

    CAS  Google Scholar 

  5. Durant, A., Francois, H., Reisse, J., and Demesmaeker, A.K., Electrochim. Acta, 1996, vol. 41, p. 277.

    Article  CAS  Google Scholar 

  6. Walton, D.J., Burke, L.D., and Murphy, M.M., Electrochim. Acta, 1996, vol. 41, p. 2747.

    Article  CAS  Google Scholar 

  7. Durant, A., Delplancke, J.L., Libert, V., and Reisse, J., Eur. J. Org. Chem., 1999, vol. 11, p. 2845.

    Article  Google Scholar 

  8. Pollet, B., Lorimer, J.P., Phull, S.S., and Hihn, J.Y., Ultrason. Sonochem., 2000, vol. 7, p. 69.

    Article  CAS  Google Scholar 

  9. Touyeras, F., Hihn, J.Y., Doche, M.L., and Roizard, X., Ultrason. Sonochem., 2001, vol. 8, p. 285.

    Article  CAS  Google Scholar 

  10. Yasman, Y., Bulatov, V., Gridin, V.V., Agur, S., Galil, N., Armon, R., and Schechter, I., Ultrason. Sonochem., 2004, vol. 11, p. 365.

    CAS  Google Scholar 

  11. Reyman, D., Guereca, E., and Herrasti, P., Ultrason. Sonochem., 2007, vol. 14, p. 653.

    Article  CAS  Google Scholar 

  12. Beckett, E.L., Lawrence, N.S., Tsai, Y.C., Davis, J., and Compton, R.G., J. Pharm. Biomed. Anal., 2001, vol. 26, p. 995.

    Article  CAS  Google Scholar 

  13. Ganesan, R., Shanmugam, S., and Gadanken, A., Synth. Met., 2008, vol. 158, p. 848.

    Article  CAS  Google Scholar 

  14. Mason, T.J., Lorimer, J.P., and Bates, D. M., Ultrasonics, 1992, vol. 30, p. 1.

    Google Scholar 

  15. Hotta, Y., Inukai, K., Taniguchi, M., and Yamagishi, A., J. Electroanal. Chem., 1997, vol. 429, p. 107.

    Article  CAS  Google Scholar 

  16. Blaedel, W.J. and Schieffer, G.W., J. Electroanal. Chem., 1977, vol. 80, p. 259.

    Article  CAS  Google Scholar 

  17. Bird, C.L. and Kuhn, A.T., Chem. Soc. Rev., 1981, vol. 10, p. 49.

    Article  CAS  Google Scholar 

  18. Morrow, G.W., Anodic Oxidation of Oxygen-Containing Compounds in Organic Electrochemistry, Lund, H. and Hammerich, O., Eds., New York: Marcel Decker, 1991, 4th ed.

    Google Scholar 

  19. Compton, R.G., Eklund, J.C., Page, S.D., Mason, T.J., and Walton, D.J., J. Appl. Electrochem., 1996, vol. 26, p. 775.

    Article  CAS  Google Scholar 

  20. Marken, F., Akkermans, R.P., and Compton, R.G., J. Appl. Electrochem., 1996, vol. 415, p. 55.

    Google Scholar 

  21. Compton, R.G., Eklund, J.C., Marken, F., and Waller, D.N., Electrochim. Acta, 1996, vol. 41, p. 315.

    Article  CAS  Google Scholar 

  22. Pollet, B.J., Lorimer, J.P., Phull, S.S., Mason, T.J., and Hihn, J.Y., Ultrason. Sonochem., 2003, vol. 10, p. 217.

    Article  CAS  Google Scholar 

  23. Luque de Castro, M.D. and Priego-Capote, F., Ultrason. Sonochem., 2007, vol. 14, p. 717.

    Article  CAS  Google Scholar 

  24. Bard, A.J. and Faulkner, L.R., Electrochemical Methods, New Delhi: Wiley-India, 2006, 2nd ed.

    Google Scholar 

  25. Wagner, N., Applications of Impedance Spectroscopy, in Impedance Spectroscopy Theory, Experiment, and Applications, Barsoukov, E. and Macdonald, J.R., Eds., New Jersey: Wiley, 2005, 2nd ed.

    Google Scholar 

  26. Boillot, M., Didierjean, S., and Lapicque, F., J. Appl. Electrochem., 2004, vol. 34, p. 1191.

    Article  CAS  Google Scholar 

  27. Marken, F., Eklund, J.C., and Compton, R.G., J. Electroanal. Chem., 1995, vol. 395, p. 335.

    Article  Google Scholar 

  28. Marken, F., Akkermans, R.P., and Compton, R.G., J. Electroanal. Chem., 1996, vol. 415, p. 5.

    Article  Google Scholar 

  29. Marken, F. and Compton, R.G., Electrochim. Acta, 1998, vol. 43, p. 2157.

    Article  CAS  Google Scholar 

  30. Del Campo, F.J., Coles, B.A., Marken, F., Compton, R.G., and Cordemans, E., Ultrason. Sonochem., 1999, vol. 6, p. 189.

    Article  Google Scholar 

  31. Goeting, C.H., Foord, J.S., Marken, F., and Compton, R.G., Diamond. Relat. Mater., 1999, vol. 8, p. 824.

    Article  CAS  Google Scholar 

  32. Saterlay, A.J., Wilkins, S.J., Goeting, C.H., Foord, J.H., Compton, R.G., and Marken, F., J. Solid State Electrochem., 2000, vol. 4, p. 383.

    Article  CAS  Google Scholar 

  33. Hardcastle, J.L., Ball, J.C., Hong, Q., Marken, F., Compton, R.G., Bull, S.D., and Davies, S.G., Ultrason. Sonochem., 2000, vol. 7, p. 7.

    Article  CAS  Google Scholar 

  34. Holt, K.B., Del Campo, J., Foord, J.S., Compton, R.G., and Marken, F., J. Electroanal. Chem., 2001, vol. 513, p. 94.

    Article  CAS  Google Scholar 

  35. Murphy, M.A., Marken, F., and Mocak, J., J. Electroanal. Chem., 2003, vol. 48, p. 3411.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Saraswathi.

Additional information

Published in Russian in Elektrokhimiya, 2011, Vol. 47, No. 1, pp. 18–29.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ramachandran, R., Saraswathi, R. Sonoelectrochemical studies on mass transport in some standard redox systems. Russ J Electrochem 47, 15–25 (2011). https://doi.org/10.1134/S1023193511010149

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193511010149

Keywords

Navigation