Skip to main content
SpringerLink
Log in

Solid electrolytes with cesium-cationic conduction in the Fe2O3-TiO2-Cs2O system

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

New cesium-conducting solid electrolytes based on cesium monoferrite in the Fe2O3-TiO2-Cs2O system are synthesized and studied. It is found that the introduction of titanium dioxide significantly reduces the electronic component of conductivity, which prevails in pure CsFeO2, and raises the ionic conductivity. The latter becomes predominant with increasing concentration of TiO2. The effect of dimensional factor on the characteristics of electrolyte is shown. The optimal compositions studied have very high cesium-cationic conductivity: it is above 10−2 S cm −1 at 300°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Burmakin, E.I., Tverdye elektrolity s provodimost’yu po kationam shchelochnykh metallov (Solid Electrolytes Conducting by Alkali Metal Cations), Moscow: Nauka, 1992.

    Google Scholar 

  2. Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Ionics of Solids), St. Petersburg: Izd-vo SPbU, 2000.

    Google Scholar 

  3. Smol’nikov, V.V., Burmakin, E.I., and Shekhtman, G.Sh., Elektrokhimiya, 1992, vol. 28, p. 1866.

    Google Scholar 

  4. Smol’nikov, V.V., Burmakin, E.I., Esina, N.O., and Shekhtman, G.Sh., in Yavleniya elektroperenosa v oksidnykh sistemakh (Electric Transfer Effects in Oxide Systems), Yekaterinburg: Nauka, 1994, p. 41.

    Google Scholar 

  5. Burmakin, E.I. and Shekhtman, G.Sh., Elektrokhimiya, 1983, vol. 19, p. 915.

    CAS  Google Scholar 

  6. Burmakin, E.I., Shekhtman, G.Sh., and Stepanov, G.K., Neorgan. Mater., 1986, vol. 22, p. 1493.

    CAS  Google Scholar 

  7. Burmakin, E.I. and Shekhtman, G.Sh., Elektrokhimiya, 1988, vol. 24, p. 383.

    CAS  Google Scholar 

  8. Vielhaber, E. and Hoppe, R., Z. Anorg. Allg. Chem., 1969, vol. 369, p. 14.

    Article  CAS  Google Scholar 

  9. Burmakin, E.I., Burov, G.V., Rozanov, I.G., and Shekhtman, G.Sh., Zh. Neorg. Khim., 1978, vol. 23, p. 3366.

    CAS  Google Scholar 

  10. Burmakin, E.I., Shekhtman, G.Sh., and Zhidovinova, S.V., Zh. Neorg. Khim., 1985, vol. 30, p. 2228.

    CAS  Google Scholar 

  11. Burmakin, E.I., Voronin, V.I., Akhtyamova, L.Z., Berger, I.F., and Shekhtman, G.Sh., Elektrokhimiya, 2004, vol. 40, p. 707 [Russ. J. Electrochem. (Engl. Transl.), vol. 40, p. 619].

    Google Scholar 

  12. Burmakin, E.I., Voronin, V.I., Akhtyamova, L.Z., Berger, I.F., and Shekhtman, G.Sh., Elektrokhimiya, 2005, vol. 41, p. 878 [Russ. J. Electrochem. (Engl. Transl.), vol. 41, p. 783].

    Google Scholar 

  13. Shannon, R.D., Acta Crystallogr., 1976, vol. A32, p. 751.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 22, Ekaterinburg, 620219, Russia

    E. I. Burmakin & G. Sh. Shekhtman

Authors
  1. E. I. Burmakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Sh. Shekhtman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Sh. Shekhtman.

Additional information

Original Russian Text © E.I. Burmakin, G.Sh. Shekhtman, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 12, pp. 1473–1478.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burmakin, E.I., Shekhtman, G.S. Solid electrolytes with cesium-cationic conduction in the Fe2O3-TiO2-Cs2O system. Russ J Electrochem 45, 1363–1367 (2009). https://doi.org/10.1134/S1023193509120088

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193509120088

Key words

Search

Navigation