Abstract
The sintering features, electroconductivity, and electrochemical characteristics of bilayer electrodes with functional composite layers based on La(Sr)MnO3 (LSM) and La(Sr)Fe(Co)O3 with LSM collector layer and Bi(Y)O1.5 (YDB) electrolyte additive in contact with Ce (Sm)O2(SDC), La(Sr)Ga(Mg)O3, and Zr(Sc)O2 electrolytes were studied. YDB additive to the electrode collector layer was shown to produce a positive effect to the properties of the studied electrode systems. The maximum electrochemical activity and electroconductivity was observed for the electrodes with 5 wt % of YDB electrolyte additive in the collector layer. Thus, electroconductivity of electrodes is almost doubled and 100 mV cathode overvoltage current density is increased by 30% at the temperatures of 800 to 900°C and up to 10-fold at 650 to 700°C. The collector layer sintering temperature of bilayer electrodes can be reduced from 1150 to 1000°C without loss of electrochemical activity. The service life tests (about 1200 h) of composite electrodes with LSM2-SDC functional layer and 90% LSM2 + 10% YDB collector layer in contact with SDC electrolyte showed the time dependences of polarization resistance tending to saturation and described with damped exponent.
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Alder, B., Lane, J.A., and Steele, B.C.H., J. Electrochem. Soc., 1996, vol. 143, p. 3554.
Tsai, T. and Barnett, S.A., Solid State Ionics, 1997, vol. 98, p. 207.
Wang, Sh. and Zhong, H., J. Power Sources, 2007, vol. 165, p. 58.
Kenjo, T. and Nishiya, M., Solid State Ionics, 1992, vol. 57, p. 295.
Kuzin, B.L., Bogdanovich N.M., Bronin, D.I., Yaroslavtsev, Yu.I., Vdovin, G.K., Kotov, Yu.A., Bagazeev, A.V., Medvedev, A.I., Murzakaev, A.M., Timoshenkova, O.R., and Shtol’ts, A.K., Elektrokhimiya, 2007, vol. 43, p. 968 [Russ. J. Electrochem. (Engl. Transl.), vol. 43, p. ].
Gorshkov, M.Yu., Bogdanovich N.M., Neuimin, A.D., Dunyushkina, L.A., Kuz’min, A.V., and Pankratov, A.A., Elektrokhimiya, 2007, vol. 43, p. 1039 [Russ. J. Electrochem. (Engl. Transl.), vol. 43, p. ].
Yaroslavtsev, I.Yu., Kuzin, B.L., Bronin, D.I., and Bogdanovich, N.M., Elektrokhimiya, 2005, vol. 41, p. 602 [Russ. J. Elecktrochem. (Engl. Transl.), vol. 41, p. ].
Hwang, H.J., Moon, J.W., Lee, S., and Lee, E.A., J. Power Sources, 2005, vol. 145, p. 243.
Zhang, J., Ji, Y., Gao, H., He, T., Liu, J., J. Alloys Comp., 2005, vol. 395, pp. 322–325.
Yamashara, K., Jacobson, C.P., Visco, S.J., and De Jonghe, L.C., Solid State Ionics, 2005, vol. 176, p. 451.
Kuzin, B.L., Demin, A.K., Komarova, N.Yu., in Tez. dokl. 2-go Vsesoyuz. simpoz. “Tverdye elektrolity i ikh analiticheskoe primenenie (Abstracts of Papers, 2-nd All-Union Symposium on Solid Electrolytes and Their Analytical Applications), Sverdlovsk: UNTs, AN SSSR, 1985, p. 153.
Bogdanovich N.M., Neuimin, A.D., Kozhevina, E.V., Vlasov, A.N., Kuz’min, B.V., and Kostareva, V.V., RF Patent no. 2079935, 1997.
Bogdanovich N.M., Gorelov, V.P., Balakireva, V.B., and Dem’yanenko, T.A., Elektrokhimiya, 2005, vol. 41, p. 656 [Russ. J. Electrochem. (Engl. Transl.), vol. 41, p. ].
Rutman, D.S., Toropov, Yu.S., Pliner, S.Yu., Neuimin, A.D., and Polezhaev, Yu.M., Vysokoogneupornye materially iz dioksida tsirkoniya (High-Temperature Zirconia Refractories), Moscow: Metallurgiya, 1985.
Perfil’ev, M.V., Demin, A.K., Kuzin, B.L., and Lipilin, A.S., Vysokotemperaturnyi elektroliz gazov (High-Temperature Electrolysis of Gases), Moscow: Nauka, 1988.
Bogdanovich, N.M., Neuimin, A.D., Vlasov, A.N., Kuz’mina, L.A., and Kuz’min, B.V., Tez. dokl. II Vseros. seminara “Toplivnye elementy I energoustanovki na ikh osnove” (Abstracts of Papers, II All-Russian Seminar on Fuel Cells and Derivative Power Plants), Novosibirsk, 2003, p. 57.
Pal’guev, S.F. and Gil’derman, V.K., Kislorodnyi perenos v oksidnykh elektronnykh provodnikakh (Oxygen Transfer in Oxide Electronic Conductors), Yekaterinburg: Ural Otd. Ros. Akad. Nauk, 2004.
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Original Russian Text © N.M. Bogdanovich, D.I. Bronin, G.K. Vdovin, I.Yu. Yaroslavtsev, B.L. Kuzin, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 4, pp. 486–494.
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Bogdanovich, N.M., Bronin, D.I., Vdovin, G.K. et al. Effect of Bi0.75Y0.25O1.5 electrolyte additive in collector layer to properties of bilayer composite cathodes of solid oxide fuel cells based on La(Sr)MnO3 and La(Sr)Fe(Co)O3 compounds. Russ J Electrochem 45, 456–464 (2009). https://doi.org/10.1134/S1023193509040168
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DOI: https://doi.org/10.1134/S1023193509040168