Skip to main content
SpringerLink
Log in

An impedance study of Ir(210) in HCl solutions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

In the Ir(210)/aqueous HCl solution system the “hydrogen adsorption region” is due to the combined process of hydrogen and chloride ion adsorption. We demonstrate that by using impedance spectroscopy the rates of, and charges associated with, hydrogen and chloride adsorption rates can be determined separately.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dolin, P. and Ershler, B., Acta Physicochimica URSS, 1940, vol. 13, no. 6, p. 747.

    CAS  Google Scholar 

  2. Pajkossy, T. and Kolb, D.M., Electrochem. Comm., 2007, vol. 9, p. 1171.

    Article  CAS  Google Scholar 

  3. Soliman, K., Simeone, F.C., and Kibler, L.A., Electrochem. Commun., 2008 (in press).

  4. Ershler, B., Disc. Farad. Soc., 1947, vol. 1, p. 269.

    Google Scholar 

  5. Frumkin, A.N. and Melik-Gaykazyan, V.I., Dokl. Akad. Nauk SSSR, 1951, vol. 5, p. 855.

    Google Scholar 

  6. Sluyters-Rehbach, M., Pure Appl. Chem., 1994, vol. 66, sect. 7, p. 1831.

    Article  CAS  Google Scholar 

  7. Sluyters-Rehbach, M. and Sluyters, J.H., in Electroanalytical Chemistry, Bard, A.J., Ed., New York: Marcel Dekker, 1970, vol. 4, p. 1.

    Google Scholar 

  8. Kerner, Z. and Pajkossy, T., Electrochim. Acta, 2002, vol. 47, p. 2055.

    Article  CAS  Google Scholar 

  9. Grafov, B.M. and Ukshe, E.A., Elektrokhimicheskie tsepi peremennogo toka (The Electrochemical AC Circuits), Moscow: Nauka, 1973 [in Russian].

    Google Scholar 

  10. Stoynov, Z.B., Grafov, B.M., Savova-Stoynov, B., and Elkin, V.V., Elektrokhimicheskii impedans (The Electrochemical Impedance), Moscow: Nauka, 1991 [in Russian].

    Google Scholar 

  11. Trasatti, S. and Parsons, R., Pure Appl. Chem., 1986, vol. 58, sect. 5.4, p. 437.

    Article  CAS  Google Scholar 

  12. Harrington, D.A. and Conway, B.E., Electrochim. Acta, 1987, vol. 32, p. 1703.

    Article  CAS  Google Scholar 

  13. Clavilier, J., Faure, R., Guinet, G., and Durand, R., J. Electroanal. Chem., 1980, vol. 107, p. 205.

    Article  CAS  Google Scholar 

  14. Kibler, L.A., Preparation and Characterization of Noble Metal Single Crystal Electrode Surfaces, Booklet of Tutorial Courses at ISE Meetings 2000 (Warsaw) and 2002 (Düsseldorf), International Society of Electrochemistry, available at http://www.uniulm.de/echem/index.html?id=1023001, International Society of Electrochemistry, 2003.

  15. Frumkin, A.N., Petrii, O.A., and Damaskin, B.B., in Comprehensive Treatise of Electrochemistry, Bockris, J.O’M., Conway, B.E., and Yeager, E., Eds., New York: Plenum Press, 1980, pp. 221–285.

    Google Scholar 

  16. Clavilier, J., Albalat, R., Gomez, R., Orts, J.M., and Feliu, J.M., J. Electroanal. Chem., 1993, vol. 360, p. 325.

    Article  CAS  Google Scholar 

  17. Orts, J.M., Gómez, R., Feliu, J.M., Aldaz, A., and Clavilier, J., Electrochim. Acta, 1994, vol. 39, p. 1519.

    Article  CAS  Google Scholar 

  18. Weaver, M.J., Langmuir, 1998, vol. 14, p. 3932.

    Article  CAS  Google Scholar 

  19. Morin, S., Dumont, H., and Conway, B.E., J. Electroanal. Chem., 1996, vol. 412, p. 39.

    Article  Google Scholar 

  20. Langkau, T. and Baltruschat, H., Electrochim. Acta, 1998, vol. 44, p. 909.

    Article  CAS  Google Scholar 

  21. Siebert, E., Faure, R., and Durand, R., Electrochem. Comm., 2001, vol. 3, p. 181.

    Article  Google Scholar 

  22. Sibert, E., Faure, R., and Durand, R., J. Electroanal. Chem., 2002, vol. 528, p. 39.

    Article  CAS  Google Scholar 

  23. Sibert, E., Faure, R., and Durand, R., J. Electroanal. Chem., 2001, vol. 515, p. 71.

    Article  CAS  Google Scholar 

  24. Pajkossy, T. and Kolb, D.M., Electrochim. Acta, 2001, vol. 46, p. 3063.

    Article  CAS  Google Scholar 

  25. Pajkossy, T., Z. Phys. Chem., 2003, vol. 217, p. 351.

    CAS  Google Scholar 

  26. Oelgeklaus, R., Rose, J., and Baltruschat, H., J. Electroanal. Chem., 1994, vol. 376, p. 127.

    Article  CAS  Google Scholar 

  27. Soliman, K., Simeone, F.C., and Kibler, L.A., (in press).

  28. Herrmann, C.C., Perrault, G.G., and Pilla, A.A., Anal. Chem., 1968, vol. 40, p. 1173.

    Article  CAS  Google Scholar 

  29. Pajkossy, T., Kibler, L.A., and Kolb, D.M., J. Electroanal. Chem., 2005, vol. 582. p. 69.

    Article  CAS  Google Scholar 

  30. Pajkossy, T., Kibler, L.A., and Kolb, D.M., J. Electroanal. Chem., 2007, vol. 600, p. 113.

    Article  CAS  Google Scholar 

  31. CRC Handbook of Chemistry and Physics, Lide, D.R., Ed., 71st Edition, CRC Press, 1990, p. 12.

Download references

Author information

Authors and Affiliations

  1. Institute of Materials and Environmental Chemistry, Chemical Reseach Center, Hungarian Acadeny of Sciences, Budapest, Pusztaszer; út 59-67, H 1025, Hungary

    T. Pajkossy

  2. Institute of Electrochemistry, University of Ulm, D-89069, Ulm, Germany

    D. M. Kolb

Authors
  1. T. Pajkossy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Kolb
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. Pajkossy.

Additional information

Dedicated to the 100th anniversary of B.V. Ershler.

Published in Elektrokhimiya in Russian, 2009, Vol. 45, No. 1, pp. 32–41.

The text was submitted by authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pajkossy, T., Kolb, D.M. An impedance study of Ir(210) in HCl solutions. Russ J Electrochem 45, 29–37 (2009). https://doi.org/10.1134/S1023193509010054

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193509010054

Key words

Search

Navigation