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Irreversible capacity of the amorphous silicon thin-film electrodes

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Abstract

Irreversible processes accompanying the lithium incorporation into amorphous thin-film silicon are investigated. It is shown that the irreversible processes occurred during the cathodic polarization result in the formation of passive film at the silicon surface. The passive film at silicon is close, in its composition, to the passive film at carbonaceous materials. However, unlike the carbonaceous electrodes, no effect of electrolyte composition on the irreversible capacity of the silicon electrodes is observed.

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References

  1. Lithium Batteries: Science and Technology, Nazri, G.-A. and Pistoia, G., Eds, Boston: Kluwer Academic, 2004.

    Google Scholar 

  2. Jung Hunjoon, Park Min, Yoon Yeo-Geon, Kim Gi-Bum, and Joo Seung-Ki, J. Power Sources, 2003, vol. 115, p. 346.

    Article  CAS  Google Scholar 

  3. Ohara, S., Suzuki, J., Sekine, K., and Takamura, T., J. Power Sources, 2004, vol. 136. p. 303.

    Article  CAS  Google Scholar 

  4. Lee Ki-Lyoung Jung, Ju-Young, Lee Seung-Won, Moon Hee-Soo, and Park Jong-Wan, J. Power Sources, 2004, vol. 129, p. 270.

    Article  CAS  Google Scholar 

  5. Lee Ki-Lyoung, Jung Ju-Young, Lee Seung-Won, Moon Hee-Soo, and Park Jong-Wan, J. Power Sources, 2004, vol. 130, p. 241.

    Article  CAS  Google Scholar 

  6. Shigeki, O., Suzuki, J., Sekine, K., and Takamura, T., J. Power Sources, 2003, vol. 119, p. 591.

    Article  Google Scholar 

  7. Takamura, T., Ohara, S., Uehara, M., Suzuki, J., and Sekine, K., J. Power Sources, 2004, vol. 129, p. 96.

    Article  CAS  Google Scholar 

  8. Kulova, T.L., Skundin, A.M., Pleskov, Yu.V., Terukov, E.I., and Kon’kov, O.I., Elektrokhimiya, 2006, vol. 42, p. 414.

    Google Scholar 

  9. Kon’kov, O.I., Terukov, E.I., and Trapeznikova, I.N., Fiz. Tekhn. Poluprovod., 1996, vol. 30, p. 2183.

    CAS  Google Scholar 

  10. Libao Chen, Xiaohua Xie, Ke Wang, and Jingying Xie, Book of Abstracts, XIII Intern. Meeting on Lithium Batteries (IMLB-2006), Biarritz, France, June 18–23, 2006, Abstr. # 373.

  11. Chusid, O., Ein-Eli, Y., Aurbach, D., Babai, M., and Carmeli, Y., J. Power Sources, 1993, vol. 43, p. 47.

    Article  CAS  Google Scholar 

  12. Novak, P., Joho, F., Lanz, M., Rykart, B., Panitz, J.-C., Alliata, D., Kotz, R., and Haas, O., J. Power Sources, 2001, vol. 97–98, p. 39.

    Article  Google Scholar 

  13. Dolle, M., Grugeon, S., Beaudoin, B., Dupont, L., and Tarascon, J.-M., J. Power Sources, 2001, vol. 97–98, p. 104.

    Article  Google Scholar 

  14. Fong, R., von Sacken, U., and Dahn J.R., J. Electrochem. Soc., 1990, vol. 137, p. 2009.

    Article  CAS  Google Scholar 

  15. Jeong, S.-K., Inaba, M., Abe, T., and Ogumi, Z., J. Electrochem. Soc., 2001, vol. 148, p. A989.

    Article  CAS  Google Scholar 

  16. Hirasawa, K.A., Sato, T., Asahina, H., Yamaguchi, S., and Mori, S., J. Electrochem. Soc., 1997, vol. 144, p. L81.

    Article  CAS  Google Scholar 

  17. Kong, F., Kostecki, R., Nadeau, G., Song, X., Zaghib, K., Kinoshita, K., and McLarnon, F., J. Power Sources, 2001, vol. 97–98, p. 58.

    Article  Google Scholar 

  18. Egorkina, O.Yu. and Skundin, A.M., Elektrokhimiya, 1987, vol. 33, p. 464.

    Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    T. L. Kulova

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  1. T. L. Kulova
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Correspondence to T. L. Kulova.

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Original Russian Text © T.L. Kulova, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 5, pp. 569–573.

Based on the paper presented in the IX International Conference “Basic Problems of Energy Conversion in Lithium Electrochemical Systems” (Ufa, 2006).

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Kulova, T.L. Irreversible capacity of the amorphous silicon thin-film electrodes. Russ J Electrochem 44, 525–529 (2008). https://doi.org/10.1134/S1023193508050042

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  • DOI: https://doi.org/10.1134/S1023193508050042

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