Skip to main content
SpringerLink
Log in

Statistical evaluations of single-ion Gibbs energies of transfer

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

A statistical approach for the evaluation of single-ion Gibbs energies of transfer of the cations Li+, Na+, K+, Rb+, Cs+, Ba2+, Ag+, Tl+, Cu+, Zn2+, Cu2+, Cd2+, Hg2+ and Pb2+ into 40 solvents based on the principal component analysis is presented. It is shown that the Gibbs energies of transfer depend both on the nature of the cation and on the donor site of the respective solvent molecule. Correlation of the data for the investigated cations required separating the solvents into subgroups according to their donor atoms in the solvent molecule. Gibbs energies of transfer into oxygen donor solvents could be correlated with the Born term [N L(z i e 0)2/(8πε0 r i )]. Several cation parameters were investigated with respect to the transfer data into nitrogen and sulfur donor solvents. No correlations were found. Thus the use of cation parameters derived from the statistical analysis are proposed to account for the Gibbs energies of transfer into nitrogen and sulfur donor solvents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pleskov, V.A., J. Phys. Chem. (U.S.S.R), 1948, vol. 22, p. 351.

    CAS  Google Scholar 

  2. Pleskov, V.A., J. Phys. Chem. (U.S.S.R), 1946, vol. 20, p. 153.

    CAS  Google Scholar 

  3. Pleskov, V.A., Acta Physicochimica U.S.S.R., 1940, vol. 13, p. 662.

    CAS  Google Scholar 

  4. Pleskov, V.A., J. Phys. Chem. (U.S.S.R), 1937, vol. 9, p. 12.

    CAS  Google Scholar 

  5. Pleskov, V.A., Usp. Chim., 1947, vol. 16, p. 254.

    CAS  Google Scholar 

  6. Koepp, H.M., Wendt, H., and Strehlow, H., Z. Elektrochem., 1960, vol. 64, p. 483.

    CAS  Google Scholar 

  7. Tanaka, N. and Ogata, T., Inorg. Nucl. Chem. Letters, 1974, vol. 10, p. 511.

    Article  CAS  Google Scholar 

  8. Gritzner, G., Gutmann, V., and Schmid, R., Electrochim. Acta, 1968, vol. 13, p. 919.

    Article  CAS  Google Scholar 

  9. Gritzner, G., Inorg. Chim. Acta, 1977, vol. 24, p. 5.

    Article  CAS  Google Scholar 

  10. Bauer, D. and Beck, J.P., Bull. Soc. Chim. (France), 1973, p. 1252.

  11. Bashkin, J.K. and Kinlen, P.J., Inorg. Chem., 1990, vol. 29, p. 4507.

    Article  CAS  Google Scholar 

  12. Noviandri, I., Brown, K.N., Fleming, D.S., Gulyas, P.T., Lay, P.A., Masters, A.F., and Phillips, L., J. Phys. Chem., Ser. B, 1999, vol. 103, p. 6713.

    Article  CAS  Google Scholar 

  13. Kakutani, T., Morihiro, Y., Senda, M., Takahashi, R., and Matsumoto, K., Bull. Chem. Soc. Jpn., 1978, vol. 51, p. 2847.

    Article  CAS  Google Scholar 

  14. Lewandowski, A., New J. Chem., 1995, vol. 19, p. 1259.

    Google Scholar 

  15. Gritzner, G. and Kuta, J., Pure Appl. Chem., 1984, vol. 56 p. 461.

    Article  Google Scholar 

  16. Gritzner, G., Pure Appl. Chem., 1990, vol. 62, p. 1839; Elektrokhimiya, 1992, vol. 28, p. 1208.

    Article  CAS  Google Scholar 

  17. Gritzner, G. and Lewandowski, A., J. Chem. Soc, Faraday Trans., 1991, vol. 87, p. 2599.

    Article  CAS  Google Scholar 

  18. Hörzenberger, F. and Gritzner, G., J. Chem. Soc, Faraday Trans., 1992, vol. 88, p. 695.

    Article  Google Scholar 

  19. Gritzner, G. and Hörzenberger, F., J. Chem. Soc, Faraday Trans., 1992, vol. 88, p. 3013.

    Article  CAS  Google Scholar 

  20. Gritzner, G. and Lewandowski, A., J. Chem. Soc, Faraday Trans., 1993, vol. 89, p. 3553.

    Article  Google Scholar 

  21. Hörzenberger, F., and Gritzner, G., J. Chem. Soc, Faraday Trans., 1993, vol. 89, p. 3557.

    Article  Google Scholar 

  22. Diggle, J.W. and Parker, A.J., Electrochim. Acta, 1973, vol. 18, p. 975.

    Article  CAS  Google Scholar 

  23. Kundu, K.K. and Parker, A.J., J. Solution Chem., 1981, vol. 10, p. 847.

    Article  CAS  Google Scholar 

  24. Stroka, J., Maksymiuk, K., and Galus, Z., J. Electroanal. Chem., 1984, vol. 167, p. 211.

    Article  CAS  Google Scholar 

  25. Bunakova, L.V., Khanova, L.A., and Krishtalik, L.I., Russian J. Electrochem., 2005, vol. 41, p. 287.

    Article  CAS  Google Scholar 

  26. Krishtalik, L.I., Alpatova, N.M., and Ovsyannikova, E.V., Electrochim. Acta, 1991, vol. 36, p. 435.

    Article  CAS  Google Scholar 

  27. Khanova, L.A., Topolev, V.V., and Krishtalik, L.I., Chem. Phys., 2006, vol. 326, p. 33.

    Article  CAS  Google Scholar 

  28. Behr, B., Gutknecht, J., Schneider, H., and Stroka, J., J. Electroanal. Chem., 1978, vol. 86, p. 289.

    Article  CAS  Google Scholar 

  29. Arnett, E.M. and McKelvey, D.R., J. Am. Chem. Soc., 1966, vol. 88, p. 5801.

    Google Scholar 

  30. Alexander, R. and Parker, A.J., J. Am. Chem. Soc., 1967, vol. 89, p. 5549.

    Article  CAS  Google Scholar 

  31. Alexander, R., Parker, A.J., Sharp, J.H., and Waghorne, W.E., J. Am. Chem. Soc., 1972, vol. 94, p. 1148.

    Article  CAS  Google Scholar 

  32. Koppel, I.A. and Palm, V.A., in Advances in Linear Free Energy Relationships, Chapman, N.B. and Shorter, J., Eds, London: Plenum, 1972, p. 203.

    Google Scholar 

  33. Kamlet, M.J. and Taft, R.W., J. Am. Chem. Soc., 1976, vol. 98, p. 2886.

    Article  Google Scholar 

  34. Kamlet, M.J. and Taft, R.W., J. Am. Chem. Soc., 1976, vol. 98, p. 377.

    Article  CAS  Google Scholar 

  35. Kamlet, M.J, Abboud, J.-L.M., Abraham, M. H., and Taft, R.W., J. Org. Chem., 1983, vol. 48, p. 2877.

    Article  CAS  Google Scholar 

  36. Kamlet, M.J., Doherty, R.M., Abboud, J.-L.M., Abraham, M.H., and Taft, R.W., Chemtech, 1986, p. 566.

  37. Fawcet, W.R. and Krygowski, T.M., Can. J. Chem., 1976, vol. 54, p. 3283.

    Article  Google Scholar 

  38. Pleskov, V.A. and Monoszon, A.M., Acta Physicochimica (U.S.S.R.), 1935, vol. 2, p. 621.

    CAS  Google Scholar 

  39. Ahrland, S., Chatt, J., and Davis, N.R., Q. Rev. Chem. Soc., 1958, vol. 12, p. 265.

    Article  CAS  Google Scholar 

  40. Pearson, R.G., J. Am. Chem. Soc., 1963, vol. 85, p. 3533.

    Article  CAS  Google Scholar 

  41. Huheey, J. E., Inorganic Chemistry, Harper International Edition.

  42. Shannon, R.D., Acta Cryst., Ser. A, 1976, vol. 32, p. 751.

    Article  Google Scholar 

  43. Myers, R.T., Inorg. Chem., 1974, vol. 13, p. 2040.

    Article  CAS  Google Scholar 

  44. Marcus, Y., Thermochim. Acta, 1986, vol. 104, p. 389.

    Article  CAS  Google Scholar 

  45. Klopmann, G., J. Am. Chem. Soc., 1968, vol. 90, p. 223.

    Article  Google Scholar 

  46. Allred, A.L., J. Inorg. Nucl. Chem., 1961, vol. 17, p. 1961.

    Google Scholar 

  47. Ahrland, S., Chem. Phys. Lett., 1968, vol. 2, p. 303.

    Article  CAS  Google Scholar 

  48. Pearson, R.G. and Mawby, R.J., Halogen Chemistry, vol. 3, Gutmann, V., Ed., London, New York: Academic Press, 1967, p. 55.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University Linz, A 4040, Linz, Austria

    G. Gritzner & M. Auinger

  2. Institute for Stochastics, Johannes Kepler University Linz, A 4040, Linz, Austria

    R. Takacs

Authors
  1. G. Gritzner
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Takacs
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Auinger
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Gritzner.

Additional information

Published in Russian in Elektrokhimiya, 2008, Vol. 44, No. 1, pp. 9–17.

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gritzner, G., Takacs, R. & Auinger, M. Statistical evaluations of single-ion Gibbs energies of transfer. Russ J Electrochem 44, 7–15 (2008). https://doi.org/10.1134/S1023193508010035

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193508010035

Key words

Search

Navigation