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Anodic oxidation of silver in 1-butyl-3-methylimidazolium bromide ionic liquid

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Abstract

Electrochemical oxidation of silver in the 1-butyl-3-methylimidazolium bromide ([BMIm]Br) ionic liquid is studied by cyclic voltammetry, chronopotentiometry, chronoammetry, and gravimetry. Two electrode processes irreversibly proceed on the silver electrode in the potential range studied: the formation of compound [BMIm]+[AgBr2]−, which is soluble in [BMIm]Br, and difficultly soluble AgBr.

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    E. P. Grishina, T. V. Vladimirova & L. M. Ramenskaya

  2. Ivanovo State University of Chemical Technology, pr. F. Engelsa 7, Ivanovo, 153460, Russia

    K. S. Shilovskii

Authors
  1. E. P. Grishina
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  2. T. V. Vladimirova
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  3. L. M. Ramenskaya
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  4. K. S. Shilovskii
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Correspondence to E. P. Grishina.

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Original Russian Text © E.P. Grishina, T.V. Vladimirova, L.M. Ramenskaya, K.S. Shilovskii, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 2, pp. 247–251.

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Grishina, E.P., Vladimirova, T.V., Ramenskaya, L.M. et al. Anodic oxidation of silver in 1-butyl-3-methylimidazolium bromide ionic liquid. Russ J Electrochem 43, 234–237 (2007). https://doi.org/10.1134/S1023193507020139

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  • DOI: https://doi.org/10.1134/S1023193507020139

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