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Electrochemical characterization of polyaniline films formed on an ITO substrate during the cathodic reduction of dioxygen

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Abstract

Polyaniline films are fabricated on an electrode of mixed indium and tin oxides (ITO) during the cathodic reduction of dioxygen in an aniline-containing solution. Their electrochemical properties are characterized by methods of cyclic voltammetry, faradaic impedance, and chronoamperometry. A quantitative treatment of results that are obtained by the last two methods leads to results that well agree with each other and makes it possible to reliably determine basic charge transport parameters.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, Petrodvorets, 198504, Russia

    D. V. Zhuzhel’skii, V. D. Ivanov & V. V. Malev

  2. Institute of Cytology, Russian Academy of Sciences, Tikhoretskii pr. 4, St. Petersburg, 194064, Russia

    V. V. Malev

Authors
  1. D. V. Zhuzhel’skii
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  2. V. D. Ivanov
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  3. V. V. Malev
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Correspondence to V. V. Malev.

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Original Russian Text © D.V. Zhuzhel’skii, V.D. Ivanov, V.V. Malev, 2006, published in Elektrokhimiya, 2006, Vol. 42, No. 7, pp. 782–790.

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Zhuzhel’skii, D.V., Ivanov, V.D. & Malev, V.V. Electrochemical characterization of polyaniline films formed on an ITO substrate during the cathodic reduction of dioxygen. Russ J Electrochem 42, 699–707 (2006). https://doi.org/10.1134/S1023193506070020

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  • DOI: https://doi.org/10.1134/S1023193506070020

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