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Pebax2533 Gas Separation Membrane for CO2 Capture Applications: Incorporation and Assessment of New Configured UiO-66 Metal-organic Frameworks

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Abstract

A new configured type of UiO-66 metal-organic frameworks including a honeycomb configuration was utilized to fabricate mixed matrix membranes. The impact of two different types of Pebax solvents, N,N-dimethylformamide and water : ethanol mixture (70 : 30 wt %), on morphological structure and CO2 capture performances of the neat Pebax2533 were initially evaluated. X-ray diffraction and scanning electron microscopy analyses were employed to study morphology of the samples. The typical constant-pressure method was also used to assess separation performance. N,N-dimethylformamide provided the production of more crystalline structures with higher porosities. Additionally, the application of metal-organic frameworks resulted in high CO2 permeability and binary selectivity due to ease of metal-organic frameworks dispersion, small particle agglomeration and hydrogen binding within the polymer matrix. This led to enhancement of CO2 solubility into Pebax2533 in a way that CO2 permeability and CO2/CH4, CO2/N2 selectivity values raised about 76.8, 38.3, and 92.7%, respectively.

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Authors and Affiliations

  1. Department of Chemical Engineering, Arak Branch, Islamic Azad University, Arak, Iran

    Rasoul Sarmadi & Mahmoud Salimi

  2. Department of Chemical Engineering, Central Tehran Branch, Islamic Azad University, Tehran, Iran

    Vahid Pirouzfar

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  1. Rasoul Sarmadi
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  2. Mahmoud Salimi
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  3. Vahid Pirouzfar
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Correspondence to Mahmoud Salimi.

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Rasoul Sarmadi, Salimi, M. & Pirouzfar, V. Pebax2533 Gas Separation Membrane for CO2 Capture Applications: Incorporation and Assessment of New Configured UiO-66 Metal-organic Frameworks. Polym. Sci. Ser. A 64, 781–793 (2022). https://doi.org/10.1134/S0965545X22700511

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  • DOI: https://doi.org/10.1134/S0965545X22700511

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