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Internal Friction in an Epoxy Polymer and a Fiberglass Reinforced Plastic Based on It

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Abstract

The internal friction spectra of cured epoxy T-107 and a fiberglass reinforced plastic based on it are studied. In the temperature dependence of mechanical losses, β and γ relaxation maxima are found below the glass transition temperature with activation energies of Eβ = 0.30 ± 0.05 eV and Eγ = 0.18 ± 0.04 eV, respectively. The first maximum is associated with the vibrations of the defective oxygen atoms of the epoxy groups of the polymer network, and the second maximum is attributed to the vibrations of the lateral OH groups of the main polymer network. The internal friction of the epoxy polymer in the region of α relaxation process has been studied. In this region, two segments with an intersection point at the glass transition temperature are seen in the temperature dependence of the internal friction in coordinates lnQ−1 vs. 1/T. The high temperature segment of the internal friction background is used to estimate the energies of migration and formation of vacancy-like defects in the amorphous matrix of glass reinforced plastics, which are associated with delocalized oxygen and equal to Em = 0.72 ± 0.05 eV and Ev = 1.41 ± 0.06 eV, respectively.

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REFERENCES

  1. T. V. Tropin, Ju. W. P. Schmelzer, and V. L. Aksenov, Phys.-Usp. 59, 42 (2016).

    Article  Google Scholar 

  2. D. V. Novikov, Phys. Solid State 63, 154 (2021).

    Article  CAS  Google Scholar 

  3. S. V. Nemilov and Yu. S. Balashov, Glass Phys. Chem. 42, 119 (2016).

    Article  CAS  Google Scholar 

  4. E. N. Kablov, Herald Russ. Acad. Sci. 82, 158 (2012).

    Article  Google Scholar 

  5. E. V. Prut, L. A. Zhorina, D. D. Novikov, A. Y. Gorenberg, L. V. Vladimirov, and A. A. Berlin, Mendeleev Commun. 27, 405 (2017).

    Article  CAS  Google Scholar 

  6. V. A. Zhuikov, Y. V. Zhuikova, T. K. Makhina, V. L. Myshkina, G. A. Bonartseva, A. P. Bonartsev, A. Rusakov, A. Useinov, V. V. Voinova, A. A. Berlin, and A. L. Iordanskii, Polymers 12, 728 (2020).

    Article  CAS  Google Scholar 

  7. I. A. Timoshkin, V. V. Aleshkevich, E. S. Afanas’eva, B. A. Bulgakov, A. V. Babkin, A. V. Kepman, and V. V. Avdeev, Polym. Sci., Ser. C 62, 172 (2020).

    Article  CAS  Google Scholar 

  8. N. N. Trofimov, M. Z. Kanovich, E. M. Kartashov, V. I. Natrusov, A. T. Ponomarenko, V. G. Shevchenko, V. I. Sokolov, I. D. Simonov-Emel’yanov, Physics of Composite Materials, Two Volumes (Mir, Moscow, 2005) [in Russian].

  9. G. M. Bartenev, Polym. Sci., Ser. B 43, 202 (2001).

    Google Scholar 

  10. S. A. Mazurina, I. D. Simonov-Emel’yanov, V. A. Lomovskoy, M. R. Kiselev, and N. Y. Konstantinov, Inorg. Mater.: Appl. Res. 10, 174 (2019).

    Article  Google Scholar 

  11. G. M. Bartenev and A. G. Barteneva, Relaxation Properties of Polymers (Khimiya, Moscow, 1992) [in Russian].

    Google Scholar 

  12. T. R. Aslamazova, V. I. Zolotarevskii, V. A. Kotenev, N. Y. Lomovskaya, V. A. Lomovskoi, and A. Y. Tsivadze, Prot. Met. Phys. Chem. Surf. 54, 1081 (2018).

    Article  CAS  Google Scholar 

  13. V. A. Lomovoskoi, N. A. Abaturova, N. Yu. Lomovskaya, O. A. Khlebnikova, and T. B. Galushko, Polym. Sci., Ser. A 60, 284 (2018).

    Article  CAS  Google Scholar 

  14. G. Bartenev, L. A. Shelkovnikova, and L. A. Akopyan, Polym. Mech. 9, 133 (1973).

    Article  Google Scholar 

  15. Yu. E. Kalinin, A. T. Kosilov, O. V. Ovdak, A. M. Kudrin, O. A. Karaeva, M. A. Kashirin, and D. Ya. Degtyarev, Tech. Phys. 64, 535 (2019).

    Article  CAS  Google Scholar 

  16. Epoxy Prepreg. https://www.inumit.ru/img/file/t107.pdf. Cited 2021.

  17. S. A. Gridnev, I. I. Popov, M. A. Kashirin, and A. I. Bocharov, J. Alloys Compd. 889, 161764 (2021).

    Article  Google Scholar 

  18. V. A. Rabinovich and Z. Ya. Khavin, Concise Handbook of Chemistry (Khimiya, Leningrad, 1978) [in Russian].

    Google Scholar 

  19. G. M. Bartenev, Structure and Relaxation Properties of Polymers (Khimiya, Moscow, 1979) [in Russian].

    Google Scholar 

  20. V. A. Lomovskoi, N. A. Abaturova, N. Y. Lomovskaya, T. B. Galushko, and V. I. Zolotarevskii, Polym. Sci., Ser. A 61, 491 (2019).

    Article  CAS  Google Scholar 

  21. G. M. Bartenev and V. A. Lomovskoi, Polym. Sci., Ser. A 44, 841 (2002).

    Google Scholar 

  22. V. A. Lomovskoi, Tonkie Khim. Tekhnol. 10 (3), 8 (2015).

    Google Scholar 

  23. A. S. Novick and B. S. Berry, Anelastic Relaxation in Crystalline Solids (Academic Press, New York; London, 1972).

    Google Scholar 

  24. D. S. Sanditov, J. Exp. Theor. Phys. 123, 429 (2016).

    Article  CAS  Google Scholar 

  25. D. S. Sanditov and M. I. Ojovan, Phys. -Usp. 62, 111 (2019).

    Article  CAS  Google Scholar 

  26. D. S. Sanditov, Dokl. Phys. Chem. 464, 255 (2015).

    Article  CAS  Google Scholar 

  27. I. V. Zolotukhin, Yu. E. Kalinin, and O. V. Stognei, New Directions in Physical Materials Science (Voronezhskii Gos. Univ., Voronezh, 2000) [in Russian].

    Google Scholar 

  28. D. S. Sanditov and A. A. Mashanov, Polym. Sci., Ser. A 61, 119 (2019).

    Article  CAS  Google Scholar 

  29. I. V. Zolotukhin and Yu. E. Kalinin, Fiz. Tverd. Tela 37, 536 (1995).

    CAS  Google Scholar 

  30. Y. E. Kalinin and B. M. Darinskii, Met. Sci. Heat Treat 54, 221 (2012).

    Article  CAS  Google Scholar 

  31. Chemical Bond Dissociation Energy: Ionizating Potential and Electron Affinity, Ed. by V. N. Kondrat’ev (Nauka; Inst. Khim. Fiz.; Inst. Vysokikh Temp., Moscow, 1974) [in Russian].

  32. R. A. De Souza, in Resistive Switching from Fundamentals of Nanoionic Redox Processes to Memristive Device Applications, Ed. by D. Ielmini and R. Waser (Wiley, Weinheim, 2016), p. 125.

    Google Scholar 

  33. A. Mehonic, A. J. Kenyon, A. L. Shluger, D. Gao, I. Valov, E. Miranda, D. Ielmini, A. Bricalli, E. Ambrosi, C. Li, J. J. Yang, and Q. Xia, Adv. Mater. 30, 1801187 (2018).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to V.V. Avdeev and A.V. Kepman for providing the initial components for the preparation of samples and useful discussions, and to A.I. Bocharov for performing experiments on a scanning electron microscope.

Funding

This study was financially supported by the Ministry of Science and Higher Education within the basic part of State assignment (project no. FZGM-2020-007).

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Authors and Affiliations

  1. Voronezh State Technical University, 394006, Voronezh, Russia

    Yu. E. Kalinin, O. V. Ovdak & I. I. Popov

  2. Joint Stock Company Rusaviainter, 394004, Voronezh, Russia

    A. M. Kudrin

Authors
  1. Yu. E. Kalinin
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  2. A. M. Kudrin
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  3. O. V. Ovdak
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  4. I. I. Popov
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Correspondence to Yu. E. Kalinin.

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Translated by O. Kadkin

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Kalinin, Y.E., Kudrin, A.M., Ovdak, O.V. et al. Internal Friction in an Epoxy Polymer and a Fiberglass Reinforced Plastic Based on It. Polym. Sci. Ser. A 64, 1–9 (2022). https://doi.org/10.1134/S0965545X22010047

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  • DOI: https://doi.org/10.1134/S0965545X22010047

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