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Thermally Stable Polypyrrole/Hematite Composites with Tunable Dielectric and Magnetic Properties

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Abstract

Polypyrrole/hematite magnetic composites are prepared by simple chemical oxidation method with different weight percentages of hematite (0–30 wt %) in polypyrrole (PPy) matrix during in situ polymerization of monomers. The as-synthesized composites are characterized by thermogravimetric analysis, differential scanning calorimetry, vibrating sample magnetometry analysis and dielectric studies. Thermal stability is improved in all the prepared composites. Enhanced AC conductivity and thermal stability in PPy/10% of hematite composite is attributed to the homogeneous dispersion of incorporated hematite particles in PPy matrix, physiochemical interactions and development of interface regions between organic polymer structure and inorganic hematite particles. Interestingly, the organic conducting polymer matrix reinforcement with inorganic hematite dispersive particles is found to transform it from weak antiferromagnetic to ferromagnetic in the range of 10 kOe with coercivity and saturation magnetization as a function of the inorganic phase loading percentage.

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Authors and Affiliations

  1. Centre of Excellence in Solid State Physics, University of the Punjab, 54590, Lahore, Pakistan

    Aisha Batool, Saira Riaz, Shahid Atiq, Shahzad Naseem & Zaka Ullah

  2. National Center for Nanoscience and Technology, University of Chinese Academy of Sciences, 100190, Beijing, China

    Aisha Batool

  3. Institute of Chemistry, University of the Punjab, 54590, Lahore, Pakistan

    Farah Kanwal & Muhammad Waheed Mushtaq

  4. Institute of Chemistry, Khwaja Fareed University of Engineering and Information Technology, 64200, Rahim Yar Khan, Pakistan

    Sumreen Asim

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  1. Aisha Batool
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  2. Farah Kanwal
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  3. Sumreen Asim
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Correspondence to Zaka Ullah.

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Aisha Batool, Kanwal, F., Asim, S. et al. Thermally Stable Polypyrrole/Hematite Composites with Tunable Dielectric and Magnetic Properties. Polym. Sci. Ser. A 61, 112–117 (2019). https://doi.org/10.1134/S0965545X19010024

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  • DOI: https://doi.org/10.1134/S0965545X19010024

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