Skip to main content
Log in

Contribution of surface rayleigh waves to the heat capacity of poly(vinyl chloride)

  • Structure, Properties
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

The method of surface acoustic waves is employed to determine the frequency and temperature dependences of the molar heat capacity of poly(vinyl chloride) on the contribution of Rayleigh local components of the longitudinal and transverse vibrations of structural units of the polymer. The calculated and experimental data are compared in terms of their dependence on the relaxation state of the system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. I. Perepechko, Acoustic Methods of Polymer Research (Khimiya, Moscow, 1973) [in Russian].

    Google Scholar 

  2. A. A. Darinskii, I. M. Neelov, N. K. Balabaev, and F. Sundholm, Polymer Science, Ser. A 40, 675 (1998) [Vysokomol. Soedin., Ser. A 40, 1110 (1998)].

    Google Scholar 

  3. S. Ya. Frenkel’, Macromolecule (Sovetskaya Entsiklopediya, Moscow, 1974) [in Russian].

    Google Scholar 

  4. V. L. Gurevich, Kinetics of Phonon Systems (Nauka, Moscow, 1987) [in Russian].

    Google Scholar 

  5. P. Painter, M. Coleman, and J. Koenig, Vibrational Spectroscopy and Its Application to Polymeric Materials (Wiley, New York, 1982; Mir, Moscow, 1985).

    Google Scholar 

  6. B. Wunderlich and G. Baur, Heat Capacities of Linear High Polymers (Springer, Heidelberg, 1970; Mir, Moscow, 1972).

    Google Scholar 

  7. A. D. Pirs, Akust. Zh. 51, 9 (2005).

    Google Scholar 

  8. P. S. Landa, Nonlinear Vibrations and Waves (Nauka, Moscow, 1997) [in Russian].

    Google Scholar 

  9. Physical Acoustics. Principles and Methods. Vol. II, Part B. Properties of Polymers and Nonlinear Acoustics, Ed. by W. P. Mason (Academic. New York, 1965; Mir, Moscow, 1969).

    Google Scholar 

  10. B. S. Kolupaev, in Relaxation and Thermal Properties of Filled Polymer Systems, Ed. by S. Ya. Frenkel’ (Vyshcha Shkola, Lvov, 1980) [in Russian].

    Google Scholar 

  11. A. Rubcic and G. Zerbi, Macromolecules 6, 759 (1974).

    Article  Google Scholar 

  12. V. V. Klepko, B. B. Kolupaev, and E. V. Lebedev, J. Polym. Sci., Part B: Polym. Phys. 49, 18 (2007).

    Google Scholar 

  13. B. Wunderlich, Thermal Analysis of Polymeric Materials (Springer, Berlin, 2005), p. 239.

    Google Scholar 

  14. A. B. Kruglov and V. S. Kharitonov, Vestn. Mezhdunar. Akad. Kholoda, No. 3, 20 (2006).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. B. Kolupaev.

Additional information

Original Russian Text © V.V. Klepko, B.B. Kolupaev, E.V. Lebedev, V.A. Mashchenko, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 9, pp. 1610–1614.

This work was supported by the Foundation for Basic Research of the Ministry of Education and Science of Ukraine (project no. 0106U000490).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klepko, V.V., Kolupaev, B.B., Lebedev, E.V. et al. Contribution of surface rayleigh waves to the heat capacity of poly(vinyl chloride). Polym. Sci. Ser. A 51, 986–990 (2009). https://doi.org/10.1134/S0965545X09090041

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X09090041

Keywords

Navigation