Skip to main content
SpringerLink
Log in

Structure of the interfacial layer and properties of crosslinked heterophase blends based on butadiene-nitrile and ethylene-propylene-diene elastomers

  • Structure, Properties
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

The density of the interfacial layer and the number of formed crosslinks have been estimated by means of swelling in selective solvents for heterophase blends of butadiene and ethylene-propylene elastomers. Ethylene-propylene-diene elastomers are characterized by an increased content of ethylene units and diene groups, a higher degree of isotacticity of propylene chain fragments, and a higher Mooney viscosity at low stereoregularity of the propylene units. The effects of the above parameters on the interfacial interaction and the kinetics of ozone degradation of the diene matrix have been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. M. Livanova, Polymer Science, Ser. A 48, 821 (2006) [Vysokomol. Soedin., Ser. A 48, 1424 (2006)].

    Article  Google Scholar 

  2. Multicomponent Polymer Systems, Ed. by R. F. Gould (American Chemical Society, Washington, 1970; Khimiya, Moscow, 1974).

    Google Scholar 

  3. Yu. N. Lednev, N. D. Zakharov, O. A. Zakharkin, et al., Kolloidn. Zh. 39, 170 (1977).

    CAS  Google Scholar 

  4. Yu. V. Kissin, V. I. Tsvetkova, and N. M. Chirkov, Dokl. Akad. Nauk SSSR 152, 1162 (1963).

    CAS  Google Scholar 

  5. Yu. V. Kissin, I. T. Popov, D. M. Lisitsin, et al., Proizvod. Shin Rezino-Tekh. Asbesto-Tekh. Izdelii, No. 7, 22 (1966).

  6. J. Dechant, R. Danz, W. Kimmer and R. Schmolke, Ultrarotspektroskopische Untersuchungen an Polymeren (Akademie, Berlin, 1972; Khimiya, Moscow, 1976).

    Google Scholar 

  7. N. V. Kozlova, F. F. Sukhov, and V. P. Bazov, Zavod. Lab. 31, 968 (1965).

    CAS  Google Scholar 

  8. N. M. Livanova, Yu. I. Lyakin, A. A. Popov, and V. A. Shershnev, Kauch. Rezina, No. 4, 2 (2006).

  9. V. A. Shershnev, V. D. Yulovskaya, N. V. Lyamkina, et al., Polymer Science, Ser. A 41, 315 (1999) [Vysokomol. Soedin., Ser. A 41, 462 (1999)].

    Google Scholar 

  10. V. N. Kuleznev, Polymer Blends (Khimiya, Moscow, 1980) [in Russian].

    Google Scholar 

  11. S. V. Orekhov, N. D. Zakharov, V. N. Kuleznev, and B. A. Dogadkin, Kolloidn. Zh. 32, 245 (1970).

    CAS  Google Scholar 

  12. S. S. Voyutskii and V. L. Vakula, Mekh. Polim. 3, 455 (1969).

    Google Scholar 

  13. B. S. Grishin, I. A. Tutorskii, and I. S. Yurovskaya, Vysokomol. Soedin., Ser. A 20, 1967 (1978).

    CAS  Google Scholar 

  14. L. V. Sokolova, O. A. Konovalova, and V. A. Shershnev, Kolloidn. Zh. 44, 716 (1982).

    CAS  Google Scholar 

  15. The Stereo Rubbers, Ed. by W. M. Saltman (Wiley, New York, 1979), Vol. 2.

    Google Scholar 

  16. A. E. Nesterov, Handbook on Physical Chemistry of Polymers (Naukova Dumka, Kiev, 1984) [in Russian].

    Google Scholar 

  17. B. E. Krisyuk, A. A. Popov, N. M. Livanova, and M. P. Farmakovskaya, Polymer Science, Ser. A 41, 94 (1999) [Vysokomol. Soedin., Ser. A 41, 102 (1999)].

    Google Scholar 

  18. N. M. Livanova, A. A. Popov, S. G. Karpova, et al., Polymer Science, Ser. A 44, 59 (2002) [Vysokomol. Soedin., Ser. A 44, 71 (2002)].

    Google Scholar 

  19. S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

  20. N. M. Livanova, A. A. Popov, V. A. Shershnev, and V. D. Yulovskaya, Polymer Science, Ser. A 45, 436 (2003) [Vysokomol. Soedin., Ser. A 45, 742 (2003)].

    Google Scholar 

  21. N. M. Livanova, Yu. I. Lyakin, A. A. Popov, and V. A. Shershnev, Polymer Science, Ser. A 49, 63 (2007) [Vysokomol. Soedin., Ser. A 49, 79 (2002)].

    Article  Google Scholar 

  22. M. V. Vol’kenshtein, Configurational Statistics of Polymer Chains (Akad. Nauk SSSR, Moscow, 1959) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    N. M. Livanova & A. A. Popov

  2. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    Yu. I. Lyakin & V. A. Shershnev

Authors
  1. N. M. Livanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. I. Lyakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Shershnev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © N.M. Livanova, Yu.I. Lyakin, A.A. Popov, V.A. Shershnev, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2007, Vol. 49, No. 3, pp. 465–472.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Livanova, N.M., Lyakin, Y.I., Popov, A.A. et al. Structure of the interfacial layer and properties of crosslinked heterophase blends based on butadiene-nitrile and ethylene-propylene-diene elastomers. Polym. Sci. Ser. A 49, 300–306 (2007). https://doi.org/10.1134/S0965545X07030108

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X07030108

Keywords

Search

Navigation