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Poly(siloxane carbonates) based on siloxane-containing bisphenols

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Abstract

Effects of the synthesis conditions and other factors on the formation of copolymers with random or block microstructures through the low-temperature homogeneous and heterophase copolycondensation of bisphenol A bis(chloroformate) with mixtures of α,ω-bis(4-hydroxy-3-methoxyphenylpropyl)oligodimethylsiloxanes and organic bisphenols have been considered. Several new poly(siloxane carbonates) have been synthesized and characterized; for copolymers with different chemical compositions and structures, molecularmass and thermal and mechanical characteristics have been compared.

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Authors and Affiliations

  1. OOO Penta-91, Pervaya Dubrovskaya ul. 1/1, Moscow, 109044, Russia

    I. M. Raigorodskii & A. G. Grigor’ev

  2. State Scientific Center of the Russian Federation, Federal State Unitary Enterprise, State Research Institute of Chemistry and Technology of Organoelement Compounds, sh. Entuziastov 38, Moscow, 111123, Russia

    V. L. Ivanova, V. M. Kopylov, M. V. Zheneva & A. M. Savitskii

  3. Petrov Plastics Institute, Perovskii pr. 35, Moscow, 111112, Russia

    Ya. G. Urman

  4. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    V. V. Kireev

Authors
  1. I. M. Raigorodskii
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  2. V. L. Ivanova
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  3. Ya. G. Urman
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  4. V. M. Kopylov
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  5. V. V. Kireev
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  6. M. V. Zheneva
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  7. A. G. Grigor’ev
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  8. A. M. Savitskii
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Additional information

Original Russian Text © I.M. Raigorodskii, V.L. Ivanova, Ya.G. Urman, V.M. Kopylov, V.V. Kireev, M.V. Zheneva, A.G. Grigor’ev, A.M. Savitskii, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 7, pp. 1058–1065.

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Raigorodskii, I.M., Ivanova, V.L., Urman, Y.G. et al. Poly(siloxane carbonates) based on siloxane-containing bisphenols. Polym. Sci. Ser. A 48, 676–682 (2006). https://doi.org/10.1134/S0965545X06070029

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  • DOI: https://doi.org/10.1134/S0965545X06070029

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