Abstract
New copolymers of norbornene and 1,5-bis(hexenyl-5)-1,1,3,3,5,5-hexamethyltrisiloxane containing flexible siloxane and rigid norbornene fragments in the main chain are synthesized. Synthesis is carried out using three types of olefin metathesis reactions: the ring-opening metathesis polymerization of norbornene, the metathesis of nonconjugated diene 1,5-bis(hexenyl-5)-1,1,3,3,5,5-hexamethyltrisiloxane, and the interchain macromolecular cross-metathesis between polynorbornene and siloxane-containing polyene. The latter reaction is studied for the first time. With its help, new statistical multiblock copolymers of norbornene and 1,5-bis(hexenyl-5)-1,1,3,3,5,5-hexamethyltrisiloxane with different average block lengths are obtained and characterized by 1H and 13C NMR and IR spectroscopy. The effect of the copolymer structure on their thermal properties is investigated.
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ACKNOWLEDGMENTS
We are grateful to R.S. Borisov for GC-MS analyses, G.A. Shandryuk for calorimetric measurements, and S.A. Legkov for taking IR spectra (all from the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences), as well as A.S. Peregudov (Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences) for recording 13C NMR spectra.
The structure of the obtained compounds was studied using the equipment of the Shared Research Center of the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, and Center for Molecule Structure Studies of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
Funding
Synthesis of initial homopolymers and siloxane-containing copolymers of norbornene was supported by the Russian Foundation for Basic Research (project no. 18-33-00961-mol-a). The rest of the research was carried out within the framework of the State Program for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.
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Morontsev, A.A., Gringolts, M.L., Filatova, M.P. et al. Synthesis of New of Norbornene–1,5-Bis(hexenyl)hexamethyltrisiloxane Copolymers via Olefin Metathesis Reaction. Polym. Sci. Ser. B 62, 638–648 (2020). https://doi.org/10.1134/S1560090420060093
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DOI: https://doi.org/10.1134/S1560090420060093