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Synthesis of Granular MCM-22 Zeolite with a Hierarchical Porous Structure

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Abstract

The study proposes a novel approach for the synthesis of granular MCM-22 zeolite with a hierarchical micro–meso–macroporous structure. This approach is based on the crystallization of zeolite granules consisting of powdered MCM-22 and synthetic amorphous aluminosilicate. The synthesized material had 97% crystallinity and volumes of micro-, meso-, and macropores of 0.18, 0.22, and 0.46 cm3/g, respectively. The H-form of the hierarchical MCM-22 exhibited high activity and selectivity in dimerization of α-methylstyrene.

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Funding

This work was performed within the State Program of the Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences (IPC UFRC RAS, project no. FMRS-2022-0080). The structural investigation was carried out at the Agidel Regional Center for Collective Use of UFRC RAS within the State Program of IPC UFRC RAS (project no. FMRS-2022-0081).

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, Ufa, 450062, Republic of Bashkortostan, Russia

    E. D. Zhirnova

  2. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450075, Republic of Bashkortostan, Russia

    O. S. Travkina

Authors
  1. E. D. Zhirnova
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  2. O. S. Travkina
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Correspondence to O. S. Travkina.

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Zhirnova, E.D., Travkina, O.S. Synthesis of Granular MCM-22 Zeolite with a Hierarchical Porous Structure. Pet. Chem. (2024). https://doi.org/10.1134/S0965544124020129

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