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Composition of Hydrocarbon Gases Formed by Dry Pysolysis of Domanik Shale Kerogen after Hydrothermal Experiment

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Abstract

The composition of hydrocarbon gases formed by pyrolysis of residual Domanik shale kerogen at 800°C, preceded by hydrothermal treatment at 250–375°С, was studied by pyrolytic gas chromatography. Starting from the autoclave temperature of 320–325°C, the hydrothermal treatment of the shale affects the kerogen structures responsible for the formation of C2+ gases in pyrolysis at 800°C. An increase in the temperature of the shale hydrothermal treatment leads to a monotonic increase in the С1/С2+ ratio in the products of the residual kerogen pyrolysis at 800°C. The methane yield at 800°C does not correlate with the content of alkyl structures, determined in kerogen by IR spectroscopy, and the yield of С2+ gases linearly correlates with the content of alkyl structures.

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REFERENCES

  1. Galimov, E.M., Chem. Geol., 1988, vol. 71, nos. 1–3, pp. 77–95. https://doi.org/10.1016/0009-2541(88)90107-6

    Article  ADS  CAS  Google Scholar 

  2. Behar, F., Vandenbroucke, M., Teerman, S.C., Hatcher, P.G., Leblond, C., and Lerat, O., Chem. Geol., 1995, vol. 126, nos. 3–4, pp. 247–260. https://doi.org/10.1016/0009-2541(95)00121-2

    Article  ADS  CAS  Google Scholar 

  3. İnan, S., Org. Geochem., 2000, vol. 31, no. 12, pp. 1409–1418. https://doi.org/10.1016/S0146-6380(00)00070-X

    Article  ADS  Google Scholar 

  4. Lewan, M.D., Orgаnic Geochemistry, Engler, M.H. and Macko, S.A., Eds., New York: Plenum, 1993, pp. 419–442.

  5. Stalker, L., Larter, S.R., and Farrimond, P., Org. Geochem., 1998, vol. 28, nos. 3–4, pp. 239–253. https://doi.org/10.1016/S0146-6380(97)00103-4

    Article  ADS  CAS  Google Scholar 

  6. Koopmans, M.P., Carson, F.C., Sinninghe Damsté, J.S., and Lewan, M.D., Org. Geochem., 1998, vol. 29, nos. 5–7, pp. 1395–1402. https://doi.org/10.1016/S0146-6380(98)00187-9

    Article  ADS  CAS  Google Scholar 

  7. Behar, F., Roy, S., and Jarvie, D., Org. Geochem., 2010, vol. 41, pp. 1235–1247.

    Article  ADS  CAS  Google Scholar 

  8. Bushnev, D.A., Burdel’naya, N.S., Shanina, S.N., and Makarova, E.S., Petrol. Chem., 2004, vol. 44, no. 6, pp. 416–425.

    Google Scholar 

  9. Melenevsky, V.N., Kontorovich, A.E., Huang, W.-L., Larichev, A.I., Bul’bak, T.A., Geochem. Int., 2009, vol. 47, no. 5, pp. 476–484.

    Article  Google Scholar 

  10. Bushnev, D.A. and Burdel’naya, N.S., Petrol. Chem., 2013, vol. 53, no. 3, pp. 145–151. https://doi.org/10.1134/S096554411303002X

    Article  CAS  Google Scholar 

  11. Bushnev, D.A. and Burdel’naya, N.S., Petrol. Chem., 2015, vol. 55, no. 7, pp. 522–529. https://doi.org/10.1134/S0965544115070038

    Article  CAS  Google Scholar 

  12. Kotarba, M.J. and Lewan, M.D., Chem. Geol., 2013, vol. 345, pp. 62–76. https://doi.org/10.1016/j.chemgeo.2013.02.023

    Article  ADS  CAS  Google Scholar 

  13. Bychkov, A.Yu., Kalmykov, G.A., Bugaev, I.A., Kalmykov, A.G., and Kozlova, E.V., Moscow Univ. Geol. Bull., 2015, vol. 70, no. 4, pp. 299–304.

    Article  ADS  Google Scholar 

  14. Bushnev, D.A., Burdelnaya, N.S., and Mokeev, M.V., Geochem. Int., 2019, vol. 57, no. 11, pp. 1173–1184. https://doi.org/10.1134/S0016702919110028

    Article  CAS  Google Scholar 

  15. Burdelnaya, N., Bushnev, D., Mokeev, M., and Dobrodumov, A., Fuel, 2014, vol. 118, pp. 308–314. https://doi.org/10.1016/j.fuel.2013.11.003

    Article  CAS  Google Scholar 

  16. Mukhina, T.N., Barabanov, N.L., and Babash, S.E., Piroliz uglevodorodnogo syr’ya (Pyrolysis of Hydrocarbon Raw Materials), Moscow: Khimiya, 1987.

  17. Savage, P.E., J. Anal. Appl. Pyrol., 2000, vol. 54, pp. 109–126. https://doi.org/10.1016/S0165-2370(99)00084-4

    Article  CAS  Google Scholar 

  18. Liu, J., Jiang, X., Shen, J., and Zhang, H., Energy Convers. Manag., 2014, vol. 87, pp. 1027–1038. https://doi.org/10.1016/j.enconman.2014.07.053

    Article  CAS  Google Scholar 

  19. Zhang, L., Qi, S., Takeda, N., Kudo, S., Hayashi, J., and Norinaga, K., Int. J. Coal Sci. Technol., 2018, vol. 5, pp. 452–463. https://doi.org/10.1007/s40789-017-0175-0

    Article  CAS  Google Scholar 

  20. Hodek, W., Kirschstein, J., and van Heek, K.H., Fuel, 1991, vol. 70, pp. 424–428. https://doi.org/10.1016/0016-2361(91)90133-U

    Article  CAS  Google Scholar 

  21. Holstein, A., Bassilakis, R., Wójtowicz, M.A., and Serio, M.A., Proc. Combust. Inst., 2005, vol. 30, pp. 2177–2185. https://doi.org/10.1016/j.proci.2004.08.231

    Article  CAS  Google Scholar 

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Funding

The study was financially supported by the Russian Science Foundation (project no. 23-27-00139: Study of the process of hydrocarbon gases formation by Domanik kerogen during the simulation of its thermal maturation in a hydrothermal experiment and dry pyrolysis.

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Authors and Affiliations

  1. Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Komi Republic, 167982, Syktyvkar, Russia

    D. A. Bushnev, N. S. Burdelnaya, A. A. Ilchenko & Ya. D. Sennikova

  2. Pitirim Sorokin Syktyvkar State University, Komi Republic, 167001, Syktyvkar, Russia

    Ya. D. Sennikova

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  1. D. A. Bushnev
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  2. N. S. Burdelnaya
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  3. A. A. Ilchenko
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  4. Ya. D. Sennikova
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Correspondence to D. A. Bushnev.

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Bushnev, D.A., Burdelnaya, N.S., Ilchenko, A.A. et al. Composition of Hydrocarbon Gases Formed by Dry Pysolysis of Domanik Shale Kerogen after Hydrothermal Experiment. Pet. Chem. 63, 1054–1060 (2023). https://doi.org/10.1134/S0965544123080017

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  • DOI: https://doi.org/10.1134/S0965544123080017

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