Abstract
The study investigates the catalytic performance of microporous (H–Y) and micro–meso–macroporous (H–Yh, Fe2O3/H–Yh, PbO/H–Yh, and La–H–Yh ) FAU-type zeolites in the condensation of acetone with ammonia. In the presence of H–Yh, Fe2O3/H–Yh, and La–H–Yh, 2,4,6-trimethylpyridine was synthesized with selectivity of 54%, 58%, and 24%, respectively. In the presence of H–Y and PbO/H–Yh, the predominant reaction was acetone condensation, with the reaction products mostly consisting of diacetone alcohol and mesityl oxide.
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Funding
This work was performed within the State Program of IPC UFRC RAS (project no. FMRS-2022-0080). The structural investigation was carried out at the Agidel Regional Center for Collective Use of UFRC RAS within the State Program of IPC UFRC RAS (project no. FMRS-2022-0081).
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Grigor’eva, N.G., Filippova, N.A., Bubennov, S.V. et al. Catalytic Performance of Microporous and Hierarchical Zeolites in Condensation of Acetone with Ammonia. Pet. Chem. 62, 942–949 (2022). https://doi.org/10.1134/S0965544122070131
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DOI: https://doi.org/10.1134/S0965544122070131