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Synthesis of Fatty Alcohol based Sterically Hindered Esters as Potential Antioxidants for Bioadditives

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Abstract

Four hindered phenolic esters were prepared by esterification between 3-(3,5-Di-tert-butyl-hydroxyphenyl)propionic acid and fatty alcohols. The synthesized esters were characterised by NMR, IR and ESI-MS and analysed for their antioxidant properties and thermal stability. Differential scanning calorimetry (DSC) and Rancimat studies were conducted to explore the effect of synthesized compounds on oxidation stability of base oil. The results from both the studies were correlated well. Thermogravimetric analysis indicates that all the esters have significantly high thermal stability. Among all the prepared compounds myristyl alcohol ester showed better antioxidant properties whereas, stearyl alcohol ester exhibited higher thermal stability. The synthesized antioxidants can be potential bio additives for lubricant formulations.

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Funding

Venkateshwarlu Kontham thanks the University Grants Commission (UGC), New Delhi, India, for financial support through a Senior Research Fellowship (SRF). Manuscript Communication Number: IICT/Pubs./2019/129.

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Authors and Affiliations

  1. Centre for Lipid Science and Technology, CSIR-Indian Institute of Chemical Technology, 500007, Hyderabad, Telangana, India

    Venkateshwarlu Kontham, Korlipara V. Padmaja & Devarapaga Madhu

  2. Academy of Scientific and Innovative Research, New Delhi, India

    Venkateshwarlu Kontham & Korlipara V. Padmaja

  3. Department of Chemistry, Indian Institute of Technology (BHU) Varanasi, 221005, Varanasi, India

    Devarapaga Madhu

Authors
  1. Venkateshwarlu Kontham
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  2. Korlipara V. Padmaja
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  3. Devarapaga Madhu
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Correspondence to Korlipara V. Padmaja or Devarapaga Madhu.

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CONFLICT OF INTEREST

The authors declare no conflict of interest to this work.

ADDITIONAL INFORMATION

Venkateshwarlu Kontham; ORCID: 0000-0001-9437-5628

Korlipara V. Padmaja; ORCID: 0000-0002-8014-2361

Devarapaga Madhu; ORCID: 0000-0002-6448-0619

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Venkateshwarlu Kontham, Padmaja, K.V. & Madhu, D. Synthesis of Fatty Alcohol based Sterically Hindered Esters as Potential Antioxidants for Bioadditives. Pet. Chem. 60, 1309–1316 (2020). https://doi.org/10.1134/S0965544120110110

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  • DOI: https://doi.org/10.1134/S0965544120110110

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