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Effect of Zeolite on Fischer–Tropsch Synthesis in the Presence of a Catalyst Based on Skeletal Cobalt

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Abstract

The joint effect of skeletal cobalt and zeolite on the main catalytic parameters of a pelletized composite catalyst has been studied. All samples contain 50 wt % fine metallic aluminum powder. The amounts of other components are as follows: 20–30 wt % binder (boehmite), 5–20 wt % Beta zeolite in the H form (SiO2/Al2O3 = 38), and 10–20 wt % fine skeletal cobalt. The reference catalyst does not contain any zeolite. All the catalysts exhibit activity in Fischer–Tropsch synthesis and secondary transformations, the intensity of which depends on the zeolite/cobalt ratio. The composition of the resulting hydrocarbons (HCs) varies over a wide range; in particular, the content of n-paraffins and olefins is 39–88 and 3–38%, respectively. The chain growth probability varies in a range of 0.65–0.83 depending on the zeolite/cobalt ratio and the synthesis conditions. It has been shown that the catalysts studied are superior advantage to other cobalt–zeolite catalysts in CO conversion, specific activity, productivity, and stability.

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Funding

This work was supported in accordance with a state task to Technological Institute for Superhard and Novel Carbon Materials.

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Authors and Affiliations

  1. Technological Institute for Superhard and Novel Carbon Materials, 108840, Troitsk, Moscow, Russia

    E. Yu. Asalieva, E. V. Kul’chakovskaya, L. V. Sineva & V. Z. Mordkovich

  2. INFRA Tekhnologii, 125009, Moscow, Russia

    L. V. Sineva & V. Z. Mordkovich

Authors
  1. E. Yu. Asalieva
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  2. E. V. Kul’chakovskaya
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  3. L. V. Sineva
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  4. V. Z. Mordkovich
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Correspondence to E. Yu. Asalieva.

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Translated by M. Timoshinina

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Asalieva, E.Y., Kul’chakovskaya, E.V., Sineva, L.V. et al. Effect of Zeolite on Fischer–Tropsch Synthesis in the Presence of a Catalyst Based on Skeletal Cobalt. Pet. Chem. 60, 69–74 (2020). https://doi.org/10.1134/S0965544120010028

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  • DOI: https://doi.org/10.1134/S0965544120010028

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