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Effects of Zeolite Type on Integrated Fischer–Tropsch Synthesis and Hydroprocessing

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A number of bifunctional composite cobalt-based catalysts were prepared with various types of molecular sieves in the H-form (zeolites ZSM-5, Y, Beta, and Mordernite, and silicoaluminophosphate SAPO-11) as an acid component. The catalytic performance of these catalysts was comparatively assessed in integrated Fischer-Tropsch synthesis of fuels. The catalysts were found to exhibit high activity and high C5+ selectivity at 2.0 MPa, 240–250°C, and a gas hourly space velocity (WHSV) of 1000 h–1. With the CO conversion reaching 80.9–93.7%, the productivity was in the range of 146.4 kg/(m3cat h). The study further revealed the effects of the crystalline and porous structures of the molecular sieves on the hydrocarbon and fractional compositions of the fuel products and on the selectivity towards branched hydrocarbons. It was shown that catalysts based on HZSM-5 and HBeta zeolites are preferable for high-performance and selective synthesis of fuels. In the presence of the HZSM-5-based catalyst, an effect atypical of Fischer–Tropsch synthesis was observed for the first time: an elevation of the process temperature leads to an enhancement of C5+ selectivity.

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Funding

This study was carried out with financial support from the Ministry of Sciences and Higher Education of the Russian Federation within the state assignment (project no. 2019-0990), using equipment of the Nanotechnology Center for Collective Use, South Russian State Polytechnic University.

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Authors and Affiliations

  1. Platov South Russian State Polytechnic University, 346428, Novocherkassk, Russia

    R. E. Yakovenko, V. G. Bakun, S. I. Sulima, I. N. Zubkov, V. V. Pyatikonova, E. A. Bozhenko & A. P. Savost’yanov

  2. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences (IPC RAS), 450075, Ufa, Russia

    M. R. Agliullin

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  1. R. E. Yakovenko
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  2. V. G. Bakun
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  4. S. I. Sulima
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  5. I. N. Zubkov
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  6. V. V. Pyatikonova
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  8. A. P. Savost’yanov
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Correspondence to S. I. Sulima.

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Yakovenko, R.E., Bakun, V.G., Agliullin, M.R. et al. Effects of Zeolite Type on Integrated Fischer–Tropsch Synthesis and Hydroprocessing. Pet. Chem. 62, 950–961 (2022). https://doi.org/10.1134/S0965544122070209

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