Petroleum Chemistry

, Volume 57, Issue 12, pp 1161–1164 | Cite as

Hydrotreating of Vacuum Gas Oil on NiW/Al2O3 Catalysts Prepared with the Use of Chelating Agents

  • P. P. Minaev
  • M. S. Nikulshina
  • L. A. Gulyaeva
  • O. L. Ovsienko
  • V. A. Khavkin
  • O. I. Shmel’kova
  • P. A. NikulshinEmail author


Alumina-based NiW catalysts have been prepared from 12-phosphotungstic heteropoly acid (PW12HPA), ammonium metatungstate (NH4)6H2[W12O40], and nickel hydroxide carbonate or nickel nitrate using citric acid (CA) or ethylenediaminetetraacetic acid (EDTA) as a chelating agent. The obtained samples have been studied by N2 adsorption, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy techniques. The catalysts obtained using the PW12HPA and CA have been characterized by the greatest dispersion of active-phase particles, and the use of EDTA has provided the maximum proportion of NiWS. The hydrodesulfurizing activity of catalysts in the hydrotreating of vacuum gas oil has been found to decrease in the following order: Ni-CAPW/Al2O3 > Ni-CAW/Al2O3 > Ni-EDTA-W/Al2O3 > Ni-W/Al2O3, which in general correlates with the particle size of the active phase and the concentration of promoted active sites.


hydrotreating vacuum gas oil NiW/Al2O3 NiWS citric acid EDTA NiWSN 


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  1. 1.
    V. M. Kogan, P. A. Nikul’shin, V. S. Dorokhov, et al., Izv. Akad. Nauk, Ser. Khim., No. 2, 332 (2014).Google Scholar
  2. 2.
    H. Topsøe, Appl. Catal., A 322, 3 (2007).CrossRefGoogle Scholar
  3. 3.
    Y. van der Meer, M. J. Vissenberg, V. H. J. de Beer, et al.,Industrial Applications of the Mössbauer Effect: Proceedings of ISIAME 2000 Held in Virginia Beach, USA, 13–18 August 2000, Ed. by D. C. Cook and G. R. Hoy (Springer, Dordrecht, 2002), p. 51.CrossRefGoogle Scholar
  4. 4.
    A. A. Pimerzin, N. N. Tomina, P. A. Nikul’shin, et al., Catal. Ind. 7, 30 (2015).CrossRefGoogle Scholar
  5. 5.
    P. Nikulshin, A. Mozhaev, C. Lancelot, et al., C. R. Chim. 19, 1276 (2016).CrossRefGoogle Scholar
  6. 6.
    A. Pimerzin, A. Mozhaev, A. Varakin, K. et al., Appl. Catal., B 205, 93 (2017).CrossRefGoogle Scholar
  7. 7.
    L. Coulier, V. H. J. de Beer, J. A. R. van Veen, and J. W. Niemantsverdriet, J. Catal. 197, 26 (2001).CrossRefGoogle Scholar
  8. 8.
    M. A. Lélias, J. van Gestel, F. Maugé, and J. A. R. van Veen, Catal. Today 130, 109 (2008).CrossRefGoogle Scholar
  9. 9.
    T. Fujikawa, M. Kato, H. Kimura, et al., J. Jpn. Pet. Inst. 48, 106 (2005).CrossRefGoogle Scholar
  10. 10.
    Y. Yoshimura, T. Sato, H. Shimada, et al., Catal. Today 29, 221 (1996).CrossRefGoogle Scholar
  11. 11.
    Y. Yoshimura, N. Matsubayashi, T. Sato, et al., Appl. Catal., A 79, 145 (1991).CrossRefGoogle Scholar
  12. 12.
    M. Breysse, M. Cattenot, T. Decamp, et al., Catal. Today 4, 39 (1988).CrossRefGoogle Scholar
  13. 13.
    B. Scheffer, J. Catal. 121, 18 (1990).CrossRefGoogle Scholar
  14. 14.
    M. J. Vissenberg, Y. van der Meer, E. J. M. Hensen, et al., J. Catal. 198, 151 (2001).CrossRefGoogle Scholar
  15. 15.
    L. Pena, D. Valencia, and T. Klimova, Appl. Catal., B 147, 879 (2014).CrossRefGoogle Scholar
  16. 16.
    G. Kishan, L. Coulier, V. H. J. de Beer, et al., J. Catal. 196, 180 (2000).CrossRefGoogle Scholar
  17. 17.
    P. P. Minaev, P. A. Nikulshin, M. S. Kulikova, et al., Appl. Catal., A 505, 456 (2015).CrossRefGoogle Scholar
  18. 18.
    P. A. Nikulshin, P. P. Minaev, A. V. Mozhaev, et al., Appl. Catal., B 176, 374 (2015).CrossRefGoogle Scholar
  19. 19.
    Y. Ohta, T. Shimizu, T. Honma, and M. Yamada, Stud. Surf. Sci. Catal. 127, 161 (1999).CrossRefGoogle Scholar
  20. 20.
    T. Shimizu, K. Hiroshima, T. Honma, et al., Catal. Today 45, 271 (1998).CrossRefGoogle Scholar
  21. 21.
    P. P. Minaev, A. S. Koklyukhin, K. I. Maslakov, and P. A. Nikulshin, Catal. Ind. 9, 146 (2017).CrossRefGoogle Scholar
  22. 22.
    A. N. Startsev, Hydrotreating Sulfide Catalysts: Synthesis, Structure, and Properties (Geo, Novosibirsk, 2008) [in Russian].Google Scholar
  23. 23.
    P. A. Nikulshin, D. I. Ishutenko, A. A. Mozhaev, et al., J. Catal. 312, 152 (2014).CrossRefGoogle Scholar
  24. 24.
    R. Cattaneo, T. Shido, and R. Prins, J. Catal. 185, 199 (1999).CrossRefGoogle Scholar
  25. 25.
    M. A. Lelias, E. Le Guludec, L. Mariey, et al., Catal. Today 150, 179 (2010).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • P. P. Minaev
    • 1
  • M. S. Nikulshina
    • 1
  • L. A. Gulyaeva
    • 2
  • O. L. Ovsienko
    • 2
  • V. A. Khavkin
    • 2
  • O. I. Shmel’kova
    • 2
  • P. A. Nikulshin
    • 1
    • 2
    Email author
  1. 1.Samara State Technical UniversitySamaraRussia
  2. 2.All-Russia Research Institute for Oil RefiningMoscowRussia

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