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Study of methanol steam reforming and ethanol conversion in conventional and membrane reactors

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Abstract

Research results for methanol steam reforming and ethanol conversion in a conventional and a membrane reactor in the presence of Ru–Rh/DND, LiZr2(PO4)3, and Li1.1Zr1.9In0.1(PO4)3 catalysts have been described. The samples have been characterized by X-ray diffraction, scanning electron microscopy, and the BET method. The study of the catalytic properties of the catalyst composites has shown that the Ru–Rh/DND catalyst mostly mediates the dehydrogenation process, while LiZr2(PO4)3 and Li1.1Zr1.9In0.1(PO4)3 exhibit activity in both the dehydration and dehydrogenation reactions. The membrane process with a Pd–Ru alloy membrane provides a 20% increase in the hydrogen yield.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. A. Lytkina, A. B. Ilin & A. B. Yaroslavtsev

Authors
  1. A. A. Lytkina
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  2. A. B. Ilin
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  3. A. B. Yaroslavtsev
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Correspondence to A. A. Lytkina.

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Original Russian Text © A.A. Lytkina, A.B. Ilin, A.B. Yaroslavtsev, 2016, published in Membrany i Membrannye Tekhnologii, 2016, Vol. 6, No. 4, pp. 397–405.

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Lytkina, A.A., Ilin, A.B. & Yaroslavtsev, A.B. Study of methanol steam reforming and ethanol conversion in conventional and membrane reactors. Pet. Chem. 56, 1048–1055 (2016). https://doi.org/10.1134/S0965544116110104

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