Abstract
The oligomerization of higher α-olefins over a set of heterogeneous mesoporous catalysts has been studied using the example of decene-1. It has been shown that mesoporous catalysts based on the sulfonated, perfluorinated copolymer F-4SF exhibit high activity in oligomerization of decene-1 in both a batch reactor and a flow system: in the former case, the olefin conversion reaches 95–99% with the yield of dimers of 90–95%; in the latter case, the conversion of decene-1 to oligomers exceeds 70%.
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Original Russian Text © A.L. Maksimov, A.B. Kulikov, A.A. Pugacheva, A.S. Vilesov, M.B. Smirnov, E.V. Galkina, D.M. Reshetnikov, A.A. Zvinchuk, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 2, pp. 122–130.
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Maksimov, A.L., Kulikov, A.B., Pugacheva, A.A. et al. Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer. Pet. Chem. 54, 120–127 (2014). https://doi.org/10.1134/S0965544114020066
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DOI: https://doi.org/10.1134/S0965544114020066