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Recent Advances in Catalysis Over Mesoporous Molecular Sieves

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Abstract

This overview covers the recent achievements in the application of mesoporous molecular sieves as catalysts and catalyst supports. Main structural and textural features are outlined in relation to the novel synthesis approaches of mesoporous molecular sieves and understanding of their properties. For application of mesoporous molecular sieves as catalysts different ways of introduction of active sites on their surfaces are provided. The main part describes selected catalytic reactions catalyzed by mesoporous molecular sieves focused on very recent papers. The examples include metathesis, acylation reactions, C–C coupling reactions of Heck and Suzuki types, base-catalyzed reactions (Knoevenagel and Michael additions, Claisen-Schmidt condensation, Tischenko reaction) and last but not least immobilization of organometallic complexes for different catalytic applications including chiral catalysts.

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Acknowledgements

The work of R.M.M.A. has been the supported by Spanish Ministerio de Educación y Ciencia (project MAT2007-66439-C02-01) while J.Č. was financially supported by the Academy of Sciences of the Czech Republic (KAN100400701), the Grant Agency of the Academy of Sciences of the Czech Republic (IAA400400805) and the Grant Agency of the Czech Republic (104/09/0561).

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Authors and Affiliations

  1. Departamento de Química Inorgánica y Química Técnica, Facultad de Ciencias, UNED, Paseo Senda del Rey 9, 28040, Madrid, Spain

    Rosa M. Martín-Aranda

  2. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 3, 182 23, Prague 8, Czech Republic

    Jiří Čejka

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  1. Rosa M. Martín-Aranda
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  2. Jiří Čejka
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Correspondence to Rosa M. Martín-Aranda or Jiří Čejka.

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Martín-Aranda, R.M., Čejka, J. Recent Advances in Catalysis Over Mesoporous Molecular Sieves. Top Catal 53, 141–153 (2010). https://doi.org/10.1007/s11244-009-9419-6

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  • DOI: https://doi.org/10.1007/s11244-009-9419-6

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