Skip to main content
Log in

Foil-supported Rh/γ-Al2O3 and Pt/γ-Al2O3 catalysts for carbon dioxide methane reforming

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Rh/γ-Al2O3 and Pt/γ-Al2O3 catalysts supported on a metal foil surface have been studied in the carbon dioxide reforming of methane. The stability and activity of platinum and rhodium catalysts with different compositions have been determined. The kinetic function parameters have been found by solving the inverse problem. It has been shown that the 0.06% rhodium catalyst is the most active; its activity is more than two orders of magnitude higher than that of the nickel-chromium catalyst studied earlier.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Ya. Rozovskii, Katal. Prom-sti 1, 23 (2001).

    Google Scholar 

  2. M. S. Safonov, B. N. Okunev, and P. A. Zhatikov, Zh. Fiz. Khim. 77, 1393 (2003).

    CAS  Google Scholar 

  3. V. S. Granovskii and V. S. Safonov, Chem. Eng. Sci. 58, 3913 (2003).

    Article  CAS  Google Scholar 

  4. N. M. Voskresenskii, V. K. Bel’nov, S. I. Serdyukov, and M. S. Safonov, Teor. Osn. Khim. Tekhnol. 36, 189 (2002).

    Google Scholar 

  5. A. V. Makunin, V. K. Bel’nov, M. S. Safonov, et al., Teor. Osn. Khim. Tekhnol. 34, 618 (2000).

    Google Scholar 

  6. A. V. Makunin, S. I. Serdyukov, and M. S. Safonov, Neftekhimiya 36, 418 (1996).

    CAS  Google Scholar 

  7. S. I. Serdyukov, T. N. Danil’chuk, O. B. Orlov, et al., Neftekhimiya 43, 438 (2003) [Pet. Chem. 43, 399 (2003)].

    CAS  Google Scholar 

  8. V. S. Arutyunov and O. V. Krylov, Oxidative Conversion of Methane (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  9. J. H. Bitter, V. Seshan, and J. A. Lercher, J. Catal. 171, 279 (1997).

    Article  CAS  Google Scholar 

  10. J. H. Bitter, V. Seshan, and J. A. Lercher, J. Catal. 176, 93 (1998).

    Article  CAS  Google Scholar 

  11. E. A. Drobakha and K. A. Solntsev, RU Patent No. 2190470, (2000).

  12. A. A. Khomenko, L. O. Apel’baum, F. S. Shub, et al., Kinet. Katal. 12, 423 (1971).

    CAS  Google Scholar 

  13. I. I. Karpov, Candidate’s Dissertation in Chemistry (Moscow, 2004).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. I. Serdyukov.

Additional information

Original Russian Text © S.I. Serdyukov, I.I. Karpov, G.S. Drobakha, V.K. Bel’nov, S.L. Levchenko, M.S. Safonov, 2011, published in Neftekhimiya, 2011, Vol. 51, No. 6, pp. 427–434.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Serdyukov, S.I., Karpov, I.I., Drobakha, G.S. et al. Foil-supported Rh/γ-Al2O3 and Pt/γ-Al2O3 catalysts for carbon dioxide methane reforming. Pet. Chem. 51, 418–425 (2011). https://doi.org/10.1134/S0965544111060156

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544111060156

Keywords

Navigation