Abstract
Partial oxidation of methane and dry methane reforming to synthesis gas in the presence of catalysts based on hydrotalcite-like hydroxo salts [AlMg2Ni x Co y (OH)6.08][(NO3) n H2O], where x = 0, 0.02, 0.04 and y = 0, 0.02, 0.04 with a total Ni and/or Co content of no more than 2 wt % have been first studied. It has been shown that the Ni-containing catalysts provide a synthesis gas yield of 90 and 97% in the case of partial oxidation and dry reforming of methane, respectively; in the presence of these catalysts, a trace amount of carbon nanotubes is formed; the catalyst sample containing both nickel and cobalt does not lead to the formation of any carbon nanotubes during dry reforming of methane.
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Original Russian Text © A.G. Dedov, A.S. Loktev, V.P. Danilov, O.N. Krasnobaeva, T.A. Nosova, I.E. Mukhin, S.I. Tyumenova, A.E. Baranchikov, V.K. Ivanov, M.A. Bykov, I.I. Moiseev, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 3.
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Dedov, A.G., Loktev, A.S., Danilov, V.P. et al. Catalytic Materials Based on Hydrotalcite-Like Aluminum, Magnesium, Nickel, and Cobalt Hydroxides for Partial Oxidation and Dry Reforming of Methane to Synthesis Gas. Pet. Chem. 58, 418–426 (2018). https://doi.org/10.1134/S0965544118050055
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DOI: https://doi.org/10.1134/S0965544118050055