Abstract
Archean gneisses cropping out on islands in the White Sea and its coast in northern Karelia host widespread bodies of Early Proterozoic metamorphosed gabbroids. Carbonate–silicate veins hosted in these metabasite bodies and constrained to their contacts with the gneisses contain Fe–Cu sulfides, whose concentrations occasionally reach economic levels. The dominant gangue minerals are plagioclase, quartz, carbonates, and chlorite. The formation stages of the veins correspond to the transition from the early quartz–plagioclase to late quartz–carbonate associations with chlorite and sulfides. The early (high-temperature) stage is discernible in the wall-rock amphibolite aureoles, which were formed at temperature of about 550–650°C (estimates by the TWQ method). This stage corresponds to the quartz–plagioclase association in the marginal zones of the veins. The transition to the late stage and the formation of veined quartz–carbonate (±biotite) associations occurred at temperatures of 540°C and lower, judging by the calcite–dolomite associations. The further development of the quartz–chlorite–carbonate and sulfide associations in the veins and wall-rock amphibolites corresponded to a temperature decrease to 350°C and below, as evaluated with the application of chlorite thermometers. The veins and wall-rock amphibolitization may have been induced by metamorphic fluids during the latest retrograde metamorphic stage in the Early Proterozoic.
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REFERENCES
Alm, E. and Sundblad, K., Sveconorwegian polymetallic quartz veins in Sweden, Neues Jahrb. Mineral. Monatsh., 1994, vol. 1994, no. 1, pp. 1–22.
Alm, E., Broman, C., Billström, K., et al., Fluid characteristics and genesis of Early Neoproterozoic orogenic gold–quartz veins in the Harnas area, southwestern Sweden, Econ. Geol., 2003, vol. 98, no. 7, pp. 1311–1328.
Anovitz, L.M. and Essene, E.J., Phase equilibria in the system CaCO3–MgCO3–FeCO3, J. Petrol., 1987, vol. 28, no. 2, pp. 389–415.
Balagansky, V.V., Main Stages of the Tectonic Evolution of the Northeastern Baltic Shield in the Paleoproterozoic, Extended Abstract of Doctoral (Geol.-Min.) Dissertation, St. Petersburg: IGGD RAN, 2002.
Balagansky, V.V., Glaznev V.N., Osipenko L.G., The Early Proterozoic evolution of the northeastern Baltic Shield: a terrane analysis, Geotectonics, 1998, vol. 32, no. 2. pp. 81–92.
Berezin, A.V., Salimgaraeva, L.I., and Skublov, S.G., Evolution of mineral composition during eclogite metamorphism in the Belomorian Mobile Belt: data from Vichennaya Luda Island, Petrology, 2020, vol. 28, no. 1, pp. 73–92.
Berezin, A.V. and Skublov, S.G., Eclogite-like apogabbro rocks in Sidorov and Bolshaya Ileika Islands, Keret Archipelago, White Sea: compositional characteristics, metamorphic age and conditions, Petrology, 2014, vol. 22, no. 3, pp. 234–254.
Berman, R.G., Internally-consistent thermodynamic data for minerals in the system Na2O–K2O–CaO–MgO–FeO–Fe2O3–Al2O3–SiO2–TiO2–H2O–CO2, J. Petrol., 1988, vol. 29, pp. 445–522.
Berman, R.G., Thermobarometry using multiequilibrium calculations: a new technique with petrologic applications, Can. Mineral., 1991, vol. 29, pp. 833–855.
Bibikova, E., Skiöld, T., Bogdanova, S., et al., Titanite–rutile thermochronometry across the boundary between the Archaean craton in Karelia and the Belomorian mobile belt, eastern Baltic Shield, Precambrian Res., 2001, vol. 105, nos. 2–4, pp. 315–330.
Bons, P.D., Elburg, M.A., and Gomez-Rivas, E., A review of the formation of tectonic veins and their microstructures, J. Struct. Geol., 2012, vol. 43, pp. 33–62.
Bourdelle, F., Parra, T., Chopin, C., and Beyssac, O., A new chlorite geothermometer for diagenetic to low-grade metamorphic conditions, Contrib. Mineral. Petrol., 2013, vol. 165, no. 4, pp. 723–735.
Cathelineau, M. and Nieva, D., A chlorite solid solution geothermometer the Los Azufres (Mexico) geothermal system, Contrib. Mineral. Petrol., 1985, vol. 91, no. 3, pp. 235–244.
Cook, N.J., Ciobanu, C.L., Danyushevsky, L.V., and Gilbert, S., Minor and trace elements in bornite and associated Cu–(Fe)-sulfides: a LA-ICP-MS study bornite mineral chemistry, Geochim. Cosmochim. Acta, 2011, vol. 75, no. 21, pp. 6473–6496.
Glebovitsky, V.A. and Smolkin, V.F., Rannii dokembrii Baltiiskogo shchita (Early Precambrian of the Baltic Shield), St. Petersburg: Nauka, 2005.
Holland, T. and Blundy, J., Non-ideal interactions in calcic amphiboles and their bearing on amphibole–plagioclase thermometry, Contrib. Mineral. Petrol., 1994, vol. 116, no. 4, pp. 433–447.
Korzhinskii, D.S., Acid-basic interaction in the mineral-forming systems, Teoriya protsessov mineraloobrazovaniya: izbrannye trudy (Theory of Mineral Formation: Selected Paper), Moscow: Nauka, 1994.
Kosoi, L.A., Geological-petrographic overview of the Keret’ area of North Karelia, Uch. Zap. Lening. Gos. Univ., 1938, no. 26, pp. 65–99.
Kotel’nikov, A.R., Suk, N.I., Kotel’nikova, Z.A., et al., Mineral geothermometers for low-temperature parageneses, Vestn. ONZ RAN, 2012, vol. 4, pp. 1–4.
Kozlovskii, V.M., Geology and Metamorphism of the Metamafic Rocks in Ductile Flow zones of the Belomorian Mobile Belt, North Karelia, Doctoral (Geol.-Min.) Dissertaion, Moscow: IGEM RAN, 2021.
Kozlovskii, V.M. and Aranovich, L.Ya., Petrology and thermobarometry of eclogite rocks in the Krasnaya Guba Dike Field, Belomorian Mobile Belt, Petrology, 2010, vol. 18, no. 1, pp. 27–49.
Kozlovskii, V.M., Travin, V.V., Savatenkov, V.M., et al., Thermobarometry of Paleoproterozoic metamorphic events in the central Belomorian Mobile Belt, Northern Karelia, Russia, Petrology, 2020, vol. 28, no. 2, pp. 183–206.
Kozlovskii, V.M., Travin, V.V., Zinger, T.F., et al., Static and dynamic metamorphism of mafic rocks of the Belomorian Belt: Evidence from the Pongoma–Navolok massif and its metamorphic surrounding, Petrologiya i geodinamika geologicheskikh protsessov (Petrology and Geodynamics of Geological Processes), 2021, vol. 2, pp. 28–31.
Leake, B.E., Woolley, A.R., Arps, C.E.S., et al., Nomenclature of amphiboles; report of the subcommittee on amphiboles of the international mineralogical association commission on new minerals and mineral names, Mineral. Mag., 1997, vol. 61, no. 405, pp. 295–310.
Lebedev, V.I., Mineralogy of quartz–carbonate veins of North Karelia, Izv. Karelo-Finskogo Fil. AN SSSR, 1950, no. 1, pp. 3–36.
Loidolt, L.H., Quartz-Feldspar-Carbonate Bodies of the Carrizo Mountains, Texas (The University of Arizona, 1970).
Marsala, A., Wagner, T., and Walle, M., Late-metamorphic veins record deep ingression of meteoric water: a LA-ICP-MS fluid inclusion study from the fold-and-thrust belt of the Rhenish Massif, Germany, Chem. Geol., 2013, vol. 351, pp. 134–153.
Nikitin, Yu.V., Molibdenitovoe orudenenie v zhilakh Severnoi Karelii (Molybdenite Mineralization in Veins of North Karelia), Moscow–Leningrad: Izd-vo AN SSSR, 1960, vol. 9, pp. 150–157.
Raj, R.M. and Kumar, S.N., Characterisation of selected sulphides associated with the granitic pegmatites of Nagamalai–Pudukottai area, Madurai district, Tamil Nadu, India, J. Appl. Geochem., 2015, vol. 17, no. 4, pp. 444–450.
Raj, R.M. and Kumar, S.N., Geothermobarometry of granitic pegmatites of Nagamalai–Pudukottai area, Madurai Block, South India, Earth Sci. India, 2018, vol. 11, pp. 168–182.
Sankar, D.B. and Prasad, K.S.S., Petrology of Garimanipenta (copper mineralisation area), Nellore District, Andhra Pradesh, South India—a case study, Int. J. Sci. Environ. Technol., 2012, vol. 1, no. 4, pp. 247–259.
Shurkin K.A. Geology and Petrography of the Archean Gabbro–Labradorites of Karelia, Geologiya i absolyutnyi vozrast dokembriya Baltiiskogo shchita i Vostochnoi Sibiri (Geology and Absolute Age of Precambrian of the Baltic Shield and East Siberia), Shurkin, K.A, Duk, V.L, Mitrofanov, F.P, Eds., Moscow–Leningrad, 1960, pp. 120–149.
Skublov S.G., Berezin A.V., Mel’nik A.E. i dr. Protolith Age of Eclogites from the Southern Part of Pezhostrov Island, Belomorian Belt: Protolith of Metabasites as Indicator of Eclogitization Time, Petrology, 2016, vol. 24, no. 6, pp. 594–607.
Skublov, S.G., Mel’nik, A.E., Marin, Yu.B., et al., New data on the age (U–Pb, Sm–Nd) of metamorphism and a protolith of eclogite-like rocks from the Krasnaya Guba Area, Belomorian Belt, Dokl. Earth Sci., 2013, vol. 453, no. 3, pp. 1158–1164.
Slabunov, A.I., Geologiya i geodinamika arkheiskikh podvizhnyi poyasov na primere Belomorskoi provintsii Fennoskandinavskogo shchita (Geology and Geodynamics of the Archean Mobile Belts: Evidence from the Belomorian Province of the Fennoscandian Shield), Petrozavodsk: KarNTs RAN, 2008.
Slabunov, A.I., Azimov, P.Ya., Glebovitsky, V.A., et al., Archaean and Palaeoproterozoic migmatizations in the Belomorian Province, Fennoscandian Shield: petrology, geochronology, and geodynamic settings, Dokl. Earth Sci., 2016, vol. 467, no. 1, pp. 259–263.
Slabunov, A.I., Balagansky, V.V., and Shchipansky, A.A., Mesoarchean to Paleoproterozoic crustal evolution of the Belomorian Province, Fennoscanidan Shield, and the tectonic setting of eclogites, Russ. Geol. Geophys., 2021, vol. 62, no. 5, pp. 525–677.
Smirnova, V.S. and Solodkaya, R.I., Geologicheskaya karta SSSR masshtaba 1 : 200 000. Seriya Karel’skaya list Q-36XVI. Ob"yasnitel’naya zapiska (Geological Map of the USSR on a Scale 1 : 200 000. Karelian Series, Sheet Q-36XVI. Explanatory Note), Moscow: Gosudarstvennoe nauchno-tekhnicheskoe izd-vo literatury po geologii i okhrane nedr, 1960.
Stepanov, V.S., Osnovnoi magmatizm dokembriya zapadnogo Belomor’ya (Precambrian Mafic Magmatism of the Western Belomorian Belt), Leningrad: Nauka, 1981.
Stepanova, A. and Stepanov, V., Paleoproterozoic mafic dyke swarms of the Belomorian Province, Eastern Fennoscandian shield, Precambrian Res., 2010, vol. 183, no. 3, pp. 602–616.
Stepanova, A.V., Stepanov, V.S., Larionov, A.N., et al., 2.5 Ga gabbro-anorthosites in the Belomorian Province, Fennoscandian Shield: petrology and tectonic setting, Petrology, 2017, vol. 25, no. 6, pp. 566–591.
Stepanova, A.V., Stepanov, V.S., Larionov, A.N., et al., Relicts of Paleoproterozoic lips in the Belomorian Province, Eastern Fennoscandian shield: barcode reconstruction for a deeply eroded collisional orogeny, Geol. Soc. London: Spec. Publ., 2022, vol. 518, no. 1, pp. 101–128.
Warr, L.N., IMA-CNMNC approved mineral symbols, Mineral. Mag., 2021, vol. 85, no. 3, pp. 291–320.
ACKNOWLEDGMENTS
The authors thank S.E. Borisovskii and E.V. Koval’chuk (Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences) for conducting microprobe analyses of minerals at the IGEM-ANALITIKA Center for the Collective Use of Analytical Equipment. The authors are thankful to A.L. Perchuk (Moscow State University) and the anonymous reviewer for constructive criticism of the manuscript.
Funding
This study was carried out under a government-financed research project for the Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences.
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Volkov, I.S., Kozlovskii, V.M. Formation Stages and Conditions of Carbonate–Silicate Veins and Their Wall-Rock Aureoles in the Early Proterozoic Complexes of the Belomorian Mobile Belt, Northern Karelia. Petrology 31, 538–557 (2023). https://doi.org/10.1134/S0869591123050077
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DOI: https://doi.org/10.1134/S0869591123050077