Abstract
Experiments were carried out to simulate the transformations of anaerobic freshwater chemistry at aeration. Quantitative characteristics of the passage from dissolved into suspended state in the course of aeration were obtained for Fe, Mn, Co, Ni, Cu, Zn, Cd, Ag, Rb, Cs, Sr, Ba, Be, Al, Ga, Cr, Ti, Zr, U, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, B, V, Ge, As, Mo, and W. The decrease in the concentration of dissolved forms was found to be maximal for Fe and Mn, reaching 0.03 and 0.2 mg/L, respectively; these values correspond to the solubility of newly-precipitated oxihydrates of those elements. Among other elements, a high degree of removal is typical of elements-hydrolysates (Cr, Zr, Al, Ga, Be, Ti, and the majority of rare-earth elements), some heavy metals (Zn, Ag, Cd, and Co), and W.
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References
Alekseevskii, E.V., Aktivnaya dvuokis’ margantsa (Active Manganese Dioxide), Leningrad: ONTIKhimteoret, 1937.
Afanas’ev, Yu.A., Eremin, V.I., Osenchuk, T.M., and Ryabinin, A.I., Studying the effect of pressure on the solubility of iron (III) and manganese (IV) hydroxides, Zh. Fiz. Khim., 1979, vol. 53, no. 8, pp. 1960–1962.
Afanas’ev, Yu.A., Eremin, V.P., and Ryabinin, A.I., On the effect of hydrostatic pressure and temperature on the solubility of major components of ferro-manganese nodules, Okeanologiya, 1982, vol. 22, no. 3, pp. 420–422.
Brusilovskii, S.A., Metodologiya i normativno-pravovye osnovy gidrokhimicheskogo monitoringa (Methodology and Legislative Basis of Hydrochemical Monitoring), Moscow: Univ. kn, 2010.
Zaborenko, K.B., Brusilovskii, S.A., and Os’kina, T.E., On the solubility of iron (III) hydroxide in water, in Vzaimodeistvie poverkhnostnogo i podzemnogo stoka. Vyp. 1 (Interaction between Surface and Subsurface Runoff), Moscow: Mosk. univ., 1973, pp. 139–147.
Krauskopf, K.B., Separation of manganese and iron in sedimentation process, in Geokhimiya litogeneza (Geochemistry of Lithogenesis), Moscow: IL, 1963, pp. 259–293.
Lur’e, Yu.Yu., Unifitsirovannye metody analiza vod (Unified Methods of Water Analysis), Moscow: Khimiya, 1971.
Mel’nik, Yu.P., Termodinamicheskie konstanty dlya analiza uslovii obrazovaniya zheleznykh rud (Thermodynamic Constants for the Analysis of Iron Ore Formation Conditions), Kiev: Nauk. dumka, 1972.
Nakhshina, E.P., Nabivanets, B.I., and Malinovskaya, L.A., Effect of organic acids on manganese release from bottom deposits (in an experiment), Gidrobiologich. Zhurn., 1976, vol. 12, no. 3, pp. 56–62.
Perel’man, A.I. and Kasimov, N.S., Geokhimiya landshafta (Landscape Geochemistry), Moscow: Astreya2000, 1999.
Pokrovskii, O.S. and Savenko, V.S., Interaction between nonstechiometric manganese oxides with aqueous solutions: solubility and redox equilibria, Geokhimiya, 1995, no. 2, pp. 239–250.
Savenko, A.V., Sorption on calcium carbonate, Radiokhimiya, 2001, vol. 43, no. 2, pp. 174–177.
Savenko, V.S., On formation processes of ferro-manganese nodules: physicochemical analysis, Geokhimiya, 1990, no. 8, pp. 1151–1160.
Savenko, V.S., Andrievskii, E.I., Pavlov, V.A., and Petrukhin, V.A., Microelements, in Vodokhranilishcha Moskvoretskoi vodnoi sistemy (Reservoirs of Moskvoretskaya Water System), Moscow: Mosk. univ., 1985, pp. 130–142.
Savenko, V.S. and Pokrovskii, O.S., Organic complexes of heavy metals in seawater, in Nauchnye i tekhnicheskie aspekty okhrany okruzhayushchei sredy. Obzornaya informatsiya (Scientific and Technical Aspects of Environmental Protection: Survey Data), Moscow: VINITI, 1995, issue 4, pp. 1–44.
Savenko, V.S. and Savenko, A.V., Geokhimiya fosfora v global’nom gidrologicheskom tsikle (Phosphorus Geochemistry in Global Hydrological Cycle), Moscow: GEOS, 2007.
Solomin, G.A., Ionic equilibria in natural waters, Gidrokhim. Mater., 1967, vol. 49, pp. 88–94.
Uil’yams, D., Metally zhizni (Life Metals), Moscow: Mir, 1975.
Khatchinson, D., Limnologiya (Limnology), Moscow: Progress, 1969.
Yatsimirskii, K.B., Vvedenie v bioneorganicheskuyu khimiyu (Introduction to Bioinorganic Chemistry), Kiev: Nauk. dumka, 1976.
Baharim, N., Ismail, R., and Omar, M.H., Effect of thermal stratification on the concentration of iron and manganese in a tropical water supply reservoir, Sains Malaysiana, 2011, vol. 40, no. 8, pp. 821–825.
Benoit, G. and Hemond, H.F., A biogeochemical mass balance of 210Po and 210Pb in an oligotrophic lake with seasonally anoxic hypolimnion, Geochim. Cosmochim. Acta, 1987, vol. 51, no. 6, pp. 1445–1456.
Benoit, G. and Hemond, H.F., 210Po and 210Pb remobilization from lake sediments in relation to iron and manganese cycling, Environ. Sci. Technol., 1990, vol. 24, no. 8, pp. 1224–1234.
Ellis-Evans, J.C. and Leman, E.C.G., Some aspects of iron cycling in maritime Antarctic lakes, Hydrobiologia, 1989, vol. 172, no. 1, pp. 149–164.
Hamilton-Taylor, J. and Davison, W., Redox-driven cycling of trace elements in lakes, in Physics and Chemistry of Lakes, Berlin: Springer-Verlag, pp. 217–2631995.
Hamilton-Taylor, J., Davison, W., and Morfett, K., The biogeochemical cycling of Zn, Cu, Fe, Mn, and dissolved organic C in a seasonally anoxic lake, Limnol. Oceanogr., 1996, vol. 41, no. 3, pp. 408–418.
Hem, J.D., Chemical factors that influence the availability of iron and manganese in aqueous systems, Geol. Soc. Am. Bull., 1972, vol. 83, no. 2, pp. 443–450.
Hongve, D., Cycling of iron, manganese and phosphate in meromictic lake, Limnol. Oceanogr., 1997, vol. 42, no. 4, pp. 635–647.
Luther, G.W., Glazer, B., Ma, S., Trouwborst, R., Shultz, B.R., Druschel, G., and Kraiya, C., Iron and sulfur chemistry in stratified lake: evidence for ironrich sulfide complexes, Aquatic Geochem., 2003, vol. 9, no. 2, pp. 87–110.
Robbins, J.A. and Eadie, B.J., Seasonal cycling of trace elements 137Cs, 9Be and 239+240Pu in Lake Michigan, J. Geophys. Res., 1991.
Roseboom, D.P., Evans, R.L., Wang, W.-C., Butts, T.A., and Twait, R.M., Effect of Bottom Conditions on Eutrophy of Impoundments, Urbana: Illinois Inst. of Natural Resources, 1979.
Seyler, P. and Martin, J.-M., Biogeochemical processes affecting arsenic species distribution in a permanently stratified lake, Environ. Sci. Technol., 1989, vol. 23, no. 10, pp. 1258–1263.
Swain, H.A., Lee, C., and Rozelle, R.B., Determination of the solubility of manganese hydroxide and manganese dioxide at 25 C by atomic absorption spectrometry, Analyt. Chem., 1975, vol. 47, no. 7, pp. 1135–1137.
Taillefert, M., Lienemann, C.-P., Gaillard, J.-F., and Perret, D., Speciation, reactivity, and cycling of Fe and Pb in a meromictic lake, Geochim. Cosmochim. Acta, 2000, vol. 64, no. 2, pp. 169–183.
Takematsu, N., Sato, Y., and Okabe, S., The partition of minor transition metals between manganese oxides and seawater, J. Oceanogr. Soc. Jpn., 1981, vol. 37, no. 4, pp. 193–197.
Takematsu, N., Sato, Y., and Okabe, S., The formation of todorokite and birnessite in sea water pumped from under ground, Geochim. Cosmochim. Acta, 1984, vol. 48, no. 5, pp. 1099–1106.
White, J.R. and Driscoll, C.T., Lead cycling in an acidic Adirondack Lake, Environ. Sci. Technol., 1985, vol. 19, no. 12, pp. 1182–1187.
Yagi, A., Manganese cycle in Lake Fukami-ike, Verh. Internat. Verein. Limnol., 1993, vol. 25, pp. 193–199.
Yagi, A. and Shimodaira, I., Seasonal changes of iron and manganese in Lake Fukami-ike—occurrence of turbid manganese layer, Japan J. Limnol., 1986, vol. 47, no. 3, pp. 279–289.
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Original Russian Text © A.V. Savenko, V.S. Savenko, O.S. Pokrovskii, 2016, published in Vodnye Resursy, 2016, Vol. 43, No. 4, pp. 408–418.
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Savenko, A.V., Savenko, V.S. & Pokrovskii, O.S. Experimental simulation of chemistry transformation of anaerobic water during aeration. Water Resour 43, 647–656 (2016). https://doi.org/10.1134/S0097807816040138
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DOI: https://doi.org/10.1134/S0097807816040138