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Evaluating the Possibility of Using Ionic Liquids in the Synthesis and Separation of Cyclohexanone

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Abstract

Using gas–liquid chromatography, the activity coefficients upon the infinite dilution of the components of the reaction mixture for obtaining cyclohexanone in the presence of various ionic liquids are determined. Activity coefficients have been calculated at three temperatures based on experimental data on the retention times of the components. The extractive effect of the ionic liquid in respect to the binary azeotropes of the reaction system is noted. The increase in selectivity of a traditional solvent (ethylene glycol) while adding small amounts of ionic liquid is shown.

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Funding

This research was carried out with financial support from the Russian Science Foundation, project no. 16-19-10632.

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Authors and Affiliations

  1. Lomonosov Institute of Fine Chemical Technology, MIREA – Russian Technological University, 119571, Moscow, Russia

    V. I. Zhuchkov, S. L. Nazansky, A. K. Frolkova & K. D. Ganina

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  1. V. I. Zhuchkov
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  2. S. L. Nazansky
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  3. A. K. Frolkova
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  4. K. D. Ganina
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Correspondence to V. I. Zhuchkov.

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Zhuchkov, V.I., Nazansky, S.L., Frolkova, A.K. et al. Evaluating the Possibility of Using Ionic Liquids in the Synthesis and Separation of Cyclohexanone. Theor Found Chem Eng 55, 786–791 (2021). https://doi.org/10.1134/S0040579521040199

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