Abstract
This work reports the main findings of the studies related to the problem of liquid radioactive waste utilization conducted at the Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, in 2013–2018. It has been shown that, during the electrochemical treatment of model aqueous solutions containing Co-EDTA, the complex is destroyed and cobalt precipitates in the form of oxides, hydroxides, and spinel of variable compositions.
Similar content being viewed by others
REFERENCES
Ryabchikov, B.E., Ochistka zhidkikh radioaktivnykh otkhodov (Purification of Liquid Radioactive Wastes), Moscow: DeLi Print, 2008.
Harada, S. and Yanagisawa, M., Evaluation of a method for removing cesium and reducing the volume of leaf litter from broad-leaved trees contaminated by the Fukushima Daiichi nuclear accident during the Great East Japan Earthquake, Chemosphere, 2017, vol. 172, pp. 516–524.
Wu, Y., Zhang, X.X., Wei, Y.Z., and Mimura, H., Development of adsorption and solidification process for decontamination of Cs-contaminated radioactive water in Fukushima through silica-based AMP hybrid adsorbent, Sep. Purif. Technol., 2017, vol. 181, pp. 76–84.
Jeon, C., Removal of cesium ions from aqueous solutions using immobilized nickel hexacyanoferrate-sericite beads in the batch and continuous processes, J. Ind. Eng. Chem. (Amsterdam, Neth.), 2016, vol. 40, pp. 93–98.
Genevois, N., Villandier, N., Chaleix, V., Poli, E., Jauberty, L., and Gloaguen, V., Removal of cesium ion from contaminated water: Improvement of Douglas fir bark biosorption by a combination of nickel hexacyanoferrate impregnation and TEMPO oxidation, Ecol. Eng., 2017, vol. 100, pp. 186–193. https://doi.org/10.1016/j.ecoleng.2016.12.012
Gordienko, P.S., Shabalin, I.A., Yarusova, S.B., Suponina, A.P., and Zhevtun, I.G., Sorption of cesium ions by nanostructured calcium aluminosilicates, Russ. J. Phys. Chem. A, 2016, vol. 90, no. 10, pp. 2022–2028. https://doi.org/10.1134/S0036024416100125
Lieberman, R.N., Green, U., Segev, G., Polat, M., Mastai, Y., and Cohen, H., Coal fly ash as a potential fixation reagent for radioactive wastes, Fuel, 2015, vol. 153, pp. 437–444.
Gasser, M.S., Mekhamer, H.S., and Abdel Rahman, R.O., Optimization of the utilization of Mg/Fe hydrotalcite like compounds in the removal of Sr(II) from aqueous solution, J. Environ. Chem. Eng., 2016, vol. 4, pp. 4619–4630.
Ghaly, M., El-Dars, F.M.S.E., Hegazy, M.M., and Abdel Rahman, R.O., Evaluation of synthetic Birnessite utilization as a sorbent for cobalt and strontium removal from aqueous solution, Chem. Eng. J., 2016, vol. 284, pp. 1373–1385. https://doi.org/10.1016/j.cej.2015.09.025
Yarusova, S.B., Gordienko, P.S., Krysenko, G.F., and Azarova, Yu.A., Sr2+ sorption by synthetic and technogenic silicate materials, Inorg. Mater., 2014, vol. 50, no. 6, pp. 599–605. https://doi.org/10.1134/S002016851406020X
Dyatlova, N.M., Temkina, V.Ya., and Popov, K.I., Kompleksony i kompleksonaty metallov (Complexones and Complexonates of Metals), Moscow: Khimiya, 1988.
Seliverstov, A.F., Lagunova, Yu.O., Milyutin, V.V., and Ershov, B.G., Recovery of 60Co from EDTA-containing aqueous solutions, Radiochemistry, 2013, vol. 55, no. 4, pp. 388–391. https://doi.org/10.1134/S1066362213040085
Ku, Y., Wang, L.-S., and Shen, Y.-S., Decomposition of EDTA in aqueous solution by UV/H2O2 process, J. Hazard. Mater., 1998, vol. 60, pp. 41–55.
Lee, H.-C., In, J.-H., Hwang, K.-Y., and Lee, C.-H., Decomposition of ethylenediaminetetraacetic acid by supercritical water oxidation, Ind. Eng. Chem. Res., 2004, vol. 43, no. 13, pp. 3223–3227. https://doi.org/10.1021/ie049952u
Lin, Q., Pan, H., Yao, K., Pan, Y., and Long, W., Competitive removal of Cu–EDTA and Ni–EDTA via microwave-enhanced Fenton oxidation with hydroxide precipitation, Water Sci. Technol., 2015, vol. 72, no. 7, pp. 1184–1190. https://doi.org/10.2166/wst.2015.329
Liu, X., Fan, J.-H., Hao, Y., and Ma, L.-M., The degradation of EDTA by the bimetallic Fe–Cu/O2 system, Chem. Eng. J., 2014, vol. 250, pp. 354–365. https://doi.org/10.1016/j.cej.2014.04.028
Gordienko, P.S., Dostovalov, V.A., and Efimenko, A.V., Mikrodugovoe oksidirovanie metallov i splavov (Microarc Oxidation of Metals and Alloys), Vladivostok: Dal’nevost. Fed. Univ., 2013.
Gordienko, P.S., Zhevtun, I.G., Shabalin, I.A., and Yarusova, S.B., Study of the composition and thermal behavior of the products of electrolysis of aqueous solutions of the Co–EDTA chelate, Khim. Tekhnol., 2013, vol. 14, no. 11, pp. 693–698.
Li, D., Ding, Y., Wei, X., Xiao, Y., and Jiang, L., Cobalt-aluminum mixed oxides prepared from layered double hydroxides for the total oxidation of benzene, Appl. Catal., A, 2015, vol. 507, pp. 130–138. https://doi.org/10.1016/j.apcata.2015.09.038
Deraz, N.M. and Fouda, M.M.G., Synthesis, structural, morphological properties of cobalt-aluminum nano-composite, Int. J. Electrochem. Sci., 2013, vol. 8, no. 2, pp. 2756–2767.
Gordienko, P.S., Zhevtun, I.G., Shabalin, I.A., Yarusova, S.B., and Dmitrieva, E.E., Electrochemical decomposition of chelate complex of ethylenediaminetetraacetic acid with cobalt, Theor. Found. Chem. Eng., 2015, vol. 49, pp. 786–789. https://doi.org/10.1134/S0040579515050073
Gordienko, P.S., Zhevtun, I.G., Yarusova, S.B., Shabalin, I.A., Vasilenko, O.S., Yudakov, A.A., Paramonov, A.N., and Amelichkin, D.A., Effect of the salt background of solutions containing Co–EDTA on the electrochemical recovery of Co2+ ions, Ekol. Khim., 2015, vol. 24, no. 3, pp. 176–180.
Funding
This work was financially supported by the Ministry of Education and Science of the Russian Federation (Decision no. 218, agreement no. 02.G25.31.0166 between the Far East Plant Zvezda and the Ministry of Education and Science of the Russian Federation).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Kharitonov
Rights and permissions
About this article
Cite this article
Zhevtun, I.G., Gordienko, P.S., Yarusova, S.B. et al. Destruction of Co-EDTA Complexes by the Electrochemical Treatment of Water-Based Solutions. Theor Found Chem Eng 54, 1090–1095 (2020). https://doi.org/10.1134/S0040579520050255
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040579520050255