Abstract
This review analyzes publications on experimental studies and mathematical modeling in the field of development of a catalytic reformer (mainly, steam methane conversion) with a fixed catalytic bed. The specific feature of such a reformer is its integration with a Pd membrane for the purpose of producing high-purity hydrogen to power a low-temperature fuel cell battery.
Similar content being viewed by others
References
Uemiya, S., Sato, N., Ando, H., et al., Steam Reforming of Methane in a Hydrogen-Permeable Membrane Reactor, Appl. Catal., 1991, vol. 67, p. 223.
Shu, J., Grandjean, B., and Kaliaguine, S., Methane Steam Reforming in Asymmetric Pd- and Pd- Ag/Porous SS Membrane Reactors, Appl. Catal., A, 1994, vol. 119, p. 305.
Lattner, J.R. and Harold, M.P., Comparison of Conventional and Membrane Reactor Fuel Processors for Hydrocarbon-Based PEM Fuel Cell Systems, Int. J. Hydrogen Energy, 2004, vol. 29, no. 4, p. 393.
Lattner, J.R. and Harold, M.P., Comparison of Methanol-Based Fuel Processors for PEM Fuel Cell Systems, Appl. Catal., B, 2005, vol. 56, p. 149.
Kikuchi, E., Nemoto, Y., Kajiwara, M., et al., Steam Reforming of Methane in Membrane Reactors: Comparison of Electroless-Plating and CVD Membranes and Catalyst Packing Modes, Catal. Today, 2000, vol. 56, p. 75.
Uemiya, S., Brief Review of Steam Reforming Using a Metal Membrane Reactor, Top. Catal., 2004, vol. 29, nos. 1–2, p. 79.
Tong, J., Matsumura, Y., Suda, H., et al., Experimental Study of Steam Reforming of Methane in a Thin (6 μm) Pd-Based Membrane Reactor, Ind. Eng. Chem. Res., 2005, vol. 44, p. 1454.
Tong, J. Matsumura, Y., et al., Pure Hydrogen Production by Methane Steam Reforming with Hydrogen-Permeable Membrane Reactor, Catal. Today, 2006, vol. 111, p. 147.
Chen, Y., Wang, Y., Xu, H., et al., Integrated One-Step PEMFC-Grade Hydrogen Production from Liquid Hydrocarbons Using Pd Membrane Reactor, Ind. Eng. Chem. Res., 2007, vol. 46, p. 510.
Chen, Y., Wang, Y., Xu, H., et al., Efficient Production of Hydrogen from Natural Gas Steam Reforming in Palladium Membrane Reactor, Appl. Catal., B, 2008, vol. 80, p. 283.
Hara, S., Sakaki, K., and Itoh, N., Decline in Hydrogen Permeation Due to Concentration Polarization and CO Hindrance in a Palladium Membrane Reactor, Ind. Eng. Chem. Res., 1999, vol. 38, p. 4913.
Koukou, M.K., Papayannakos, N., Markatos, N.C., et al., Performance of Ceramic Membranes at Elevated Pressure and Temperature: Effect of Non-Ideal Flow Conditions in a Pilot Scale Membrane Separator, J. Membr. Sci., 1999, vol. 155, p. 241.
Vogiatzis, E., Koukou, M.K., Papayannakos, N., et al., Heat Dispersion Effects on the Functional Characteristics of Industrial-Scale Adiabatic Membrane Reactors, Chem. Eng. Technol., 2004, vol. 27, p. 857.
Markatos, N.C., Vogiatzis, E., Koukou, M.K., et al., Membrane Reactor Modeling: A Comparative Study To Evaluate the Role of Combined Mass and Heat Dispersion in Large-Scale Adiabatic Membrane Modules, Chem. Eng. Res. Des., 2005, vol. 83, p. 1171.
Mori, N., Nakamura, T., Noda, K., et al., Reactor Configuration and Concentration Polarization in Methane Steam Reforming by a Membrane Reactor with a Highly Hydrogen-Permeable Membrane, Ind. Eng. Chem. Res., 2007, vol. 46, p. 1952.
Mori, N., Nakamura, T., Sakai, O., et al., CO-Free Hydrogen Production by Membrane Reactor Equipped with CO Methanator, Ind. Eng. Chem. Res., 2008, vol. 47, p. 1421.
Tiemersma, T.P., Patil, C.S., Annaland, M., et al., Modelling of Packed Bed Membrane Reactors for Autothermal Production of Ultrapure Hydrogen, Chem. Eng. Sci., 2006, vol. 61, p. 1602.
Simakov, D. and Sheintuch, M., Design of a Thermally Balanced Membrane Reformer for Hydrogen Production, AIChE J., 2008, vol. 54, no. 10, p. 2735.
Simakov, D. and Sheintuch, M., Demonstration of a Scaled-Down Autothermal Membrane Methane Reformer for Hydrogen Generation, Int. J. Hydrogen Energy, 2009, vol. 34, p. 8866.
Simakov, D. and Sheintuch, M., Experimental Optimization of an Autonomous Scaled-Down Methane Membrane Reformer for Hydrogen Generation, Ind. Eng. Chem. Res., 2010, vol. 49, no. 3, p. 1123.
Pieterse, J.A.Z., Boon, J., van Delft, Y.C., et al., On the Potential of Nickel Catalysts for Steam Reforming in Membrane Reactors, Catal. Today, 2010, vol. 156, p. 153.
Babak, V.N., Babak, T.B., Zakiev, S.E., and Kholpanov, L.P., Theoretical Study of Hydrocarbon Dehydrogenation at High Temperatures, Theor. Found. Chem. Eng., 2009, vol. 43, no. 1, p. 74.
Li, A., Lim, C.J., and Grace, J.R., Staged-Separation Membrane Reactor for Steam Methane Reforming, Chem. Eng. J., 2008, vol. 138, p. 452.
Caravella, A., Di Maio, F.P., and Di Renzo, A., Computational Study of Staged Membrane Reactor Configurations for Methane Steam Reforming. I. Optimization of Stage Lengths, AIChE J., 2010, vol. 56, no. 1, p. 248.
Caravella, A., Di Maio, F.P., and Di Renzo, A., Computational Study of Staged Membrane Reactor Configurations for Methane Steam Reforming. II. Effect of Number of Stages and Catalyst Amount, AIChE J., 2010, vol. 56, no. 1, p. 259.
Kirillov, V.A. and Meshcheryakov, V.D., Modeling of a Membrane Reactor for ÑÎ Steam Conversion for Pure Hydrogen Production from Synthesis Gas, Khim. Promst’. Segodnya, 2009, no. 9, p. 33.
Kirillov, V.A., Meshcheryakov, V.D., Brizitskii, O.F., and Terent’ev, V. Ya., Analysis of a Power System Based on Low-Temperature Fuel Cells and a Fuel Processor with a Membrane Hydrogen Separator, Theor. Found. Chem. Eng., 2010, vol. 44, no. 3, p. 227.
Campanari, S., Macchi, E., and Manzo, G., Membrane Reformer PEM Cogeneration Systems for Residential Applications-Part A: Full Load and Partial Load Simulation, Asia-Pac. J. Chem. Eng., 2009, vol. 4, p. 301.
Bernardo, P., Barbieri, G., and Drioli, E., Evaluation of Membrane Reactor with Hydrogen-Selective Membrane in Methane Steam Reforming, Chem. Eng. Sci., 2010, vol. 65, p. 1159.
Shirasaki, Y., Tsuneki, T., Ota, Y., et al., Development of Membrane Reformer System for Highly Efficient Hydrogen Production from Natural Gas, Int. J. Hydrogen Energy, 2009, vol. 34, p. 4482.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.B. Shigarov, V.D. Meshcheryakov, V.A. Kirillov, 2011, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2011, Vol. 45, No. 5, pp. 504–518.
Rights and permissions
About this article
Cite this article
Shigarov, A.B., Meshcheryakov, V.D. & Kirillov, V.A. Use of Pd membranes in catalytic reactors for steam methane reforming for pure hydrogen production. Theor Found Chem Eng 45, 595 (2011). https://doi.org/10.1134/S0040579511050356
Received:
Published:
DOI: https://doi.org/10.1134/S0040579511050356