Skip to main content
Log in

Heat Capacity of Phenol and Its Aqueous Solutions at High Temperatures and Pressures

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The isobaric heat capacities of phenol and its aqueous solutions with concentrations of 2, 4, and 5.9 wt % were studied using a scanning calorimeter (IT-s-400) at temperatures from 313 to 473 K and pressures of up to 19.6 MPa. The results were compared with the literature data in the given range of state parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. N. B. Vargaftic, Tables on the Thermophysical Properties of Liquids and Gases (Nauka, Moscow, 1972; Halsted Press, New York, 1975).

  2. Thermophysical Properties of Fluid Systems. http://webbook.nist.gov/chemistry/fluid/

  3. M. Frenkel, R. Chirico, V. Diky, et al., NIST Thermo Data Engine, NIST Standard Reference Database 103b-Pure Compound, Binary Mixtures, and Chemical Reactions, Vers. 5.0 (Natl. Inst. Stand. Technol., Boulder, CO, 2010).

    Google Scholar 

  4. G. S. Parks, H. Huffman, and M. Barmore, J. Am. Chem. Soc. 55, 2733 (1933).

    Article  CAS  Google Scholar 

  5. A. N. Campbell and A. J. R. Campbell, J. Am. Chem. Soc. 62, 291 (1940).

    Article  CAS  Google Scholar 

  6. R. J. L. Andon, J. F. Counsell, E. F. G. Herington, et al., Trans. Faraday Soc. 59, 830 (1963).

    Article  CAS  Google Scholar 

  7. Yu. L. Rastorguev and Yu. A. Ganiev, Izv. Vyssh. Uchebn. Zaved., Neft Gaz 10, 79 (1967).

    CAS  Google Scholar 

  8. N. Nichols and I. Wads, J. Chem. Thermodyn. 7, 329 (1975).

    Article  CAS  Google Scholar 

  9. G. Perron and J. E. Desnoyers, Fluid Phase Equilib. 2, 239 (1979).

    Article  CAS  Google Scholar 

  10. M. L. Origlia-Luster, K. Ballerat-Busserolles, E. D. Merkley, et al., J. Chem. Thermodyn. 35, 331 (2003).

    Article  CAS  Google Scholar 

  11. M. Censky, L. Hnedkovsky, and V. Majer, J. Chem. Thermodyn. 37, 205 (2005).

    Article  CAS  Google Scholar 

  12. V. Hynek, L. Hnedkovsky, and I. Cibulka, J. Chem. Thermodyn. 29, 1237 (1997).

    Article  CAS  Google Scholar 

  13. C. M. Criss and R. H. Wood, J. Chem. Thermodyn. 28, 723 (1996).

    Article  CAS  Google Scholar 

  14. M. Censky, J. Sedlbauer, V. Majer, et al., Geochim. Cosmochim. Acta 71, 580 (2007).

    Article  CAS  Google Scholar 

  15. R. A. Usmanov, R. R. Gabitov, S. A. Biktashev, et al., Russ. J. Phys. Chem. B 5, 1216 (2011).

    Article  CAS  Google Scholar 

  16. Z. I. Zaripov, A. U. Aetov, R. R. Nakipov, et al., J. Mol. Liq. 307, 112935 (2020).

  17. Z. I. Zaripov, A. U. Aetov, R. R. Nakipov, et al., J. Chem. Thermodyn. 152, 106270 (2021).

  18. W. Wagner and A. Pruß, J. Phys. Chem. Ref. Data 31, 387 (2002).

    Article  CAS  Google Scholar 

  19. E. W. Lemmon, M. L. Huber, and M. O. McLinden, NIST Standard Reference Database 23, NIST Reference Fluid Thermodynamic and Transport Properties, REFPROP, Vers. 10.0, Standard Reference Data Program (NIST, Gaithersburg, MD, 2018).

    Google Scholar 

  20. Y. M. Naziev, A. N. Shakhverdiev, M. M. Bashirov, et al., High Temp. 32, 936 (1994).

    Google Scholar 

  21. V. L. Gurvich and N. P. Sosnovskii, Selective Solvents in Petroleum Refining (Gos. Izdat. Neft. Gorno-Topl. Liter., Moscow, 1953) [in Russian].

    Google Scholar 

  22. M. Zabransky, Z. Kolska, V. Ruzicka, et al., J. Phys. Chem. Ref. Data 39, 404 (2010).

    Article  Google Scholar 

  23. M. Zabransky and V. Ruzicka, J. Phys. Chem. Ref. Data 33, 1071 (2004).

    Article  CAS  Google Scholar 

Download references

Funding

This study was financially supported by the Russian Science Foundation (project no. 22-19-00117; https://rscf.ru/prjcard_int?22-19-00117).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. V. Mazanov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zaripov, Z.I., Nakipov, R.R., Mazanov, S.V. et al. Heat Capacity of Phenol and Its Aqueous Solutions at High Temperatures and Pressures. Russ. J. Phys. Chem. (2024). https://doi.org/10.1134/S0036024424020225

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1134/S0036024424020225

Keywords:

Navigation