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Formation of a Single- and Two-Layer Solid Electrolyte by Electrophoresis on Anodic Substrates Metalized with Silver or Platinum

  • ELECTROCHEMISTRY. GENERATION AND STORAGE OF ENERGY FROM RENEWABLE SOURCES
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Abstract

A study is performed of the possibilities of the electrophoretic deposition (EPD) of a single- and two-layer film electrolyte based on Ce0.8Sm0.2O1.9 (SDC) and BaCe0.8Sm0.19Cu0.01O3 (BCSCuO). The materials are deposited on a porous NiO–SDC anode substrate, which is relevant to the technology of creating solid oxide fuel cells. A new procedure is proposed for creating electrical conductivity by infiltrating an aqueous solution of silver nitrate into the porous structure of an anode substrate with subsequent centrifugation and annealing. The procedure is compared to metallizing an anode’s surface by applying a suspension of finely dispersed platinum powder. The dispersity of SDC and BCSCuO particles in aggregatively stable suspensions is studied to perform EPD. The effect adding iodine to a suspension of BCSCuO powder has on precipitation is shown. Metallizing an anode substrate with a silver layer can be considered a variant of EPD for single-layer electrolytes. The formation of a two-layer SDC/BCSCuO electrolyte is observed upon one metallizing of an anode substrate with a platinum layer. It is found that the conductivity of the SDC film on an anode substrate with a Pt sublayer is 17 mS/cm at a temperature of 700°С, with an energy of activation conductivity of 0.51 eV.

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ACKNOWLEDGMENTS

The authors are grateful to researcher L.V. Ermakova at the Institute of Solid State Chemistry for performing our microstructural studies, researcher K.S. Shubin at the Institute of High-Temperature Electrochemistry for performing our electrical studies properties, and researcher A.A. Kol’chugin at the Institute of High-Temperature Electrochemistry for helping to interpret our impedance spectroscopy data. Part of this work was performed on equipment at the shared resource centers of the Institute of High-Temperature Electrochemistry, the Institute of Electrophysics, and the Institute of Solid State Chemistry.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 20-03-00151. Our study of the properties of suspensions based on powder materials was performed a part of a State Task for the Institute of Electrophysics, topic no. 122011200363-9. An in-depth DRT analysis of the spectra was performed as part of a State Task for the Institute of High-Temperature Electrochemistry, topic no. 122020100324-3.

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Authors and Affiliations

  1. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    E. G. Kalinina

  2. Ural Federal University, 620075, Yekaterinburg, Russia

    E. G. Kalinina & E. Yu. Pikalova

  3. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620066, Yekaterinburg, Russia

    E. Yu. Pikalova

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  1. E. G. Kalinina
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Correspondence to E. G. Kalinina.

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Translated by V. Kudrinskaya

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Kalinina, E.G., Pikalova, E.Y. Formation of a Single- and Two-Layer Solid Electrolyte by Electrophoresis on Anodic Substrates Metalized with Silver or Platinum. Russ. J. Phys. Chem. 96, 2763–2773 (2022). https://doi.org/10.1134/S0036024422120147

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