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Dynamics of Lignin Destruction in Pine Wood under the Action of Ozone

  • BIOPHYSICAL CHEMISTRY
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Abstract

The destruction of lignin in pinewood during ozonization is studied via diffuse reflection IR spectroscopy (DRIFT) and Raman spectroscopy. The DRIFT spectra are deconvoluted into Lorentz components. Samples of dioxanlignin obtained from wood are analyzed by means of UV spectroscopy (second derivatives). Based on the DRIFT, Raman, and UV spectra, specific rates of ozone (Qr) consumption corresponding to the oxidation of different structures on the wood surface are determined. In the range of Qr ≤ 1.5 mmol/g, the predominant process is the breakdown of aromatic rings. In the range of 1.5–3.0 mmol/g, hydroxyaromatic compounds formed at the first stage of ozonization are oxidized. At Qr higher than 2.0 mmol/g, aliphatic structures of lignin are also oxidized by ozone, along with carbonyl and carboxylic oxidation products occurring on the surface. These lignin oxidation products block to some extent the accessibility of lignin for ozone.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    N. A. Mamleeva, A. N. Kharlanov & V. V. Lunin

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  1. N. A. Mamleeva
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  2. A. N. Kharlanov
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  3. V. V. Lunin
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Correspondence to N. A. Mamleeva.

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Translated by O. Polyakov

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Mamleeva, N.A., Kharlanov, A.N. & Lunin, V.V. Dynamics of Lignin Destruction in Pine Wood under the Action of Ozone. Russ. J. Phys. Chem. 93, 2550–2554 (2019). https://doi.org/10.1134/S0036024419120185

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