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Thermodynamic Approach to Substantiating the Work and Potential for Separation of Multicomponent Mixtures

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Abstract

Equations for calculating the thermodynamic work of separation are proposed and generalized.

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REFERENCES

  1. A. M. Rozen, Theory of Isotope Separation in Columns (Atomizdat, Moscow, 1960) [in Russian].

    Google Scholar 

  2. M. Benedict and T. Pigford, Nuclear Chemical Engineering (McGraw-Hill, New York, 1981; Khimiya, Moscow, 1960).

  3. S. T. Hwang and K. Kammermeyer, Techniques of Chemistry, Vol. 7: Membranes in Separation (Wiley, New York, 1975).

    Google Scholar 

  4. Isotopes: Properties, Production, Application, Ed. by V. Yu. Baranov (IzdAT, Moscow, 2000) [in Russian].

  5. A. Yu. Smirnov and G. A. Sulaberidze, Russ. J. Phys. Chem. A 93, 786 (2019).

  6. P. G. Kuznetsov, V. A. Sokolov, and I. P. Sedin, Separation and Analysis of Hydrocarbon Gases (Akad. Nauk SSSR, Moscow, 1963), p. 114 [in Russian].

    Google Scholar 

  7. L. A. Nisel’son and V. N. Vigdorovich, in Proceedings of the All-Union Workshop on Production Methods of High Purity Substances (NIITEKhIM, Moscow, 1967), p. 48.

  8. V. M. Popov, A. D. Gerasimov, V. P. Filippov, and V. K. Pervushina, Methods for the Preparation and Analysis of High Purity Substances (Nauka, Moscow, 1970), p. 21 [in Russian].

    Google Scholar 

  9. V. P. Chizhkov, N. V. Sterkhov, and M. P. Zabokritskii, Zh. Fiz. Khim. 65, 1729 (1991).

    Google Scholar 

  10. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 90, 226 (2016).

    Article  CAS  Google Scholar 

  11. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 87, 497 (2013).

    Article  CAS  Google Scholar 

  12. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 89, 309 (2015).

    Article  CAS  Google Scholar 

  13. F. J. Rahn, A. G. Adamantiades, J.E. Kenton, and C. Braun, A Guide to Nuclear Power Technology–A Resource for Decision Making (Wiley, New York, 1984).

  14. S. Allenmark, Chromatographic Enantioseparation: Methods and Applications (Ellis Horwood, Chichester, 1991).

    Google Scholar 

  15. G. A. Sulaberidze and V. D. Borisevich, Russ. J. Phys. Chem. A 82, 1239 (2008).

    Article  CAS  Google Scholar 

  16. V. P. Chizhkov, V. N. Boitsov, and A. V. Demin, Russ. J. Phys. Chem. A 84, 510 (2010).

    Article  CAS  Google Scholar 

  17. R. Treybal, Liquid Extraction (McGraw-Hill, New York, 1951; Khimiya, Moscow, 1966).

  18. Guide on Gas Chromatography, Ed. by E. Leibnitz and H. G. Struppe (Akad. Verlag, Leipzig, 1966; Mir, Moscow, 1988).

  19. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 89, 699 (2015).

    Article  CAS  Google Scholar 

  20. E. I. Eremin, Basics of Chemical Thermodynamics (Vysshaya Shkola, Moscow, 1974) [in Russian].

    Google Scholar 

  21. R. Haywood, Equilibrium Thermodynamics for Engineers and Scientists (Wiley, Chichester, 1980).

    Google Scholar 

  22. I. P. Bazarov, Thermodynamics (Vysshaya Shkola, Moscow, 1983) [in Russian].

    Google Scholar 

  23. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 78, 1136 (2004).

    Google Scholar 

  24. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 82, 1243 (2008).

    Article  CAS  Google Scholar 

  25. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 91, 1127 (2017).

    Article  CAS  Google Scholar 

  26. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 92, 191 (2018).

    Article  CAS  Google Scholar 

  27. V. P. Chizhkov and N. V. Sterkhov, Russ. J. Phys. Chem. A 78, 1651 (2004).

    Google Scholar 

  28. V. P. Chizhkov, V. N. Boitsov, and A. V. Demin, Russ. J. Phys. Chem. A 85, 494 (2011).

    Article  CAS  Google Scholar 

  29. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 91, 586 (2017).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

We express our sincere gratitude to the authors of [5] for their interest in [10–12]. The data and equations presented in [5] will be considered in our further studies.

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. P. Chizhkov & V. N. Boitsov

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  1. V. P. Chizhkov
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  2. V. N. Boitsov
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Correspondence to V. N. Boitsov.

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Translated by A. Bannov

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Chizhkov, V.P., Boitsov, V.N. Thermodynamic Approach to Substantiating the Work and Potential for Separation of Multicomponent Mixtures. Russ. J. Phys. Chem. 93, 790–797 (2019). https://doi.org/10.1134/S0036024419040083

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  • DOI: https://doi.org/10.1134/S0036024419040083

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