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Dependence of the Thermodynamic Characteristics of a Carbon Monoxide–Ethylene–Butene-1 Copolymer on the Concentration of Butane Fragments in the Macromolecules

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
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Abstract

The heat capacity, temperatures and enthalpies of the physical transformations of a triple alternating copolymer of carbon monoxide with ethylene and butene-1 with a 46 mol % concentration of butane fragments are studied via adiabatic and differential scanning calorimetry in the region of 6−570 K. Its combustion energy in a condensed state at T = 298.15 K is measured calorimetrically. Standard thermodynamic functions of the copolymer in the region of T → 0 to 400 K and the thermodynamic characteristics of its formation at T = 298.15 K and synthesis within the range of T → 0 to 400 K are calculated. The dependences of the thermodynamic properties of the copolymer on the concentration of butane fragments in the macromolecules are obtained.

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ACKNOWLEDGMENTS

The authors are grateful to O.M. Chukanova for providing the sample of copolymer used in our calorimetric measurements. This work was performed as part of State Task no. 4.6138.2017/6.7, “Leading Researchers,” from the RF Ministry of Education and Science.

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Authors and Affiliations

  1. Lobachevsky National Research University, 603950, Nizhny Novgorod, Russia

    P. D. Afonin, N. N. Smirnova, A. V. Markin & E. V. Khabarova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    O. N. Golodkov & G. P. Belov

Authors
  1. P. D. Afonin
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  2. N. N. Smirnova
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  3. A. V. Markin
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  4. E. V. Khabarova
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  5. O. N. Golodkov
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  6. G. P. Belov
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Correspondence to N. N. Smirnova.

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Translated by E. Boltukhina

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Afonin, P.D., Smirnova, N.N., Markin, A.V. et al. Dependence of the Thermodynamic Characteristics of a Carbon Monoxide–Ethylene–Butene-1 Copolymer on the Concentration of Butane Fragments in the Macromolecules. Russ. J. Phys. Chem. 92, 1645–1653 (2018). https://doi.org/10.1134/S0036024418090029

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  • DOI: https://doi.org/10.1134/S0036024418090029

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