Abstract
The temperature dependences of the heat capacity and the temperatures and enthalpies of physical transitions of the alternating copolymer of propylene and CO were studied in the 5–550 K region by adiabatic vacuum and dynamic calorimetry techniques. The heat of combustion of the copolymer was measured at 298.15 K in a calorimeter with a static bomb and an isothermal shield. The thermodynamic parameters of glass transition and fusing were estimated. The thermodynamic functions in the 0–450 K region and the thermodynamic characteristics of the formation of the copolymer from simple substances atT=298.15 K andp=101.325 kPa were calculated. The thermodynamic parameters of the alternating copolymerization of bulk propylene and CO were calculated in the 0–450 K region at standard pressure.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1527–1532, August, 1999.
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Lebedev, B.V., Tsevtkova, A.V., Smirnova, N.N. et al. Thermodynamics of alternating copolymer of propylene and CO in the 0–550 K region. Russ Chem Bull 48, 1507–1512 (1999). https://doi.org/10.1007/BF02496401
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DOI: https://doi.org/10.1007/BF02496401