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Self-Assembly of Supramolecular Aggregates Based on Sector- and Cone-Shaped Dendrons and Bolaamphiphiles

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Abstract

Using a number of classes of such sector-shaped macromolecules as derivatives of 2,3,4- and 3,4,5- tri(dodecyloxy)benzenesulfonic acid and dendrimers based on gallic acid as an example, the main stages in the formation of supramolecular ensembles are considered: the formation of individual supramolecular aggregates due to the weak noncovalent interactions of mesogenic groups, and the subsequent ordering within these aggregates, which lowers the free energy of a system. Supramolecular aggregates are in turn organized into two- or three-dimensional supramolecular lattices. It is shown that the shape of the supramolecular aggregates and its change along with temperature are functions of the chemical structure of the mesogenic group (resulting in the controlled design of complex self-organizing systems with a given response to external stimuli).

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Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, 117393, Russia

    M. A. Shcherbina

  2. National Research Center Kurchatov Institute, Moscow, 123182, Russia

    M. A. Shcherbina & S. N. Chvalun

  3. Karpov Institute of Physical Chemistry, Moscow, 105064, Russia

    S. N. Chvalun

Authors
  1. M. A. Shcherbina
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  2. S. N. Chvalun
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Correspondence to M. A. Shcherbina.

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Original Russian Text © M.A. Shcherbina, S.N. Chvalun, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 6, pp. 987–995.

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Shcherbina, M.A., Chvalun, S.N. Self-Assembly of Supramolecular Aggregates Based on Sector- and Cone-Shaped Dendrons and Bolaamphiphiles. Russ. J. Phys. Chem. 92, 1171–1179 (2018). https://doi.org/10.1134/S0036024418060171

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  • DOI: https://doi.org/10.1134/S0036024418060171

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