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Sb(III)-Imprinted Organic-Inorganic Hybrid Sorbent Prepared by Hydrothermal-Assisted Surface Imprinting Technique for Selective Adsorption of Sb(III)

  • Physical Chemistry of Surface Phenomena
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Abstract

Sb(III)-imprinted organic-inorganic hybrid sorbent was prepared by hydrothermal-assisted surface imprinting technique and was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy coupled to an energy dispersive spectrometer and N2 adsorption/desorption isotherms. Hydrothermal-assisted process can improve the selectivity of the Sb(III)-imprinted hybrid sorbent for Sb(III) due to stable control of temperature and pressure. The Sb(III)-imprinted hybrid sorbent IIS indicated higher selectivity for Sb(III), had high static adsorption capacity of 37.3 mg g–1 for Sb(III), displayed stable adsorption capacity in pH range from 4 to 8, reached an rapid adsorption equilibrium within 30 min. According to the correlation coefficient (r2 > 0.99), the experimental data fitted better the pseudo-second-order kinetic model and Langmuir equilibrium isotherm.

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Authors and Affiliations

  1. Department of Chemical Engineering, Yingkou Institute of Technology, Yingkou, 115014, China

    Dan Zhang

  2. College of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China

    Dan Zhang, Yue Zhao & Hong-Bo Xu

Authors
  1. Dan Zhang
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  2. Yue Zhao
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  3. Hong-Bo Xu
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Correspondence to Dan Zhang.

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Zhang, D., Zhao, Y. & Xu, HB. Sb(III)-Imprinted Organic-Inorganic Hybrid Sorbent Prepared by Hydrothermal-Assisted Surface Imprinting Technique for Selective Adsorption of Sb(III). Russ. J. Phys. Chem. 92, 575–581 (2018). https://doi.org/10.1134/S0036024418030056

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  • DOI: https://doi.org/10.1134/S0036024418030056

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