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Heat capacity and thermodynamic functions of thulium orthophosphate TmPO4 in the range of 10–1350 K

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The heat capacity of TmPO4 in temperature ranges of 9.11–346.05 and 304.6–1344.6 K is measured via adiabatic and differential scanning calorimetry, respectively. The measurement data are used to calculate the temperature dependences of the heat capacity, entropy, change in enthalpy, and reduced Gibbs energy of TmPO4 in the range of 10–1344 K. The Gibbs energy of formation of thulium orthophosphate from elements ΔfG0(298.15 K) is determined.

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References

  1. I. A. Bondar’, A. I. Domanskii, L. P. Mezentseva, et al., Zh. Neorg. Khim. 21, 2045 (1976).

    Google Scholar 

  2. P. Morin, J. Rouchy, and Z. Kazei, Phys. Rev. B 51, 15103 (1995).

    Article  CAS  Google Scholar 

  3. P. K. Chakrabarti, K. N. Chattopadhyay, S. Modak, and J. Mondal, Hyperfine Interact. 175, 131 (2007).

    Article  CAS  Google Scholar 

  4. M. D. Kaplan and B. G. Vekhter, J. Phys. C: Solid State Phys. 16, L191 (1983).

    Article  CAS  Google Scholar 

  5. P. Morin and Z. Kazei, Phys. Rev. B 55, 8887 (1997).

    Article  CAS  Google Scholar 

  6. P. Morin, J. Rouchy, and Z. Kazei, J. Phys.: Condens. Matter. 8, 7967 (1996).

    CAS  Google Scholar 

  7. A. Kirste, M. von Ortenberg, A. A. Demidov, et al., Physica B 336, 335 (2003).

    Article  CAS  Google Scholar 

  8. H. Suzuki, Y. Higashino, and T. Ohtsuka, J. Low Temp. Phys. 41, 449 (1980).

    Article  CAS  Google Scholar 

  9. F. Mehran, T. S. Plaskett, and K. W. H. Stewens, Phys. Rev. B 16, 1 (1977).

    Article  CAS  Google Scholar 

  10. V. A. Ioffe, S. I. Andronenko, I. A. Bondar’, et al., JETP Lett. 34, 562 (1981).

    Google Scholar 

  11. G. A. Gehring and K. A. Gehring, Rep. Prog. Phys. 38, 1 (1975).

    Article  CAS  Google Scholar 

  12. R. T. Harley and D. I. Manning, Phys. C 11, L633 (1978).

    Article  CAS  Google Scholar 

  13. S. V. Ushakov, K. B. Helean, A. Navrotsky, and L. A. Boatner, J. Mater. Res. 16, 2623 (2001).

    Article  CAS  Google Scholar 

  14. I. A. Rat’kovskii, V. A. Ashuiko, V. P. Orlovskii, et al., Dokl. Akad. Nauk SSSR 219, 1413 (1974).

    Google Scholar 

  15. K. S. Gavrichev, N. N. Smirnova, V. M. Gurevich, et al., Thermochim. Acta 448, 63 (2006).

    Article  CAS  Google Scholar 

  16. K. S. Gavrichev, M. A. Ryumin, A. V. Tyurin, et al., Thermochim. Acta 474, 47 (2008).

    Article  CAS  Google Scholar 

  17. Y. Ni, J. M. Hughes, and A. N. Mariano, Am. Mineral. 80, 21 (1995).

    Article  CAS  Google Scholar 

  18. A. T. Aldred, Acta Crystallogr. B 40, 569 (1984).

    Article  Google Scholar 

  19. H. Schwarz, Z. Anorg. Allg. Chem. 323, 44 (1963).

    Article  CAS  Google Scholar 

  20. V. V. Malyshev, G. A. Mil’ner, E. L. Sorkin, and V. F. Shibakin, Prib. Tekh. Eksp., No. 6, 195 (1985).

    Google Scholar 

  21. http://www.physics.nist.gov/PhysRefData/Compositions.

  22. V. M. Gurevich and V. G. Khlyustov, Geokhimiya, No. 6, 829 (1979).

    Google Scholar 

  23. D. Hudson, Statistics Lectures on Elementary Statistics and Probability (CERN, Geneva, 1964).

    Google Scholar 

  24. C. G. Maier and K. K. Kelley, J. Am. Chem. Soc. 54, 3243 (1932).

    Article  CAS  Google Scholar 

  25. E. F. Westrum, Jr., J. Chem. Thermodyn. 15, 305 (1983).

    Article  CAS  Google Scholar 

  26. V. M. Gurevich, M. A. Ryumin, A. V. Tyurin, and L. N. Komissarova, Geochem. Int. 50, 702 (2012).

    Article  CAS  Google Scholar 

  27. G. E. Nikiforova, M. A. Ryumin, K. S. Gavrichev, and V. M. Gurevich, Inorg. Mater. 48, 841 (2012).

    Article  CAS  Google Scholar 

  28. S. Rodriguez-Liviano, A. I. Becerro, D. Alcántara, et al., Inorg. Chem. 52, 647 (2013).

    Article  CAS  Google Scholar 

  29. S. M. Skuratov, V. P. Kolesov, and A. F. Vorob’ev, Thermochemistry (Mosk. Gos. Univ., Moscow, 1966), Vol. 2 [in Russian].

  30. Z. A. Kazei, N. P. Kolmakova, and O. A. Shishkina, Phys. Solid State 39, 91 (1997).

    Article  Google Scholar 

  31. Thermal Constants of Substances, Ed. by V. P. Glushko (Nauka, Moscow, 1965–1982) [in Russian]. http://www.chem.msu.ru.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117907, Russia

    M. A. Ryumin, A. V. Khoroshilov, A. V. Tyurin & K. S. Gavrichev

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. M. Gurevich

Authors
  1. M. A. Ryumin
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  2. V. M. Gurevich
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  3. A. V. Khoroshilov
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  4. A. V. Tyurin
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  5. K. S. Gavrichev
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Correspondence to M. A. Ryumin.

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Original Russian Text © M.A. Ryumin, V.M. Gurevich, A.V. Khoroshilov, A.V. Tyurin, K.S. Gavrichev, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 12, pp. 2023–2029.

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Ryumin, M.A., Gurevich, V.M., Khoroshilov, A.V. et al. Heat capacity and thermodynamic functions of thulium orthophosphate TmPO4 in the range of 10–1350 K. Russ. J. Phys. Chem. 91, 2310–2316 (2017). https://doi.org/10.1134/S003602441711019X

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  • DOI: https://doi.org/10.1134/S003602441711019X

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