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Hydroxylation of phenol over MeAPO molecular sieves synthesized by vapor phase transport

  • Chemical Kinetics and Catalysis
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Abstract

In this study, MeAPO-25 (Me = Fe, Cu, Mn) molecular sieves were first synthesized by a vapor phase transport method using tetramethyl guanidine as the template and applied to hydroxylation of phenol. The zeolites were characterized by XRD, SEM, FT-IR, and DR UV–Vis. As a result, MeAPO-21 and MeAPO-15 were synthesized by changing the Me/Al ratio. UV–Visible diffuse reflectance study suggested incorporation of heteroatoms into the framework and FT-IR study also supported these data. Effects of heteroatoms, contents of Me in MeAPO-25, reaction temperature, phenol/H2O2 mole ratios, reaction time and concentration of catalyst on the conversion of phenol, as well as on the selectivity were studied. FeAPO-25 exhibited a high catalytic activity at the mole ratio of FeO and Al2O3 equal to 0.1 in the synthesis gel, giving the phenol conversion of 88.75% and diphenols selectivity of 66.23% at 60°C within 3 h [n(phenol)/n(H2O2) = 0.75, m(FeAPO-25)/m(phenol) = 7.5%]. Experimental results indicated that the FeAPO-25 molecular sieve was a fairly promising candidate for the application in hydroxylation of phenol.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China

    Hui Shao, Jingjing Chen, Xia Chen, Yixin Leng & Jing Zhong

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  1. Hui Shao
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  2. Jingjing Chen
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  3. Xia Chen
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  4. Yixin Leng
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  5. Jing Zhong
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Correspondence to Hui Shao.

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Shao, H., Chen, J., Chen, X. et al. Hydroxylation of phenol over MeAPO molecular sieves synthesized by vapor phase transport. Russ. J. Phys. Chem. 90, 1326–1333 (2016). https://doi.org/10.1134/S0036024416070116

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  • DOI: https://doi.org/10.1134/S0036024416070116

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