Abstract
Task-specific ionic liquid 1-butyl-3-methylimidazolium salicylate ([BMI]Sal) was synthesized in two steps. In the temperature range of 298.15–353.15 K, the density and surface tension for pure ionic liquid were determined and the thermodynamic properties of the ionic liquid were discussed in terms of Glasser’s theory. The standard molar entropy and lattice energy for [BMI]Sal have been estimated. In addition, the thermal expansion coefficient, α = 5.53 × 10−4 K−1, calculated by the interstice model is in extreme agreement with α (experimental) = 5.50 × 10−4 K−1.
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References
R. D. Rogers and K. R. Seddon, Science 302, 792 (2003).
M. Galiński, A. Lewandowski, and I. Stępniak, Electrochim. Acta 51, 5567 (2006).
J. S. Wilkes and M. J. Zaworotko, Chem. Commun. 16, 965 (1992).
J. H. Davis, Jr., Chem. Lett. 33, 1072 (2004).
H. Liu, G. Cheng, M. Kent, V. Stavila, B. A. Simmons, K. L. Sale, S. Singh, J. Phys. Chem. B 116, 8131 (2012).
L. Guo, T. Shi, Z. Li, and Y. Duan, J. Chem. Ind. Eng. (Chin.) 59, 1329 (2008).
I. Krossing and J. M. Slattery, Z. Phys. Chem. 220, 1343 (2006).
J. Z. Yang, Q. G. Zhang, B. Wang, and J. Tong, J. Phys. Chem. B 110, 22521 (2006).
W. Guan, J. Tong, S. P. Chen, Q. S. Liu, and S. L. Gao, J. Chem. Eng. Data 55, 4075 (2010).
J. S. Wilkes, J. A. Levisky, R. A. Wilson, and C. L. Hussey, Inorg. Chem. 21, 1263 (1982).
X. D. Wang, W. Y. Wu, G. F. Tu, and K. X. Jiang, Trans. Nonferrous Met. Soc. China 20, 2032 (2010).
Y. Wei and Q. G. Zhang, Acta Chim. Sin. 66, 1879 (2008).
Q. G. Zhang and Y. Wei, J. Chem. Thermodyn. 40, 640 (2008).
J. Z. Yang, J. S. Gui, X. M. Lu, G. Q. Zhang, and H. W. Li, Acta Chim. Sin. 63, 577 (2005).
D. R. Lide, Handbook of Chemistry and Physics, 82nd ed. (CRC Press, Boca Raton, 2001).
L. Glasser, Thermochim. Acta 421, 87 (2004).
Z. Q. Huang, The Introduction to Electrolyte Solution Theory (Science Press, Beijing, 1983) [in Chinese].
A. W. Adamson, Physical Chemistry of Surfaces, 3rd ed. (Wiley, New York, 1976).
L. P. N. Rebelo, L. Canongia, J. Esperança, and E. Filipe, J. Phys. Chem. B 109, 6040 (2005).
J. Z. Yang, X. M. Lu, J. S. Gui, and W. G. Xu, Green Chem. 6, 541 (2004).
Q. G. Zhang, J. Z. Yang, X. M. Lu, J. S. Gui, and M. Huang, Fluid Phase Equilib. 226, 207 (2004).
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Wang, XD., Han, C. & Fan, HT. Synthesis and thermodynamic properties of a new task-specific ionic liquid 1-butyl-3-methylimidazolium salicylate. Russ. J. Phys. Chem. 89, 1158–1162 (2015). https://doi.org/10.1134/S0036024415070328
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DOI: https://doi.org/10.1134/S0036024415070328